Deposition and anneal behavior of Al-1.5%Cu films: TEM characterization
Al-1.5%Cu materials are of interest for interconnect-metallization in semiconductor integrated-circuits. It is known from the literature that the mean-time-to-failure (MTF) due to electromigration of the Al-1.5%Cu interconnects depends on the microstructure of the materials. A correlation is seen for instance between grain-size distributions in the material and the MTF. Uniform large-grained distributions improve lifetime. The present study evaluated the microstructure of Al-1.5%Cu films deposited and annealed under different conditions.Al-1.5%Cu films had been deposited at 25°C and at 300°C; the layers had then been annealed at 300°C for 17 hours, prior to TEM investigation. Plan-view TEM specimens were prepared in the 100 substrategeometry, and cross-section TEM specimens were prepared in the 110 substrate-geometry. These were then analyzed using bright-field and dark-field TEM imaging techniques. A JEOL JEM 200CX transmission electron microscope was used for the investigation, operating at 200 kV.