TEM study of boron additions to cobalt aluminide

Author(s):  
Gerald B. Feldewerth

In recent years an increasing emphasis has been placed on the study of high temperature intermetallic compounds for possible aerospace applications. One group of interest is the B2 aiuminides. This group of intermetaliics has a very high melting temperature, good high temperature, and excellent specific strength. These qualities make it a candidate for applications such as turbine engines. The B2 aiuminides exist over a wide range of compositions and also have a large solubility for third element substitutional additions, which may allow alloying additions to overcome their major drawback, their brittle nature.One B2 aluminide currently being studied is cobalt aluminide. Optical microscopy of CoAl alloys produced at the University of Missouri-Rolla showed a dramatic decrease in the grain size which affects the yield strength and flow stress of long range ordered alloys, and a change in the grain shape with the addition of 0.5 % boron.

2000 ◽  
Vol 646 ◽  
Author(s):  
Fritz Appel ◽  
Helmut Clemens ◽  
Michael Oehring

ABSTRACTIntermetallic titanium aluminides are one of the few classes of emerging materials that have the potential to be used in demanding high-temperature structural applications whenever specific strength and stiffness are of major concern. However, in order to effectively replace the heavier nickel-base superalloys currently in use, titanium aluminides must combine a wide range of mechanical property capabilities. Advanced alloy designs are tailored for strength, toughness, creep resistance, and environmental stability. Some of these concerns are addressed in the present paper through specific comments on the physical metallurgy and technology of gamma TiAl-base alloys. Particular emphasis is placed on recent developments of TiAl alloys with enhanced high-temperature capability.


2021 ◽  
Author(s):  
VINOTHINI VENKATACHALAM, ◽  
JON BINNER ◽  
THOMAS REIMER ◽  
BUCKARD ESSER ◽  
STEFANO MUNGIGUERRA ◽  
...  

Carbon fibre (Cf) reinforced Ultra High Temperature Ceramic (UHTC) Matrix Composites (UHTCMCs) have proven to be excellent materials that can survive nearly 3000°C in highly oxidizing environments along with a good specific strength. Consequently, they have excellent potential for use in aerospace applications such as rocket nozzle throats and thermal protection systems (TPS). Due to the presence of the carbon fibres, UHTCMCs offer high strength and modulus combined with excellent thermal shock behaviour whilst the presence of the ultra-high temperature ceramic phase protects the carbon fibres at the application temperatures. High temperature oxidation, thermal ablation behaviour and mechanical properties of the UHTCMC’s relies heavily on the bonding between the carbon fibre and matrices especially the oxides formed to avoid any progressive failure and predict the life of the components. In the present investigation, a radio frequency assisted chemical vapor infiltration (RF-CVI) technique has been used to make the 2.5D Cf reinforced ZrB2, ZrB2/carbon matrices composites with various interphase materials. The advantage of RF heating is that it creates an inverse temperature profile in the sample, which means that the infiltration starts from inside and progresses outwards. This allows the time needed for processing to be reduced very significantly compared to the conventional CVI process. This presentation will report on the latest results from the research that has been undertaken at the University of Birmingham, including the results from a wide range of testing that has been undertaken at both DLR in Germany and the University of Naples in Italy.


1951 ◽  
Vol 49 (2-3) ◽  
pp. 169-174 ◽  
Author(s):  
J. Gordon ◽  
R. A. Hall ◽  
L. H. Stickland

The lysis of Bacterium coli suspensions brought about by glycine shows the following characteristics:(1) There is a latent period of 2 hr., followed by a rapid lysis reaching a maximum in about 8 hr.(2) The extent of the lysis is independent of the dilution of the bacterial suspension over a wide range.(3) The extent of the lysis increases with the glycine concentration up to 10M, but is approaching a limit at this concentration.(4) The lysis is negligible below pH 5 and above pH 10, and shows a maximum rate in the region of pH 6–5–8–5.(5) The rate of lysis has a very high temperature coefficient (Q10 of the order of 5).


2008 ◽  
Vol 59 ◽  
pp. 87-91 ◽  
Author(s):  
K. Mergia ◽  
Volker Liedtke ◽  
T. Speliotis ◽  
G. Apostolopoulos ◽  
S. Messoloras

The use of ceramic composite materials in aerospace applications requires the development of oxidization protection coatings which can withstand very high temperatures. HfO2 is a promising material as a high temperature oxidization protective layer. HfO2 coatings have been deposited by radiation frequency magnetron sputtering all over the surface of SiC substrates and were tested under re-entry conditions. Also their oxidization resistance in air in the temperature range 1100 to 1450°C has been examined. The coatings were found to be stable and well-adhering to the substrate even after 100 re-entry cycles. No oxidization of the underlying SiC structure is observed. Re-entry and oxidization tests result in the formation of HfSiO4 at the HfO2/SiC interface, which further promotes their oxidization resistance.


2016 ◽  
Author(s):  
◽  
Bassem Shebl

[ACCESS RESTRICTED TO THE UNIVERSITY OF MISSOURI AT AUTHOR'S REQUEST.] Synthesizing proteins in the cell is a critical aspect of life. Protein synthesis is a complicated process and involve highly functional machines at a molecular level. The ribosome is the molecular machine that translate coded sequences of nucleic acids into functional proteins. Understanding how ribosomes function is key to understanding protein synthesis / translation. We focus our work on ribosomes from bacterial cells. This allows us to study much simpler systems and extrapolate our knowledge to higher levels. One key challenge in the field is to be able to isolate a high quantity of good and active ribosomes out of the cell to study it in a controlled environment. Classically known methods involve extensive resources, high technical expertise, and a week of preparation. We developed a one-step protocol to purify ribosomes that are more active than the ones purified from classical methods. This developed technique saves time and money and results in much higher amounts of product. This approach also makes the technique approachable to a wider community of scientists and researchers. The same methodology could be applied towards purifying other molecular machines in the cells. Using these ribosomes, we wanted to investigate how the ribosomes function in cells when faced with specific signals. These signals are utilized by the cells to control protein synthesis. However, in dome diseased cells and for some viruses, normal protein synthesis is overridden by the invaders to produce faulty proteins that could result in a wide range of diseases such as Alzheimer and others. In this study, we investigated how the ribosome functions in the presence of such signals and how close do they need to be to the ribosome to affect protein synthesis. This allows us to design drugs to mimic or inhibit such changes thus fixing faulty protein production or sometimes induce it to inhibit protein synthesis in bacterial cells and as such designing and producing novel drugs.


1985 ◽  
Vol 6 (1) ◽  
pp. 38-43 ◽  
Author(s):  
J . Davis ◽  
W . J . Tango

AbstractThe Chatterton Astronomy Department of the University of Sydney is proposing the construction of a very high angular resolution stellar interferometer of major astronomical and international significance. Based on the prototype modern Michelson stellar interferometer which the Department has developed, the new instrument will be used in a wide range of astrophysical programmes. The siting, specification, design and costing of the instrument are outlined.


Author(s):  
Hooshang Heshmat ◽  
James F. Walton ◽  
Brian D. Nicholson

In this paper, the authors present the results of recent developments demonstrating that ultra-high temperature compliant foil bearings are suitable for application in a wide range of high temperature turbomachinery including gas turbine engines, supercritical CO2 power turbines and automotive turbochargers as supported by test data showing operation of foil bearings at temperatures to 870°C (1600°F). This work represents the culmination of efforts begun in 1987, when the U.S. Air Force established and led the government and industry collaborative Integrated High Performance Turbine Engine Technology (IHPTET) program. The stated goal of IHPTET was to deliver twice the propulsion capability of turbine engines in existence at that time. Following IHPTET, the Versatile Affordable Advanced Turbine Engines (VAATE) program further expanded on the original goals by including both versatility and affordability as key elements in advancing turbine engine technology. Achieving the stated performance goals would require significantly more extreme operating conditions including higher temperatures, pressures and speeds, which in turn would require bearings capable of sustaining temperatures in excess of 815°C (1500°F). Similarly, demands for more efficient automotive engines and power plants are subjecting the bearings in turbochargers and turbogenerators to more severe environments. Through the IHPTET and VAATE programs, the U.S. has made considerable research investments to advancing bearing technology, including active magnetic bearings, solid and vapor phase lubricated rolling element bearings, ceramic/hybrid ceramic bearings, powder lubricated bearings and compliant foil gas bearings. Thirty years after the IHPTET component goal of developing a bearing capable of sustained operation at temperatures above 540°C and potentially as high as 815°C (1500°F) recent testing has demonstrated achievement of this goal with an advanced, ultra-high temperature compliant foilgas bearing. Achieving this goal required a combination of high temperature foil material, a unique elastic-tribo-thermal barrier coating (KOROLON 2250) and a self-adapting compliant configuration. The authors describe the experimental hardware designs and design considerations of the two differently sized test rigs used to demonstrate foil bearings operating above 815°C (1500°F). Finally, the authors present and discuss the results of testing at temperatures to 870°C (1600°F).


2018 ◽  
Author(s):  
◽  
Nick Francis Potter

[ACCESS RESTRICTED TO THE UNIVERSITY OF MISSOURI AT AUTHOR'S REQUEST.] This manuscript considers the influence of twentieth-century avant-garde literature and painting in contemporary art comics, particularly the growing sub-genre of comics poetry. The introduction lays a historical groundwork for this specific strain of comics, including antecedent works and a consideration for how the genre fits into the comics medium's longstanding struggle for cultural legitimacy. Further, the introductory essay examines how the wide range of comics that fit under the umbrella of comics poetry remediate modernist practices in poetry and painting, foregrounding simultaneity and materiality over transparency and narrative. This introduction considers seminal works in the field, including Warren Craghead's How to be Everywhere (2007), which reworks the calligrammes of Apollinaire, and Erin Curry's Songs of the Sea (2016), directly inspired by Cy Twombly's series of paintings by the same name. In addition to analyzing these comics, the paper considers how these works have been utilized by comics critics (Baetens, Gronesteen, Bennett, Badman) in revising and expanding critical frameworks in comics studies and developing an artist-critic relationship that closely mirrors those documented between the modernist avant-garde and the semiotic theory of Saussure early in the twentieth century (Drucker). The subsequent manuscript follow exhibits a collection of comics works that maintain a formal relationship with those discussed in the introduction.


2015 ◽  
Author(s):  
◽  
Roman Hillebrand

[ACCESS RESTRICTED TO THE UNIVERSITY OF MISSOURI AT REQUEST OF AUTHOR.] Protein-tyrosine phosphatase 1B (PTP1B) is a negative regulator in the insulin signaling cascade. A lot of research has focused on inhibiting PTP1B but with no success. Only one drug is currently in phase II clinical trials. We have developed a synthetic protocol to create a library of molecules that target residues outside the active site and covalently bind to the enzyme via close proximity alkylation. These molecules will be analyzed towards inactivation/inhibition capabilities. Tirapazamine is a hypoxia selective anti-cancer drug. New derivatives of Tirapazamine are sought after. We have analyzed and optimized Suzuki-Miyaura and Buchwald-Hartwig couplings reactions towards new derivatives of Tirapazamine. Allyl isothiocyanate (AITC) is a phytochemical that can be found in cruciferous vegetables and has received interest due to beneficial health effects. During our analyses of AITC towards inactivation of PTP1B we noticed the surprising absence of the isothiocyanate carbon in 13C NMR spectra. Calculations show that the absence is due to the facile change of the N-hybridization in the wide range of 120 less than 180 bond angles in AITC.


2019 ◽  
Author(s):  
◽  
Nathan Edward White

[ACCESS RESTRICTED TO THE UNIVERSITY OF MISSOURI AT REQUEST OF AUTHOR.] High-temperature gas-cooled reactors (HTGRs) generate carbonaceous dust during both normal operations and accidents. The dust particles can be both highly irregular and porous and have exceptionally large surface areas, making dust-facilitated fission product (FP) transport a major factor in the computation of the nuclear source term. Since the FP interactions with the dust can occur while the dust is on a surface as well as in suspension, there is a need to obtain computational and experimental results for both situations. Since the particle sizes of interest span a wide range, from nanometers to microns, and are porous with various pathways for FP interactions to occur, these computations need to include not only the continuum regime, but the transport regime as well where the particle (or pore) size is comparable to the vapor (FP) mean free path. The focus of this dissertation is on Monte Carlo computation of the condensation rate on chainlike particles and particle agglomerates in the transport regime, towards a better understanding of how aerosol geometry affects mass transport on those particles.


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