Nanoscale Reactivity Mapping of a Single-Crystal Boron-Doped Diamond Particle

2021 ◽  
Vol 93 (14) ◽  
pp. 5831-5838
Author(s):  
Tomohiro Ando ◽  
Kai Asai ◽  
Julie Macpherson ◽  
Yasuaki Einaga ◽  
Takeshi Fukuma ◽  
...  
2009 ◽  
Vol 76-78 ◽  
pp. 684-689 ◽  
Author(s):  
Kiyoshi Suzuki ◽  
Yoichi Shiraishi ◽  
Nobuhiro Nakajima ◽  
Manabu Iwai ◽  
Shinichi Ninomiya ◽  
...  

This paper deals with a new PCD named EC-PCD which is made up of boron doped diamond particles and its properties related to EDM machinability. For the purpose of improving various properties of standard PCD including resistance to heat, wear and reactivity, a new PCD (EC-PCD) was manufactured on a trial basis using electrically conductive diamond particle as a basic ingredient. Grain size, resistivity and thermal conductivity of the boron doped diamond used are 10μm, 5~37×10Ω•m and 440~580W/m•K. In this report, machinability of newly developed PCD (EC-PCD) by wire EDM was investigated in comparison with that of standard PCD. In wire cutting of 2 types of PCD in water under the condition of open gap voltage: ue=80V, set peak current: iP=0.8A and pulse condition: te/to=20/20μs, it was found that roughness of the first cut surface of standard PCD was approximately 8μm Rz, while that of EC-PCD was far better such as 3μm. Also in finish cut (7th cut), the latter achieved the value of Rz=1.7μm while the former achieved only the value of Rz=2.7μm. Expecting better performance, EC-PCD was tested also in oil. As a result, the best achieved roughness was improved to Rz=0.4μm with no chipping on the edge. To explore a reason for such a good roughness obtained, the cut samples were observed on the SEM, which revealed that the diamond particles in EC-PCD were flattened by electro discharge.


2011 ◽  
Vol 1282 ◽  
Author(s):  
Tomas L. Martin ◽  
Kane M. O’Donnell ◽  
Hidetsugu Shiozawa ◽  
Cristina E. Giusca ◽  
Neil A. Fox ◽  
...  

ABSTRACTThin lithium layers on oxygenated C(100) boron-doped diamond have been observed using x-ray photoemission spectroscopy. Conductive boron-doped diamond was oxygen-terminated using an ozone cleaner. Lithium was evaporated onto the oxygen-terminated C(100) surface and an as-grown hydrogen terminated surface to a thickness of approximately 50 nm. After washing with deionised water, significant lithium signal is still detected on oxygenated diamond, but not on hydrogenated diamond, indicating a strongly bound lithium-oxygen surface layer is formed, as predicted by recent theoretical modeling.


2008 ◽  
Vol 25 (7) ◽  
pp. 2667-2669 ◽  
Author(s):  
Zhang He-Min ◽  
Zang Chuan-Yi ◽  
Li Xiao-Lei ◽  
Ma Hong-An ◽  
Li Shang-Sheng ◽  
...  

2009 ◽  
Vol 1203 ◽  
Author(s):  
Timothy Grotjohn ◽  
Shannon Nicley ◽  
Dzung Tran ◽  
Donnie K. Reinhard ◽  
Michael Becker ◽  
...  

AbstractThe electrical characteristics of high quality single crystal boron-doped diamond are studied. Samples are synthesized in a high power-density microwave plasma-assisted chemical vapor deposition (CVD) reactor at pressures of 130-160 Torr. The boron-doped diamond films are grown using diborane in the feedgas at concentrations of 1 to 50 ppm. The boron acceptor concentration is investigated using infrared absorption and a four point probe is used to study the conductivity. The temperature dependent conductivity is analyzed to determine the boron dopant activation energy.


1998 ◽  
Vol 10 (6) ◽  
pp. 1267-1272 ◽  
Author(s):  
Takao Saotome ◽  
Kazutoshi Ohashi ◽  
Toshimaro Sato ◽  
Hiroshi Maeta ◽  
Katsuji Haruna ◽  
...  

2009 ◽  
Vol 18 (5-8) ◽  
pp. 816-819 ◽  
Author(s):  
C. Pietzka ◽  
A. Denisenko ◽  
L.A. Kibler ◽  
J. Scharpf ◽  
Y. Men ◽  
...  

2016 ◽  
Vol 28 (10) ◽  
pp. 2297-2302 ◽  
Author(s):  
Lucy I. Tomlinson ◽  
Hollie V. Patten ◽  
Ben L. Green ◽  
James Iacobini ◽  
Katherine E. Meadows ◽  
...  

2002 ◽  
Vol 149 (6) ◽  
pp. E179 ◽  
Author(s):  
Takeshi Kondo ◽  
Yasuaki Einaga ◽  
Bulusu V. Sarada ◽  
Tata N. Rao ◽  
Donald A. Tryk ◽  
...  

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