The Conformational Preference of Chemical Cross-linkers Determines the Cross-linking Probability of Reactive Protein Residues

2020 ◽  
Vol 124 (22) ◽  
pp. 4446-4453 ◽  
Author(s):  
Zhou Gong ◽  
Shang-Xiang Ye ◽  
Ze-Feng Nie ◽  
Chun Tang
Keyword(s):  
Cross Linking ◽  
Conformational Preference ◽  
Protein Residues ◽  
Reactive Protein ◽  
The Cross

scholarly journals Investigation of the functional network modifier loading on the stoichiometric ratio of epoxy resins and their dielectric properties

2021 ◽  
Author(s):  
Istebreq A. Saeedi ◽  
Sunny Chaudhary ◽  
Thomas Andritsch ◽  
Alun S. Vaughan
Keyword(s):  
Glass Transition ◽  
Dielectric Properties ◽  
Electrical Properties ◽  
Epoxy Resins ◽  
Functional Network ◽  
Cross Linking ◽  
Network Modifier ◽  
Epoxy Resin System ◽  
The Cross ◽  
The Impact

AbstractReactive molecular additives have often been employed to tailor the mechanical properties of epoxy resins. In addition, several studies have reported improved electrical properties in such systems, where the network architecture and included function groups have been modified through the use of so-called functional network modifier (FNM) molecules. The study reported here set out to investigate the effect of a glycidyl polyhedral oligomeric silsesquioxane (GPOSS) FNM on the cross-linking reactions, glass transition, breakdown strength and dielectric properties of an amine-cured epoxy resin system. Since many previous studies have considered POSS to act as an inorganic filler, a key aim was to consider the impact of GPOSS addition on the stoichiometry of curing. Fourier transform infrared spectroscopy revealed significant changes in the cross-linking reactions that occur if appropriate stoichiometric compensation is not made for the additional epoxide groups present on the GPOSS. These changes, in concert with the direct effect of the GPOSS itself, influence the glass transition temperature, dielectric breakdown behaviour and dielectric response of the system. Specifically, the work shows that the inclusion of GPOSS can result in beneficial changes in electrical properties, but that these gains are easily lost if consequential changes in the matrix polymer are not appropriately counteracted. Nevertheless, if the system is appropriately optimized, materials with pronounced improvements in technologically important characteristics can be designed.

scholarly journals The Effect of Surfactant-Modified Montmorillonite on the Cross-Linking Efficiency of Polysiloxanes

Materials ◽  
2021 ◽  
Vol 14 (10) ◽  
pp. 2623
Author(s):  
Monika Wójcik-Bania ◽  
Jakub Matusik
Keyword(s):  
Total Pore Volume ◽  
Cross Linking ◽  
X Ray Diffraction ◽  
X Ray ◽  
Transmission Electron ◽  
The Cross ◽  
Chain Lengths ◽  
First Time ◽  
Substituent Influence ◽  
Benzyl Substituent

Polymer–clay mineral composites are an important class of materials with various applications in the industry. Despite interesting properties of polysiloxanes, such matrices were rarely used in combination with clay minerals. Thus, for the first time, a systematic study was designed to investigate the cross-linking efficiency of polysiloxane networks in the presence of 2 wt % of organo-montmorillonite. Montmorillonite (Mt) was intercalated with six quaternary ammonium salts of the cation structure [(CH3)2R’NR]+, where R = C12, C14, C16, and R’ = methyl or benzyl substituent. The intercalation efficiency was examined by X-ray diffraction, CHN elemental analysis, and Fourier transform infrared (FTIR) spectroscopy. Textural studies have shown that the application of freezing in liquid nitrogen and freeze-drying after the intercalation increases the specific surface area and the total pore volume of organo-Mt. The polymer matrix was a poly(methylhydrosiloxane) cross-linked with two linear vinylsiloxanes of different siloxane chain lengths between end functional groups. X-ray diffraction and transmission electron microscopy studies have shown that the increase in d-spacing of organo-Mt and the benzyl substituent influence the degree of nanofillers’ exfoliation in the nanocomposites. The increase in the degree of organo-Mt exfoliation reduces the efficiency of hydrosilylation reaction monitored by FTIR. This was due to physical hindrance induced by exfoliated Mt particles.

scholarly journals The Biosynthesis of the Cross-linking Peptides in the Cell Wall Peptidoglycan of Staphylococcus aureus

1972 ◽  
Vol 247 (19) ◽  
pp. 6306-6311 ◽  
Author(s):  
Tatsuyuki Kamiryo ◽  
Michio Matsuhashi
Keyword(s):  
Staphylococcus Aureus ◽  
Cell Wall ◽  
Cross Linking ◽  
Cell Wall Peptidoglycan ◽  
The Cross

Effects of a crosslinking agent on a supramolecular gel to control lost circulation

2021 ◽  
Vol 45 (16) ◽  
pp. 7089-7095
Author(s):  
Bo Wang ◽  
Jinsheng Sun ◽  
Kaihe Lv ◽  
Feng Shen ◽  
Yingrui Bai
Keyword(s):  
Crosslinking Agent ◽  
Network Density ◽  
Cross Linking ◽  
Supramolecular Gel ◽  
Lost Circulation ◽  
The Cross

The Cr3+ can improve the cross-linking degree and network density of the GP-A gel, and enhance its strength and plugging ability to control lost circulation.

scholarly journals Superoxide peroxidase activity of ovoperoxidase, the cross-linking enzyme of fertilization.

1990 ◽  
Vol 265 (16) ◽  
pp. 9241-9246
Author(s):  
J W Heinecke ◽  
B M Shapiro
Keyword(s):  
Peroxidase Activity ◽  
Cross Linking ◽  
The Cross

scholarly journals Effect of the Cross-Linking Density on the Swelling and Rheological Behavior of Ester-Bridged β-Cyclodextrin Nanosponges

Materials ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 478
Author(s):  
Gjylije Hoti ◽  
Fabrizio Caldera ◽  
Claudio Cecone ◽  
Alberto Rubin Pedrazzo ◽  
Anastasia Anceschi ◽  
...  
Keyword(s):  
Scale Up ◽  
Future Application ◽  
Cross Linking ◽  
Synthesis Reaction ◽  
Dependent Behavior ◽  
Cyclodextrin Nanosponges ◽  
Potential Applications ◽  
Cross Linker ◽  
The Cross ◽  
Shed Light

The cross-linking density influences the physicochemical properties of cyclodextrin-based nanosponges (CD-NSs). Although the effect of the cross-linker type and content on the NSs performance has been investigated, a detailed study of the cross-linking density has never been performed. In this contribution, nine ester-bridged NSs based on β-cyclodextrin (β-CD) and different quantities of pyromellitic dianhydride (PMDA), used as a cross-linking agent in stoichiometric proportions of 2, 3, 4, 5, 6, 7, 8, 9, and 10 moles of PMDA for each mole of CD, were synthesized and characterized in terms of swelling and rheological properties. The results, from the swelling experiments, exploiting Flory–Rehner theory, and rheology, strongly showed a cross-linker content-dependent behavior. The study of cross-linking density allowed to shed light on the efficiency of the synthesis reaction methods. Overall, our study demonstrates that by varying the amount of cross-linking agent, the cross-linked structure of the NSs matrix can be controlled effectively. As PMDA βCD-NSs have emerged over the years as a highly versatile class of materials with potential applications in various fields, this study represents the first step towards a full understanding of the correlation between their structure and properties, which is a key requirement to effectively tune their synthesis reaction in view of any specific future application or industrial scale-up.

The Cross-linking of Cellulose and its Derivatives

2008 ◽  
Vol 77 (11) ◽  
pp. 543-547 ◽  
Author(s):  
W. M. Corbett ◽  
J. E. McKay
Keyword(s):  
Cross Linking ◽  
The Cross
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