scholarly journals Self-Sorting of Bidispersed Colloidal Particles Near Contact Line of an Evaporating Sessile Droplet

Langmuir ◽  
2018 ◽  
Vol 34 (40) ◽  
pp. 12058-12070 ◽  
Author(s):  
Nagesh D. Patil ◽  
Rajneesh Bhardwaj ◽  
Atul Sharma
2011 ◽  
Vol 11 (2) ◽  
pp. 138-142 ◽  
Author(s):  
David M. Kaz ◽  
Ryan McGorty ◽  
Madhav Mani ◽  
Michael P. Brenner ◽  
Vinothan N. Manoharan

2020 ◽  
Vol 142 (9) ◽  
Author(s):  
Tianyi Li ◽  
Aravinda Kar ◽  
Ranganathan Kumar

Abstract Particle transport through Marangoni convection inside a sessile droplet can be controlled by the ultraviolet (UV) light distribution on the surface. The photosensitive solution changes the surface tension gradient on the droplet surface and can induce clockwise and counterclockwise circulations depending on the incident light distribution. In this paper, the stream function in the sessile drop has been evaluated in toroidal coordinates by solving the biharmonic equation. Multiple primary clockwise and counterclockwise circulations are observed in the droplet under various concentric UV light profiles. The downward dividing streamlines are expected to deposit the particles on the substrate, thus matching the number of deposited rings on the substrate with the number of UV light rings. Moffatt eddies appear near the contact line or centerline of the droplet depending on the UV light profile and its distance from the contact line.


Nanoscale ◽  
2022 ◽  
Author(s):  
Yongfeng Huang ◽  
Cui Zhang ◽  
Sheng Meng

By analyzing the behaviors of water molecules at the solid–water–vapor contact line, we explore the molecular origins of large evaporation rates at the contact line and find new ways to...


Author(s):  
Gui-Ping Zhu ◽  
Kian-Soo Ong ◽  
Karen Siew-Ling Chong ◽  
Hu-Lin Huang ◽  
Fei Duan

The wetting, spreading and drying of pure liquid and nanofluid sessile droplets on a patterned solid surface were investigated systematically in terms of liquid and surface property. The patterned nickel surface was characterized with diamond, circular, hexagon and rectangular pillars. The size ratio between interval and pillars varies from 1.0 to 5.0. The study was firstly carried out for the effect of pure water droplet size on liquid spreading and droplet evaporation process on diamond-shape micro structured substrate with LInterval/LPillar=1.0. Larger amount of liquid leads to a larger wetting area. With fixed substrate (diamond, LInterval/LPillar=1.0) and droplet size (1 μm), mixture of DI water and Ethanol (volume ratio varies from 0.5 to 2.0) was used for generating droplets with different surface tension and evaporation coefficient. Fingering shape would generate on the contact line. With higher concentration of ethanol, the fingering effect is stronger and appeared in a shorter time. The contact area shrinks when increase the size ratio of interval and pillar. This would reduce the length of the contact line, and thus slow down the liquid evaporation. The role of pillar shape was examined based on time for complete evaporation. The effect of surface material on evaporation process was conducted on nickel and PMMA substrate fabricated with the same design. Additionally, investigations were conducted with solutions consisted with nanoparticles and DI water. The mixture were made at different weight ration to achieve concentration of nanoparticles varies from 0.02% to 0.18% with an interval at 0.04%.


2014 ◽  
Vol 760 ◽  
pp. 5-38 ◽  
Author(s):  
J. B. Bostwick ◽  
P. H. Steen

AbstractA sessile droplet partially wets a planar solid support. We study the linear stability of this spherical-cap base state to disturbances whose three-phase contact line is (i) pinned, (ii) moves with fixed contact angle and (iii) moves with a contact angle that is a smooth function of the contact-line speed. The governing hydrodynamic equations for inviscid motions are reduced to a functional eigenvalue problem on linear operators, which are parameterized by the base-state volume through the static contact angle and contact-line mobility via a spreading parameter. A solution is facilitated using inverse operators for disturbances (i) and (ii) to report frequencies and modal shapes identified by a polar $k$ and azimuthal $l$ wavenumber. For the dynamic contact-line condition (iii), we show that the disturbance energy balance takes the form of a damped-harmonic oscillator with ‘Davis dissipation’ that encompasses the dynamic effects associated with (iii). The effect of the contact-line motion on the dissipation mechanism is illustrated. We report an instability of the super-hemispherical base states with mobile contact lines (ii) that correlates with horizontal motion of the centre-of-mass, called the ‘walking’ instability. Davis dissipation from the dynamic contact-line condition (iii) can suppress the instability. The remainder of the spectrum exhibits oscillatory behaviour. For the hemispherical base state with mobile contact line (ii), the spectrum is degenerate with respect to the azimuthal wavenumber. We show that varying either the base-state volume or contact-line mobility lifts this degeneracy. For most values of these symmetry-breaking parameters, a certain spectral ordering of frequencies is maintained. However, because certain modes are more strongly influenced by the support than others, there are instances of additional modal degeneracies. We explain the physical reason for these and show how to locate them.


2010 ◽  
Vol 132 (2) ◽  
Author(s):  
S. Biswas ◽  
S. Gawande ◽  
V. Bromberg ◽  
Y. Sun

Using fluorescence microscopy, the inkjet deposition dynamics of monodispersed polystyrene particles in the size range of 0.02–1.1 μm have been studied on glass, Ar plasma cleaned glass, and PDMS coated glass substrates. The results show that the substrate properties play an important role in determining the final dried patterns formed by the colloidal particles. Our observations also reveal that particle size and contact angle formed by the solvent in the dispersion determine how close to the contact line the particles can be deposited. It is found that smaller particles can move closer to the deposited contact line than particles with bigger sizes. This study can serve as a realistic experimental model system for a number of fundamental queries on how the final deposition microstructure depends on the ink formulation and substrate properties. The knowledge obtained here can be explored further to optimize process parameters for the fabrication of hybrid solar cells with improved morphology and device properties.


2021 ◽  
Vol 542 ◽  
pp. 148611
Author(s):  
Bo Hou ◽  
Chunya Wu ◽  
Xiguang Li ◽  
Junjie Huang ◽  
Mingjun Chen

RSC Advances ◽  
2014 ◽  
Vol 4 (67) ◽  
pp. 35649-35652 ◽  
Author(s):  
Jun Wu ◽  
Jun Xia ◽  
Wei Lei ◽  
Bao-ping Wang

The evolution of the “local triple-phase contact line” with increasing droplet volume on a micropillared superhydrophobic surface, from (a) the initial contacting stage to (b) the pinning stage to (c) the depinning stage. (d) The sketch of the evolutionary process of local contact angles.


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