Formation of LiF Surface Layer During Direct Fluorination of High-Capacity Co-Free Disordered Rocksalt Cathodes

2021 ◽  
Author(s):  
Yiman Zhang ◽  
Ethan C. Self ◽  
Bishnu P. Thapaliya ◽  
Raynald Giovine ◽  
Harry M. Meyer ◽  
...  
Keyword(s):  
Surface Layer ◽  
High Capacity ◽  
Direct Fluorination

scholarly journals Cover Feature: Synthesizing High‐Capacity Oxyfluoride Conversion Anodes by Direct Fluorination of Molybdenum Dioxide (MoO 2 ) (ChemSusChem 15/2020)

ChemSusChem ◽  
2020 ◽  
Vol 13 (15) ◽  
pp. 3727-3727
Author(s):  
Bishnu P. Thapaliya ◽  
Ethan C. Self ◽  
Charl J. Jafta ◽  
Albina Y. Borisevich ◽  
Harry M. Meyer ◽  
...  
Keyword(s):  
High Capacity ◽  
Molybdenum Dioxide ◽  
Direct Fluorination

scholarly journals Synthesizing High‐Capacity Oxyfluoride Conversion Anodes by Direct Fluorination of Molybdenum Dioxide (MoO 2 )

ChemSusChem ◽  
2020 ◽  
Vol 13 (15) ◽  
pp. 3825-3834
Author(s):  
Bishnu P. Thapaliya ◽  
Ethan C. Self ◽  
Charl J. Jafta ◽  
Albina Y. Borisevich ◽  
Harry M. Meyer ◽  
...  
Keyword(s):  
High Capacity ◽  
Molybdenum Dioxide ◽  
Direct Fluorination

A New Type of Protective Surface Layer for High-Capacity Ni-Based Cathode Materials: Nanoscaled Surface Pillaring Layer

Nano Letters ◽  
2013 ◽  
Vol 13 (3) ◽  
pp. 1145-1152 ◽  
Author(s):  
Yonghyun Cho ◽  
Pilgun Oh ◽  
Jaephil Cho
Keyword(s):  
Surface Layer ◽  
Cathode Materials ◽  
High Capacity ◽  
New Type

Controlled Formation of Mixed Nanoscale Domains of High Capacity Fe2O3–FeF3 Conversion Compounds by Direct Fluorination

ACS Nano ◽  
2015 ◽  
Vol 9 (3) ◽  
pp. 2530-2539 ◽  
Author(s):  
Hui Zhou ◽  
Rose E. Ruther ◽  
Jamie Adcock ◽  
Wu Zhou ◽  
Sheng Dai ◽  
...  
Keyword(s):  
High Capacity ◽  
Direct Fluorination

scholarly journals Innovative Method of Treating Sintered Metal Powders Surfaces with Optical Radiation Pulses, Using Gas-Discharge Lamp

2020 ◽  
Vol 71 (9) ◽  
pp. 162-171
Author(s):  
Ioan Virca ◽  
Ghita Barsan ◽  
Constantin Bungau ◽  
Danut Mosteanu ◽  
Simona Bungau ◽  
...  
Keyword(s):  
Surface Layer ◽  
Alternative Energy ◽  
Radiant Energy ◽  
High Capacity ◽  
Gas Discharge ◽  
Energy Sources ◽  
Powder Materials ◽  
Metal Powders ◽  
High Voltage Power Supply ◽  
Discharge Lamp

The research conducted in the present paper is part of a comprehensive study to innovate a method of surface treatment for some metallic powder materials with alternative energy sources to lasers and electron beams (i.e. with gas-discharge lamp (GDL)), typically used as sources of optical pumping for the lasers, having a solid active element. The radiant energy sources used for study are composed of a GDL and the high voltage power supply consists of a block of high-capacity capacitors. The materials were selected from the Fe-Cu-C grade, with a carbon content between 0.5 to 0.72%, and the measurements were made on microscopes with electron beam scanning. Configurational modifications of a surface layer of approximatively 30-35 im, characteristic for Fe-C-Cu alloys, containing nearly 0.7% C (pearlite, ferrite and cementite) are highlighted by the microscopic examinations. At the surface level, the energy flux created by the lamp in the visible spectrum, generates pressure, determining elongation of the surface layer pores, under optical action, resulting an effect comparable to plastic deformation by induration or compaction through mechanical actions. The results obtained highlight the potential of this class of materials to surface treatments and the options for the energy sources used.

The oxidation of Inconel alloy MA754 at low oxidation potential

1983 ◽  
Vol 41 ◽  
pp. 218-219
Author(s):  
D. N. Braski ◽  
P. D. Goodell ◽  
J. V. Cathcart ◽  
R. H. Kane
Keyword(s):  
Surface Layer ◽  
Oxidation Potential ◽  
Metal Interface ◽  
Elevated Temperature Strength ◽  
Surface Conditions ◽  
Inconel Alloy ◽  
Inco Alloy ◽  
Resistance To Oxidation ◽  
Oxide Particles ◽  
Cold Worked

It has been known for some time that the addition of small oxide particles to an 80 Ni—20 Cr alloy not only increases its elevated-temperature strength, but also markedly improves its resistance to oxidation. The mechanism by which the oxide dispersoid enhances the oxidation resistance is being studied collaboratively by ORNL and INCO Alloy Products Company.Initial experiments were performed using INCONEL alloy MA754, which is nominally: 78 Ni, 20 Cr, 0.05 C, 0.3 Al, 0.5 Ti, 1.0 Fe, and 0.6 Y2O3 (wt %).Small disks (3 mm diam × 0.38 mm thick) were cut from MA754 plate stock and prepared with two different surface conditions. The first was prepared by mechanically polishing one side of a disk through 0.5 μm diamond on a syntron polisher while the second used an additional sulfuric acid-methanol electropolishing treatment to remove the cold-worked surface layer. Disks having both surface treatments were oxidized in a radiantly heated furnace for 30 s at 1000°C. Three different environments were investigated: hydrogen with nominal dew points of 0°C, —25°C, and —55°C. The oxide particles and films were examined in TEM by using extraction replicas (carbon) and by backpolishing to the oxide/metal interface. The particles were analyzed by EDS and SAD.

Structural analysis of the surface-layer protein of spirillum serpens by high-resolution electron microscopy

1983 ◽  
Vol 41 ◽  
pp. 738-739
Author(s):  
W. H. Wu ◽  
R. M. Glaeser
Keyword(s):  
Electron Microscopy ◽  
Surface Layer ◽  
Structural Analysis ◽  
High Resolution ◽  
Low Dose ◽  
High Resolution Electron Microscopy ◽  
Optical Diffraction ◽  
Surface Layer Protein ◽  
Morphological Unit ◽  
Resolution Electron

Spirillum serpens possesses a surface layer protein which exhibits a regular hexagonal packing of the morphological subunits. A morphological model of the structure of the protein has been proposed at a resolution of about 25 Å, in which the morphological unit might be described as having the appearance of a flared-out, hollow cylinder with six ÅspokesÅ at the flared end. In order to understand the detailed association of the macromolecules, it is necessary to do a high resolution structural analysis. Large, single layered arrays of the surface layer protein have been obtained for this purpose by means of extensive heating in high CaCl2, a procedure derived from that of Buckmire and Murray. Low dose, low temperature electron microscopy has been applied to the large arrays.As a first step, the samples were negatively stained with neutralized phosphotungstic acid, and the specimens were imaged at 40,000 magnification by use of a high resolution cold stage on a JE0L 100B. Low dose images were recorded with exposures of 7-9 electrons/Å2. The micrographs obtained (Fig. 1) were examined by use of optical diffraction (Fig. 2) to tell what areas were especially well ordered.

Electron-Mirror Microscopic Aspects of Ferroelectric Domains of BaTiO3 And Ca2Sr (C2H5CO2)6

1970 ◽  
Vol 28 ◽  
pp. 478-479
Author(s):  
Teruo Someya ◽  
Jinzo Kobayashi
Keyword(s):  
Surface Layer ◽  
Electric Fields ◽  
Quantitative Study ◽  
Recent Progress ◽  
Ferroelectric Domain ◽  
Resolving Power ◽  
Surface Pattern ◽  
Crystal Surfaces ◽  
One Dimensional ◽  
Ferroelectric Domains

Recent progress in the electron-mirror microscopy (EMM), e.g., an improvement of its resolving power together with an increase of the magnification makes it useful for investigating the ferroelectric domain physics. English has recently observed the domain texture in the surface layer of BaTiO3. The present authors ) have developed a theory by which one can evaluate small one-dimensional electric fields and/or topographic step heights in the crystal surfaces from their EMM pictures. This theory was applied to a quantitative study of the surface pattern of BaTiO3).

Microstructure of Electro-Eroded Cemented Carbide Surfaces

1968 ◽  
Vol 26 ◽  
pp. 284-285
Author(s):  
V. N. Filimonenko ◽  
M. H. Richman ◽  
J. Gurland
Keyword(s):  
Surface Layer ◽  
Cobalt Content ◽  
Cemented Carbides ◽  
Face Centered Cubic ◽  
X Ray Diffraction ◽  
Metallographic Examination ◽  
Standard Procedures ◽  
Face Centered ◽  
Diamond Paste ◽  
Plastic Carbon

The high temperatures and pressures that are found in a spark gap during electrical discharging lead to a sharp phase transition and structural transformation in the surface layer of cemented carbides containing WC and cobalt. By means of X-ray diffraction both W2C and a high-temperature monocarbide of tungsten (face-centered cubic) were detected after electro-erosion. The W2C forms as a result of the peritectic reaction, WC → W2C+C. The existence and amount of the phases depend on both the energy of the electro-spark discharge and the cobalt content. In the case of a low-energy discharge (i.e. C=0.01μF, V = 300v), WC(f.c.c.) is generally formed in the surface layer. However, at high energies, (e.g. C=30μF, V = 300v), W2C is formed at the surface in preference to the monocarbide. The phase transformations in the surface layer are retarded by the presence of larger percentages of cobalt.Metallographic examination of the electro-eroded surfaces of cemented carbides was carried out on samples with 5-30% cobalt content. The specimens were first metallographically polished using diamond paste and standard procedures and then subjected to various electrical discharges on a Servomet spark machining device. The samples were then repolished and etched in a 3% NH4OH electrolyte at -0.5 amp/cm2. Two stage plastic-carbon replicas were then made and shadowed with chromium at 27°.

The concerted use of SEM, TEM, and SCM for examination of resin-dentin interfaces

1994 ◽  
Vol 52 ◽  
pp. 476-477
Author(s):  
B. Van Meerbeek ◽  
L. J. Conn ◽  
E. S. Duke
Keyword(s):  
Surface Layer ◽  
Stress Distribution ◽  
Phosphoric Acid ◽  
Bonding Mechanism ◽  
Restorative Dentistry ◽  
Dental Adhesive ◽  
Low Viscosity ◽  
Dentin Adhesives ◽  
Acid Etch ◽  
Tooth Tissue

Restoration of decayed teeth with tooth-colored materials that can be bonded to tooth tissue has been a highly desirable property in restorative dentistry for many years. Advantages of such an adhesive restorative technique over conventional techniques using non-adhesive metal-based restoratives include improved restoration retention with minimal sacrifice of sound tooth tissue for retention purposes, superior adaptation and sealing of the restoration margins in prevention of caries recurrence, improved stress distribution across the tooth-restoration interface throughout the whole tooth, and even reinforcement of weakened tooth structures. The dental adhesive technology is rapidly changing. An efficient resin bond to enamel has already long been achieved. Its bonding mechanism has been fully elucidated and has proven to be a durable and reliable clinical treatment. However, bonding to dentin represents a greater challenge. After the failures of a dentin acid-etch technique in imitation of the enamel phosphoric-acid-etch technique and a bonding procedure based on chemical adhesion, modern dentin adhesives are currently believed to bond to dentin by a micromechanical hybridization process. This process is developed by an initial demineralization of the dentin surface layer with acid etchants exposing a collagen fibril arrangement with interfibrillar microporosities that subsequently become impregnated by low-viscosity monomers. Although the development of such a hybridization process has well been documented in the literature, questions remain with respect to parameters of-primary importance to adhesive efficacy.

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