Na2BaMgP2O8phosphors were synthesized by a standard solid state reaction and their luminescent properties were investigated. The phase structure was analyzed by X-ray powder diffraction measurement. Under the excitation of 365nm, Na2BaMgP2O8:Tb3+, Eu3+phosphors show two color bands of green and red color due to5D4−7F5transition of Tb3+ions and5D0−7F2transition of Eu3+ions, respectively. The emission intensity of Tb3+deceased with the increasing concentration of Eu3+, which verified that an effective energy transfer occurred from Tb3+to Eu3+in Na2BaMgP2O8host. The present study indicated that the phosphors have a high potential application in solid state lighting.