Highly Thermally Conductive Fluorinated Graphene Films with Superior Electrical Insulation and Mechanical Flexibility

2019 ◽  
Vol 11 (24) ◽  
pp. 21946-21954 ◽  
Author(s):  
Xiongwei Wang ◽  
Peiyi Wu
Keyword(s):  
Electrical Insulation ◽  
Graphene Films ◽  
Thermally Conductive ◽  
Fluorinated Graphene

scholarly journals Ultralight, Ultraflexible, Anisotropic, Highly Thermally Conductive Graphene Aerogel Films

Molecules ◽  
2021 ◽  
Vol 26 (22) ◽  
pp. 6867
Author(s):  
Zheng Liu ◽  
Qinsheng Wang ◽  
Linlin Hou ◽  
Yingjun Liu ◽  
Zheng Li
Keyword(s):  
Thermal Conductivity ◽  
Expansion Method ◽  
Graphene Aerogel ◽  
3D Graphene ◽  
Graphene Layers ◽  
Thermal Insulating ◽  
Graphene Films ◽  
High Anisotropy ◽  
Thermally Conductive ◽  
Aerogel Films

Graphene aerogels have attracted much attention as a promising material for various applications. The unusually high intrinsic thermal conductivity of individual graphene sheets makes an obvious contrast with the thermal insulating performance of assembled 3D graphene materials. We report the preparation of anisotropy 3D graphene aerogel films (GAFs) made from tightly packed graphene films using a thermal expansion method. GAFs with different thicknesses and an ultimate low density of 4.19 mg cm−3 were obtained. GAFs show high anisotropy on average cross-plane thermal conductivity (K⊥) and average in-plane thermal conductivity (K||). Additionally, uniaxially compressed GAFs performed a large elongation of 11.76% due to the Z-shape folding of graphene layers. Our results reveal the ultralight, ultraflexible, highly thermally conductive, anisotropy GAFs, as well as the fundamental evolution of macroscopic assembled graphene materials at elevated temperature.

scholarly journals Enhanced thermal conductivity of graphene nanoplatelets epoxy composites

2017 ◽  
Vol 35 (2) ◽  
pp. 382-389 ◽  
Author(s):  
Lukasz Jarosinski ◽  
Andrzej Rybak ◽  
Karolina Gaska ◽  
Grzegorz Kmita ◽  
Renata Porebska ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Heat Dissipation ◽  
Electronic Devices ◽  
Graphene Nanoplatelets ◽  
Electrical Insulation ◽  
Graphene Nanocomposites ◽  
Thermally Conductive ◽  
Conductive Particles ◽  
Proper Performance ◽  
Enhanced Thermal Conductivity

Abstract Efficient heat dissipation from modern electronic devices is a key issue for their proper performance. An important role in the assembly of electronic devices is played by polymers, due to their simple application and easiness of processing. The thermal conductivity of pure polymers is relatively low and addition of thermally conductive particles into polymer matrix is the method to enhance the overall thermal conductivity of the composite. The aim of the presented work is to examine a possibility of increasing the thermal conductivity of the filled epoxy resin systems, applicable for electrical insulation, by the use of composites filled with graphene nanoplatelets. It is remarkable that the addition of only 4 wt.% of graphene could lead to 132 % increase in thermal conductivity. In this study, several new aspects of graphene composites such as sedimentation effects or temperature dependence of thermal conductivity have been presented. The thermal conductivity results were also compared with the newest model. The obtained results show potential for application of the graphene nanocomposites for electrical insulation with enhanced thermal conductivity. This paper also presents and discusses the unique temperature dependencies of thermal conductivity in a wide temperature range, significant for full understanding thermal transport mechanisms.

scholarly journals Thermally Conductive and Electrical Insulation BNNS/CNF Aerogel Nano-Paper

Polymers ◽  
2019 ◽  
Vol 11 (4) ◽  
pp. 660 ◽  
Author(s):  
Wang ◽  
Yu ◽  
Bian ◽  
Wu ◽  
Xiao ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Volume Resistivity ◽  
Electrical Insulation ◽  
Heat Conducting ◽  
Working Process ◽  
Safety Issues ◽  
Blending Method ◽  
Thermally Conductive ◽  
Electrical Insulation Materials ◽  
Insulation Performance

Adding heat conducting particles to a polymer matrix to prepare thermally conductive and electrical insulation materials is an effective approach to address the safety issues arising from the accumulation of heat in the working process of electronic devices. In this work, thermally conductive and electrical insulation nano-paper, consisting of Boron Nitride nano-sheet (BNNS) and cellulose nanofiber (CNF), was prepared using an aerogel 3D skeleton template method. For comparison, BNNS/CNF nano-paper was also produced using a simple blending method. At a BNNS loading of 50 wt%, the thermal conductivity of BNNS/CNF aerogel nano-paper and blended nano-paper at 70 °C are 2.4 W/mK and 1.2 W/mK respectively, revealing an increase of 94.4%. Under similar conditions, the volume resistivity of BNNS/CNF aerogel nano-paper and blended nano-paper are 4.0 × 1014 and 4.2 × 1014 Ω·cm respectively. In view of its excellent thermal conductivity and electrical insulation performance, therefore, BNNS/CNF aerogel nano-paper holds great potential for electronic-related applications.

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