scholarly journals Design and Synthesis of Core–Shell Carbon Polymer Dots with Highly Stable Fluorescence in Polymeric Materials

2019 ◽  
Vol 2 (10) ◽  
pp. 6503-6512 ◽  
Author(s):  
Yuan Yu ◽  
Peixin Tang ◽  
Bogdan Barnych ◽  
Cunyi Zhao ◽  
Gang Sun ◽  
...  
Polymers ◽  
2018 ◽  
Vol 10 (10) ◽  
pp. 1084
Author(s):  
Kaimin Chen ◽  
Lan Cao ◽  
Ying Zhang ◽  
Kai Li ◽  
Xue Qin ◽  
...  

Stimuli-responsive nanoparticles are among the most popular research topics. In this study, two types of core-shell (polystyrene with a photoiniferter (PSV) as the core and diblock as the shell) polymer brushes (PSV@PNIPA-b-PAA and PSV@PAA-b-PNIPA) were designed and prepared using surface-initiated photoiniferter-mediated polymerization (SI-PIMP). Moreover, their pH- and temperature-stimuli responses were explored by dynamic light scattering (DLS) and turbidimeter under various conditions. The results showed that the conformational change was determined on the basis of the competition among electrostatic repulsion, hydrophobic interaction, hydrogen bonding, and steric hindrance, which was also confirmed by protein adsorption experiments. These results are not only helpful for the design and synthesis of stimuli-responsive polymer brushes but also shed light on controlled protein immobilization under mild conditions.


2009 ◽  
Vol 48 (20) ◽  
pp. 9723-9731 ◽  
Author(s):  
Wenjin Zhang ◽  
Guanjiao Chen ◽  
Jian Wang ◽  
Bang-Ce Ye ◽  
Xinhua Zhong

MRS Advances ◽  
2020 ◽  
Vol 5 (40-41) ◽  
pp. 2121-2127
Author(s):  
Ssu-Hao Huang ◽  
Pei-Hua Chen ◽  
Yan-Ping Chen ◽  
Muoi Tang

ABSTRACTThe polymerization of 3,4-ethylenedioxythiophene (EDOT) onto nanosilica (SiO2) was synthesized in this study by using supercritical carbon dioxide (SCCO2). With the addition of dopants of p-toluenesulfonic acid (p-TSA) or decylbenzene sulfonic acid (DBSA), the PEDOT/SiO2 composite became conductive. The product was characterized by FTIR spectroscopy and the core-shell structure was confirmed through the TEM images. The electrical properties were analyzed by UV-vis absorbance and four-point probe measurement. DBSA is shown as the better dopants with the molar ratio (DBSA/EDOT) of 0.2 at the reaction time of 48 hours. The maximum coating percentage is 63 wt% under the optimal operation conditions at 40oC and 280 bar. The conductivity is tuned up to 6.6×10-2 S/cm after the coating process.


2020 ◽  
Vol 11 (2) ◽  
pp. 315-325 ◽  
Author(s):  
Sabine Schneider ◽  
Falco Jung ◽  
Olga Mergel ◽  
Janik Lammertz ◽  
Anne C. Nickel ◽  
...  

Modelling and synthesis go hand in hand to efficiently engineer copolymer microgels with various architectures: core–shell structures (with ferrocene mainly in the core or in the shell) and also microgels with homogeneous comonomer distribution.


1988 ◽  
Vol 25 (5-7) ◽  
pp. 555-570 ◽  
Author(s):  
Yukio Imanish ◽  
Yoshihiro Ito ◽  
Lin-Shu Liu ◽  
Masako Kajihara

The Analyst ◽  
2019 ◽  
Vol 144 (24) ◽  
pp. 7368-7377 ◽  
Author(s):  
Hui-Hui Zeng ◽  
Zhi-Ying Zhou ◽  
Fang Liu ◽  
Jie Deng ◽  
Shu-Yun Huang ◽  
...  

YVO4:Eu3+@CDs core–shell nanomaterial was synthesized through a simple self-assembly of carbon dots (CDs) with YVO4:Eu3+, since the high affinity of oxygen-containing groups such as –COOH or –OH of CDs to the metal ions on the surface of YVO4:Eu3+.


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