Sample Concentration Affects Optical Gain Results in Colloidal Nanomaterials: Circumventing the Distortions by Below Band Gap Excitation

ACS Photonics ◽  
2021 ◽  
Author(s):  
Gabriel Nagamine ◽  
Tomas A. C. Ferreira ◽  
Diogo B. Almeida ◽  
Jonathan C. Lemus ◽  
Jun Hyuk Chang ◽  
...  
2020 ◽  
Vol 101 (7) ◽  
Author(s):  
L. Meckbach ◽  
J. Hader ◽  
U. Huttner ◽  
J. Neuhaus ◽  
J. T. Steiner ◽  
...  
Keyword(s):  
Band Gap ◽  

2013 ◽  
Vol 205-206 ◽  
pp. 394-399
Author(s):  
Yan Cai ◽  
Jurgen Michel

We review two ex-situ doping methods to achieve high n-type doping up to mid-1019 cm-3 in Ge-on-Si thin films. For both, delta doping and ion implantation, rapid thermal annealing is used to diffuse phosphorus from a diffusion source into the single crystal Ge layer. The diffusion mechanism is studied and we find that dopant enhanced diffusion in in-situ doped Ge attributes to the high doping level. A band gap narrowing effect is observed in highly doped n-type Ge through photoluminescence measurements by determining the photoluminescence peak shift. An empirical linear expression of the direct band gap narrowing shift with carrier concentration is proposed.


1983 ◽  
Vol 52 (2) ◽  
pp. 677-685 ◽  
Author(s):  
Shosaku Tanaka ◽  
Takaaki Kuwata ◽  
Takehiro Hokimoto ◽  
Hiroshi Kobayashi ◽  
Hiroshi Saito

2015 ◽  
Vol 1107 ◽  
pp. 308-313
Author(s):  
Sib Krishna Ghoshal ◽  
M.R. Sahar ◽  
R. Arifin ◽  
M.S. Rohani ◽  
K. Hamzah

Tuning the visible emission of Si nanomaterials by modifying their size and shape is one of the key issue in optoelectronics. The observed optical gain in Si-nanoclusters (NCs) has given further impulse to nanosilicon research. We develop a phenomenological model by combining the effects of surface passivation, exciton states and quantum confinement (QC). The size and passivation dependent band gap, oscillator strength, radiative lifetime and photoluminescence (PL) intensity for NCs with diameter ranging from 1.0 to 6.0 nm are presented. By controlling a set of fitting parameters, it is possible to tune the optical band gap, PL peak and intensity. In case of pure clusters, the band gap is found to decrease with increasing NC size. Furthermore, the band gap increases on passivating the surface of the cluster with hydrogen and oxygen respectively in which the effect of oxygen is more robust. Both QC and surface passivation in addition to exciton effects determine the optical and electronic properties of silicon NCs. Visible luminescence is due to radiative recombination of electrons and holes in the quantum-confined NCs. The role of surface states on the band gap as well as on the HOMO-LUMO states is also examined and a correlation is established. Our results are in conformity with other observations. The model can be extended to study the light emission from other nanostructures and may contribute towards the development of Si based optoelectronics.


1992 ◽  
Vol 117 (1-4) ◽  
pp. 732-737 ◽  
Author(s):  
Y. Masumoto ◽  
B. Fluegel ◽  
K. Meissner ◽  
S.W. Koch ◽  
R. Binder ◽  
...  
Keyword(s):  
Band Gap ◽  

Author(s):  
Joanna L. Batstone

Interest in II-VI semiconductors centres around optoelectronic device applications. The wide band gap II-VI semiconductors such as ZnS, ZnSe and ZnTe have been used in lasers and electroluminescent displays yielding room temperature blue luminescence. The narrow gap II-VI semiconductors such as CdTe and HgxCd1-x Te are currently used for infrared detectors, where the band gap can be varied continuously by changing the alloy composition x.Two major sources of precipitation can be identified in II-VI materials; (i) dopant introduction leading to local variations in concentration and subsequent precipitation and (ii) Te precipitation in ZnTe, CdTe and HgCdTe due to native point defects which arise from problems associated with stoichiometry control during crystal growth. Precipitation is observed in both bulk crystal growth and epitaxial growth and is frequently associated with segregation and precipitation at dislocations and grain boundaries. Precipitation has been observed using transmission electron microscopy (TEM) which is sensitive to local strain fields around inclusions.


Author(s):  
J.M. Bonar ◽  
R. Hull ◽  
R. Malik ◽  
R. Ryan ◽  
J.F. Walker

In this study we have examined a series of strained heteropeitaxial GaAs/InGaAs/GaAs and InGaAs/GaAs structures, both on (001) GaAs substrates. These heterostructures are potentially very interesting from a device standpoint because of improved band gap properties (InAs has a much smaller band gap than GaAs so there is a large band offset at the InGaAs/GaAs interface), and because of the much higher mobility of InAs. However, there is a 7.2% lattice mismatch between InAs and GaAs, so an InxGa1-xAs layer in a GaAs structure with even relatively low x will have a large amount of strain, and misfit dislocations are expected to form above some critical thickness. We attempt here to correlate the effect of misfit dislocations on the electronic properties of this material.The samples we examined consisted of 200Å InxGa1-xAs layered in a hetero-junction bipolar transistor (HBT) structure (InxGa1-xAs on top of a (001) GaAs buffer, followed by more GaAs, then a layer of AlGaAs and a GaAs cap), and a series consisting of a 200Å layer of InxGa1-xAs on a (001) GaAs substrate.


Sign in / Sign up

Export Citation Format

Share Document