Simple, Fast, and Accurate In silico Estimations of Contact Angle, Surface Tension, and Work of Adhesion of Water and Oil Nanodroplets on Amorphous Polypropylene Surfaces

2012 ◽  
Vol 4 (6) ◽  
pp. 2855-2859 ◽  
Author(s):  
Daniel Romero Nieto ◽  
Francesca Santese ◽  
Radovan Toth ◽  
Paola Posocco ◽  
Sabrina Pricl ◽  
...  
Keyword(s):  
Surface Tension ◽  
Contact Angle ◽  
In Silico ◽  
Work Of Adhesion

scholarly journals Oil Adjuvants Enhance the Efficacy of Pyraclostrobin in Managing Cucumber Powdery Mildew (Podosphaera xanthii) by Modifying the Affinity of Fungicide Droplets on Diseased Leaves

Plant Disease ◽  
2019 ◽  
Vol 103 (7) ◽  
pp. 1657-1664
Author(s):  
Lifei He ◽  
Xiaoxu Li ◽  
Yangyang Gao ◽  
Beixing Li ◽  
Wei Mu ◽  
...  
Keyword(s):  
Surface Tension ◽  
Contact Angle ◽  
Powdery Mildew ◽  
Field Experiments ◽  
Plant Diseases ◽  
Work Of Adhesion ◽  
Podosphaera Xanthii ◽  
Effective Strategy ◽  
Cucumber Powdery Mildew ◽  
Fungicide Mixtures

Adding adjuvants improved the affinity of fungicide droplets to cucumber leaves infected with powdery mildew (Podosphaera xanthii) and subsequent efficacy of fungicide treatments in reducing the disease. The affinity of oil adjuvants was quantified by adhesional tension and “work of adhesion”. Oil adjuvant-fungicide mixtures were applied to plants in field experiments to evaluate their effectiveness in disease prevention. Both the adhesional tension and work of adhesion of the adjuvants at selected concentrations increased on powdery-mildew-infected cucumber leaves more than on healthy cucumber leaves. The adjuvant GY-Tmax (GYT) displayed the best surface activity or “surfactivity” in enhancing the affinity and adherence of droplets to powdery-mildew-infected cucumber leaves, while epoxidized soybean oil (ESO), methyl oleate, and biodiesel exhibited much lower effects in terms of the surface tension, contact angle, adhesional tension, and work of adhesion. Field experiments determined that the combination of GYT at 1,000 mg liter−1 and pyraclostrobin (150 g a.i. ha−1) was most effective (91.52%) in controlling cucumber powdery mildew. Pyraclostrobin with ESO was also highly effective (ranging from 77.54 to 89.65%). The addition of oil adjuvants, especially GYT and ESO, to fungicide applications can be an effective strategy to enhance the efficacy of pesticides in controlling plant diseases by modifying the affinity of fungicide droplets to symptomatic leaves.

Ring distraction technique for measuring surface tension of sputum: relationship to sputum clearability

1996 ◽  
Vol 81 (6) ◽  
pp. 2690-2695 ◽  
Author(s):  
G. M. Albers ◽  
R. P. Tomkiewicz ◽  
M. K. May ◽  
O. E. Ramirez ◽  
B. K. Rubin
Keyword(s):  
Surface Tension ◽  
Contact Angle ◽  
Work Of Adhesion ◽  
Small Samples ◽  
Low Surface Energy ◽  
Measuring Surface ◽  
Significant Difference ◽  
Ring Method ◽  
Young Equation ◽  
Made In

Albers, G. M., R. P. Tomkiewicz, M. K. May, O. E. Ramirez, and B. K. Rubin. Ring distraction technique for measuring surface tension of sputum: relationship to sputum clearability. J. Appl. Physiol. 81(6): 2690–2695, 1996.—Poor sputum clearance has been related to sputum adhesion tension. In this study, we describe a modified du Noüy ring method for measuring the surface tension (γ) of small samples of sputum and for comparinge the calculated work of adhesion (Wad) for sputum specimens with the measured mucociliary transportability (MCTR) and cough transportability (CTR). The γ, as measured by this method, correlates with γ measured by sputum contact angle on a low-surface-energy solid ( R 2= 0.368, P = 0.03). There is a small but significant difference in measurements made by these two methods ( P = 0.03). Wad calculated from the surface tension ring method is inversely correlated with CTR ( R 2= 0.181, P = 0.004) but has no correlation with MCTR in this study. The miniaturized ring method gives accurate and reproducible measurements of the surface tension of small amounts of respiratory secretions. Because sputum behaves enough like a liquid that the assumptions made in using the Young equation to calculate Wad appear valid, we also showed that the Neumann equation can be used to determine the surface tension of sputum by its contact angle on tetrafluoroethylene (Teflon).

scholarly journals Influence of moisture content on the contact angle and surface tension measured on birch wood surfaces

2021 ◽  
Author(s):  
Rami Benkreif ◽  
Fatima Zohra Brahmia ◽  
Csilla Csiha
Keyword(s):  
Surface Tension ◽  
Contact Angle ◽  
Moisture Content ◽  
Solid Wood ◽  
Contact Angles ◽  
Surface Moisture ◽  
Wood Coatings ◽  
The Relationship ◽  
Wood Surfaces

AbstractSurface tension of solid wood surfaces affects the wettability and thus the adhesion of various adhesives and wood coatings. By measuring the contact angle of the wood, the surface tension can be calculated based on the Young-Dupré equation. Several publications have reported on contact angle measured with different test liquids, under different conditions. Results can only be compared if the test conditions are similar. While the roles of the drop volume, image shooting time etc., are widely recognized, the role of the wood surface moisture content (MC) is not evaluated in detail. In this study, the effect of wood moisture content on contact angle values, measured with distilled water and diiodomethane, on sanded birch (Betula pendula) surfaces was investigated, in order to find the relationship between them. With increasing MC from approximately 6% to 30%, increasing contact angle (decreasing surface tension) values were measured according to a logarithmic function. The function makes possible the calculation of contact angles that correspond to different MCs.

Increasing Storage Modulus, Contact Angle and Surface Tension of Airway Mucus Increases Clearance by Simulated Cough Through a Model Trachea

2010 ◽  
Author(s):  
Anpalaki J. Ragavan ◽  
Cahit A. Evrensel ◽  
Peter Krumpe
Keyword(s):  
Surface Tension ◽  
Contact Angle ◽  
Storage Modulus ◽  
Surface Properties ◽  
Respiratory Diseases ◽  
Interactive Effects ◽  
Altered Surface ◽  
Human Trachea ◽  
Tension Increase ◽  
And Storage

Altered surface and viscoelastic material properties of mucus during respiratory diseases have a strong influence on its clearance by cilia and cough. Combined effects of the surface properties (contact angle and surface tension) and storage modulus with relatively unchanged viscosity on displacement of the simulated mucus aliquot during simulated cough through a model adult human trachea is investigated. For the mucus simulants used in this study contact angle and surface tension increase significantly as storage modulus increase while viscosity remains practically unchanged. Displacement of mucus simulant aliquots increased significantly with increasing storage modulus (and contact angle) at a given cough velocity in the range between 5 meters/second (m/s) and 30 m/s with duration 0.3 s. Results suggest that the interactive effects of elasticity and surface properties may help facilitate mucus displacement at low cough velocities.

scholarly journals Experimental Investigation of Coal Dust Wettability Based on Surface Contact Angle

2016 ◽  
Vol 2016 ◽  
pp. 1-8 ◽  
Author(s):  
Gang Zhou ◽  
Han Qiu ◽  
Qi Zhang ◽  
Mao Xu ◽  
Jiayuan Wang ◽  
...  
Keyword(s):  
Surface Tension ◽  
Contact Angle ◽  
Specific Surface ◽  
Coal Dust ◽  
Single Point ◽  
Contact Angles ◽  
Critical Surface ◽  
Volume Percentage ◽  
Surface Areas ◽  
Specific Surface Areas

Wettability is one of the key chemical properties of coal dust, which is very important to dedusting. In this paper, the theory of liquid wetting solid was presented firstly; then, taking the gas coal of Xinglongzhuang coal mine in China as an example, by determination of critical surface tension of coal piece, it can be concluded that only when the surface tension of surfactant solution is less than 45 mN/m can the coal sample be fully wetted. Due to the effect of particle dispersity, compared with the contact angle of milled coal particle, not all the contact angles of screened coal powder with different sizes have a tendency to increase. Furthermore, by the experiments of coal samples’ specific surface areas and porosities, it can be achieved that the volume of single-point total pore decreases with the gradual decreasing of coal’s porosity, while the ultramicropores’ dispersities and multipoint BET specific surface areas increase. Besides, by a series of contact angle experiments with different surfactants, it can be found that with the increasing of porosity and the decreasing of volume percentage of ultramicropore, the contact angle tends to reduce gradually and the coal dust is much easier to get wetted.

scholarly journals Effect of Pesticide Addition Sequence on the Preparation of Phytosanitary Spray Solutions

2019 ◽  
Vol 37 ◽  
Author(s):  
M.F.T. RAMOS ◽  
R.T.S. SANTOS ◽  
D.P. ALMEIDA ◽  
J.F.D. VECHIA ◽  
M.C. FERREIRA
Keyword(s):  
Surface Tension ◽  
Contact Angle ◽  
Propionic Acid ◽  
Biological Effect ◽  
Surface Coverage ◽  
Mineral Oil ◽  
Application Rate ◽  
Physicochemical Interactions ◽  
Effect Of Treatment ◽  
Droplet Method

ABSTRACT: The addition of adjuvants to herbicide solutions is aimed at preserving or enhancing the biological effect of treatment. However, it is commonly performed without knowledge of the physicochemical interactions between products. This study aimed to assess the effects of different addition sequences of the herbicide aminopyralid + fluroxypyr and adjuvants in the preparation of phytosanitary spray solutions on the surface tension and contact angle. Two experiments were carried out with herbicide doses of 1 and 2 L ha-1 associated with the adjuvants mineral oil (MO), silicone-polyether copolymer (SIL), and a mixture of phosphatidylcholine (lectin) and propionic acid (LEC), all at a proportion of 0.3% v v-1. The application rate was 150 L ha-1. Surface tension was measured by the pendant droplet method. Contact angle was measured on the adaxial and abaxial surfaces of leaves of the pasture weed Senna obtusifolia and parafilm. Preparation sequence did not change the contact angle on any of the analyzed surfaces at a dose of 1 L ha-1 of herbicide. For the dose of 2 L ha-1, the adjuvants SIL and LEC showed a higher spreading when previously added to the herbicide. MO resulted in a higher spreading when added after the herbicide, with higher surface coverage. Therefore, the preparation sequence influences the dispersion of phytosanitary spray solutions on targets.

Relationship between Work of Adhesion and Contact Angle Hysteresis on Superhydrophobic Surfaces

2008 ◽  
Vol 112 (30) ◽  
pp. 11403-11407 ◽  
Author(s):  
Yonghao Xiu ◽  
Lingbo Zhu ◽  
Dennis W. Hess ◽  
C. P. Wong
Keyword(s):  
Contact Angle ◽  
Contact Angle Hysteresis ◽  
Superhydrophobic Surfaces ◽  
Work Of Adhesion
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