Effect of Binders on the Flow Behavior of a Paper Coating Suspension over a Wide Range of Shear Rates

2002 ◽  
Vol 41 (10) ◽  
pp. 2399-2404
Author(s):  
Mamdouh T. Ghannam
Keyword(s):  
Flow Behavior ◽  
Paper Coating ◽  
Shear Rates ◽  
Wide Range ◽  
Coating Suspension

Rheology of Plastisols of Poly(Vinyl Chloride)

1979 ◽  
Vol 52 (3) ◽  
pp. 676-691 ◽  
Author(s):  
E. A. Collins ◽  
D. J. Hoffmann ◽  
P. L. Soni
Keyword(s):  
Flow Behavior ◽  
Basic Mechanism ◽  
Particle Sizes ◽  
Solvent Interaction ◽  
Factors Affecting ◽  
Shear Rates ◽  
Wide Range ◽  
Size Of Particles ◽  
Increasing Temperature ◽  
Future Work

Abstract The viscosity of PVC plastisols is seen to be affected by numerous variables. Increase in concentration of the resin causes the viscosity to rise, with the increase being more abrupt at the higher concentrations. Deviation from Newtonian behavior also increases with concentration. Decrease in the size of particles results in an increase in viscosity, the effect being more pronounced at low shear rates. Broadening the distribution of particle sizes results in a decrease in viscosity. Porous particles yield plastisols with higher viscosity as compared to nonporous compact particles. The type of plasticizer also affects the viscosity. A plasticizer which is a better solvent for PVC (low value of polymer-solvent interaction parameter, χ) results in a higher viscosity due to an increase in the amount of dissolved polymer. Additives such as alcohols and soaps affect the viscosity in an, as yet, unknown way. Fillers, heat stabilizers, and pigments also increase the viscosity. With increasing temperature, the viscosity first decreases, passes through a minimum and then increases until gelation. With further rise in temperature the viscosity again decreases and then levels out before degradation occurs. In future work, particular emphasis needs to be given to the understanding of the basic mechanism involved in the effect of additives on the flow behavior. Systematic experiments with a range of well-defined particle sizes and over a wide range of shear rates are also needed. A better understanding of the factors affecting the behavior of plastisols will go a long way in changing the art of plastisol formulation to a science.

Nonnewtonian Flow of Poly(Dimethyl Siloxane)

1967 ◽  
Vol 40 (5) ◽  
pp. 1483-1491
Author(s):  
Yoshio Ito
Keyword(s):  
Shear Rate ◽  
Polymer Solutions ◽  
Flow Behavior ◽  
Degree Of Polymerization ◽  
High Shear ◽  
Newtonian Viscosity ◽  
Shear Rates ◽  
Molecular Weights ◽  
Dimethyl Siloxane ◽  
Wide Range

Abstract Nonnewtonian flow of poly(dimethyl siloxanes) of various molecular weights has been studied with a short capillary viscosimeter. The experiment covered a wide range of shear rate, from 10−1 to 3×106sec−1. Results were as follows: (1) Flow behavior of the sample changes with the degree of polymerization. For siloxanes with degrees of polymerization less than 1.55×102, flow of the fluid is newtonian throughout the whole range of shear rates; for siloxanes with degrees of polymerization from 3.22×102 to 2.63×103, flow is nonnewtonian at moderate shear rates; it again becomes newtonian at high shear rates. With degrees of polymerization more than 3.31×103, the spiral flow rises to a high shear rate. (2) Plow behavior of the samples is expressed by modifying Shishido's equation proposed for nonnewtonian polymer solutions. (3) When the observed flow curve contains its inflection point, the upper newtonian viscosity can be estimated by a new method proposed here. (4) The relations among the end correction of capillary, the pressure loss, and the shear stress proposed by Shishido for polymer solutions are applicable to poly(dimethy! siloxane) also.

Experimental and theoretical investigations on the viscosity of heterogeneous asphalt binders

2017 ◽  
Vol 50 (4) ◽  
pp. 354-371 ◽  
Author(s):  
Aboelkasim Diab
Keyword(s):  
Flow Behavior ◽  
Ethylene Vinyl Acetate ◽  
Hydrated Lime ◽  
Crumb Rubber ◽  
Asphalt Binders ◽  
Zero Shear Viscosity ◽  
Shear Rates ◽  
Wide Range ◽  
Theoretical Investigations ◽  
Pavement Construction

The inherent multiphase structure of heterogeneous asphalt binders (additives containing binders) may complicate viscosity understanding and predictions in the Newtonian or non-Newtonian response. The objective of this article is to understand the viscosity characteristics of heterogeneous asphalt binders based on experimental and theoretical investigations over a wide range of conditions the matter may encounter in the field (temperatures and oxidative aging). Selected materials representing the generic additives commonly used for pavement construction including styrene–butadiene–styrene block copolymer and ethylene–vinyl acetate copolymer, crumb rubber, and two mineral fillers, namely hydrated lime and fly ash, were utilized separately at different concentrations to produce the heterogeneous materials under study. The effects of varied temperatures as well as short- and long-term aging processes were studied for the materials over a wide range of shear rates. A further theoretical investigation was carried out by addressing the capability of Tscheuschner model to predict the flow behavior under the aforementioned conditions. In addition, the zero shear viscosity said to be an intrinsic characteristic of asphalt binders was evaluated using the regression analysis of data predicted from Tscheuschner model. Overall, the shear thinning behavior of heterogeneous asphalt binders occurred at low shear rates as compared to the base binder, especially at low temperatures. Emphasis was placed on the repeatability of the model predictions under different conditions, which could be an initiative to provide a simple but accurate representation of the viscosity of heterogeneous asphalt binders.

scholarly journals Non-Newtonian Patient-specific Simulations of Left Atrial Hemodynamics

2021 ◽  
Author(s):  
Alejandro Gonzalo ◽  
Manuel Garcia-Villalba ◽  
Lorenzo Rossini ◽  
Eduardo Duran ◽  
David Vigneault ◽  
...  
Keyword(s):  
Blood Flow ◽  
Left Atrial ◽  
Flow Behavior ◽  
Blood Rheology ◽  
Patient Specific ◽  
Shear Rates ◽  
Wide Range ◽  
History Of ◽  
Slow Blood Flow ◽  
Cell Aggregations

Atrial fibrillation (AF) is the most common arrhythmia, affecting ~35M people worldwide. The irregular beating of the left atrial (LA) caused by AF impacts the LA hemodynamics increasing the risk of thrombosis and ischemic stroke. Most LA thrombi appear in its appendage (LAA), a narrow sac of varied morphology where blood is prone to stagnate. In the LAA, the combination of slow blood flow and low shear rates (<100 [1/s]) promotes the formation of red blood cell aggregations called rouleaux. Blood experiences a non-Newtonian behavior when rouleaux formed that has not been considered in previous CFD analysis of the LA. We model the anatomy and motion of the LA from 4D-CT images and solve the blood flow inside the LA geometry with our CFD in-house code, which models Non-Newtonian rheology with the shear-hematocrit-dependent Carreau-Yasuda equation. We cover a wide range of non-Newtonian effects considering a small and a large hematocrit, including an additional constitutive relation to account for themrouleaux formation time, and we compare our results with Newtonian simulations. Blood rheology influence in LAA hemostasis is studied in 6 patient-specific anatomies. Two subjects had an LAA thrombus (digitally removed before running the simulations), another had a history of TIAs, and the remaining three had normal atrial function. In our simulations, the shear rate remains below 50 [1/s] in the LAA for all non-Newtonian models considered. This triggers an increase of viscosity that alters the flow behavior in that site, which exhibits different flow patterns than Newtonian simulations. These hemodynamic changes translate into differences in the LAA hemostasis, calculated with the residence time.

URBAN FACADE GEOMETRY ON OUTDOOR COMFORT CONDITIONS: A REVIEW

2020 ◽  
Vol 4 (1) ◽  
pp. 45
Author(s):  
Elahe Mirabi ◽  
Nasrollahi Nazanin
Keyword(s):  
Thermal Comfort ◽  
Urban Areas ◽  
Natural Ventilation ◽  
Flow Behavior ◽  
Air Flow ◽  
Urban Geometry ◽  
Wide Range ◽  
Low Energy Buildings ◽  
Outdoor Comfort ◽  
Solar Access

<p>Designing urban facades is considered as a major factor influencing issues<br />such as natural ventilation of buildings and urban areas, radiations in the<br />urban canyon for designing low-energy buildings, cooling demand for<br />buildings in urban area, and thermal comfort in urban streets. However, so<br />far, most studies on urban topics have been focused on flat facades<br />without details of urban layouts. Hence, the effect of urban facades with<br />details such as the balcony and corbelling on thermal comfort conditions<br />and air flow behavior are discussed in this literature review. <strong>Aim</strong>: This<br />study was carried out to investigate the effective factors of urban facades,<br />including the effects of building configuration, geometry and urban<br />canyon’s orientation. <strong>Methodology and Results</strong>: According to the results,<br />the air flow behavior is affected by a wide range of factors such as wind<br />conditions, urban geometry and wind direction. Urban façade geometry<br />can change outdoor air flow pattern, thermal comfort and solar access.<br /><strong>Conclusion, significance and impact study</strong>: In particular, the geometry of<br />the facade, such as indentation and protrusion, has a significant effect on<br />the air flow and thermal behavior in urban facades and can enhance<br />outdoor comfort conditions. Also, Alternation in façade geometry can<br />affect pedestrians' comfort and buildings energy demands.</p>

VISCOSITY OF NATURAL RUBBER SOLUTIONS AT VERY LOW RATES OF SHEAR

1957 ◽  
Vol 35 (4) ◽  
pp. 381-387 ◽  
Author(s):  
Morton A. Golub
Keyword(s):  
Experimental Data ◽  
Natural Rubber ◽  
Pressure Head ◽  
Viscosity Data ◽  
Theoretical Relation ◽  
Newtonian Flow ◽  
Shear Rates ◽  
Reduced Viscosity ◽  
Wide Range ◽  
Composite Data

The shear dependence of viscosity of benzene solutions of natural rubber was studied at rates of shear from about 500 down to less than 1 sec.−1. Measurements involved following the change of pressure head with time of the various solutions flowing in a capillary, U-tube viscometer. Curvature in the plots of the logarithm of pressure head versus time indicated non-Newtonian flow. From such curves, reduced viscosity data over the above-mentioned shear range were readily derived. As a check, data over the range 100–500 sec.−1 were also obtained with a five-bulb viscometer of the Krigbaum–Flory type, and these data overlapped those obtained with the U tube. The reduced viscosity increased very sharply with decrease in gradient, making extrapolation to the viscosity axis quite unreliable. However, a theoretical relation proposed by Bueche fitted the composite data rather well. This work furnished a nice technique for determining the zero shear reduced viscosity (ηap/c)0 without the necessity of performing an uncertain extrapolation: evaluate the parameters of the Bueche formula which best satisfies the experimental data over a fairly wide range of shear rates, and then calculate (ηap/c)0 directly.

Study of Gas Flow in Micronozzles Using an Unstructured DSMC Method

2009 ◽  
Author(s):  
Ehsan Roohi ◽  
Masoud Darbandi ◽  
Vahid Mirjalili
Keyword(s):  
Boundary Layer ◽  
Knudsen Number ◽  
Gas Flow ◽  
Subsonic Flow ◽  
Flow Behavior ◽  
Boundary Layer Separation ◽  
Back Pressure ◽  
Viscous Force ◽  
Dsmc Method ◽  
Wide Range

The current research uses an unstructured direct simulation Monte Carlo (DSMC) method to numerically investigate supersonic and subsonic flow behavior in micro convergent–divergent nozzle over a wide range of rarefied regimes. The current unstructured DSMC solver has been suitably modified via using uniform distribution of particles, employing proper subcell geometry, and benefiting from an advanced molecular tracking algorithm. Using this solver, we study the effects of back pressure, gas/surface interactions (diffuse/specular reflections), and Knudsen number, on the flow field in micronozzles. We show that high viscous force manifesting in boundary layers prevents supersonic flow formation in the divergent section of nozzles as soon as the Knudsen number increases above a moderate magnitude. In order to accurately simulate subsonic flow at the nozzle outlet, it is necessary to add a buffer zone to the end of nozzle. If we apply the back pressure at the outlet, boundary layer separation is observed and a region of backward flow appears inside the boundary layer while the core region of inviscid flow experiences multiple shock-expansion waves. We also show that the wall boundary layer prevents forming shocks in the divergent part. Alternatively, Mach cores appear at the nozzle center followed by bow shocks and an expansion region.

Prediction of High Viscosity Liquid/Gas Two-Phase Slug Length in Horizontal and Slightly Inclined Pipelines

2021 ◽  
Author(s):  
Omar Shaaban ◽  
Eissa Al-Safran
Keyword(s):  
Numerical Optimization ◽  
Flow Behavior ◽  
Mechanistic Model ◽  
High Viscosity ◽  
Oil Well ◽  
Liquid Slug ◽  
Two Phase ◽  
Proposed Model ◽  
Wide Range ◽  
Flow Closure

Abstract The production and transportation of high viscosity liquid/gas two-phase along petroleum production system is a challenging operation due to the lack of understanding the flow behavior and characteristics. In particular, accurate prediction of two-phase slug length in pipes is crucial to efficiently operate and safely design oil well and separation facilities. The objective of this study is to develop a mechanistic model to predict high viscosity liquid slug length in pipelines and to optimize the proper set of closure relationships required to ensure high accuracy prediction. A large high viscosity liquid slug length database is collected and presented in this study, against which the proposed model is validated and compared with other models. A mechanistic slug length model is derived based on the first principles of mass and momentum balances over a two-phase slug unit, which requires a set of closure relationships of other slug characteristics. To select the proper set of closure relationships, a numerical optimization is carried out using a large slug length dataset to minimize the prediction error. Thousands of combinations of various slug flow closure relationships were evaluated to identify the most appropriate relationships for the proposed slug length model under high viscosity slug length condition. Results show that the proposed slug length mechanistic model is applicable for a wide range of liquid viscosities and is sensitive to the selected closure relationships. Results revealed that the optimum closure relationships combination is Archibong-Eso et al. (2018) for slug frequency, Malnes (1983) for slug liquid holdup, Jeyachandra et al. (2012) for drift velocity, and Nicklin et al. (1962) for the distribution coefficient. Using the above set of closure relationships, model validation yields 37.8% absolute average percent error, outperforming all existing slug length models.

NUMERICAL ANALYSIS OF FLOW BEHAVIOR IN GAS-LIQUID CYLINDRICAL CYCLONE (GLCC©*) SEPARATORS WITH INLET DESIGN MODIFICATIONS

2021 ◽  
pp. 1-27
Author(s):  
Srinivas Swaroop Kolla ◽  
Ram S. Mohan ◽  
Ovadia Shoham
Keyword(s):  
Numerical Study ◽  
Flow Behavior ◽  
Low Cost ◽  
Field Application ◽  
Attractive Alternative ◽  
Inlet Section ◽  
Wide Range ◽  
Cylindrical Cyclone ◽  
Light Oil ◽  
Section Design

Abstract The Gas-Liquid Cylindrical Cyclone (GLCC©*) is a simple, compact and low-cost separator, which provides an economically attractive alternative to conventional gravity-based separators over a wide range of applications. More than 6,500 GLCC©'s have been installed in the field to date around the world over the past 2 decades. The GLCC© inlet section design is a key parameter, which is crucial for its performance and proper operation. The flow behavior in the GLCC© body is highly dependent on the fluid velocities generated at the reduced area nozzle inlet. An earlier study (Kolla et al. [1]) recommended design modifications to the inlet section, based on safety and structural robustness. It is important to ensure that these proposed configuration modifications do not adversely affect the flow behavior at the inlet and the overall performance of the GLCC©. This paper presents a numerical study utilizing specific GLCC© field application working under 3 different case studies representing the flow entering the GLCC, separating light oil, steam flooded wells in Minas, Indonesia. Commercially available Computational Fluid Dynamics (CFD) software is utilized to analyze the hydrodynamics of flow with the proposed modifications of the inlet section for GLCC© field applications.

Rheo-Optics Studies in the Development of Hybrid Liquid Crystalline Based Mwir Polarizers

1999 ◽  
Vol 559 ◽  
Author(s):  
P.T. Mather ◽  
W. Barnes ◽  
P.J. Hood ◽  
T.J. Bunning
Keyword(s):  
Liquid Crystalline ◽  
Flow Behavior ◽  
Optical Microscope ◽  
Processing Technique ◽  
Strain Rates ◽  
Alignment Layer ◽  
Small Pitch ◽  
Wide Range ◽  
Measured Polarization ◽  
Free Films

ABSTRACTWe present here a rheo-optical study of the flow behavior of two cholesteric liquid crystals, one with a large pitch and one with a small pitch. The large pitch compound has been investigated as a possible fixed wavelength polarizer in the mid-wavelength infra-red region (3-5 micron). The investigation of these compounds is driven by their low melt viscosity and ability to vitrify order, and thus functionality, into films with a wide range of thickness. In our attempts to obtain consistent thin films with reproducible contrast ratios, we explored the defect textures of both compounds under a polarizing optical microscope. These materials were sheared at various strain rates and at various temperatures in an attempt to determine the best processing window for defect free films. The pitch lengths of the two materials investigated were 160 and 1330 nm. The flow behavior of the large pitch material resembles a pure nematic with defect refinement taking place under flow. The short pitch material exhibited the typical Grandjean oily streaks upon shearing followed by coarsening. Observations made during this rheological study were used to identify a processing technique for the large pitch materials. Upon application of a conventional buffed alignment layer, films with consistent quality were routinely made. The measured polarization contrast of >70:1 exceeds the values obtained from state-of-the art commercial polarizers in this wavelength regime.

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