Surface Area Development within Artificial Graphite Rods Reacted with Carbon Dioxide from 900° to 1300° C.

1955 ◽  
Vol 47 (8) ◽  
pp. 1629-1630 ◽  
Author(s):  
E. E. Peterson ◽  
P. L. Walker ◽  
C. C. Wright
Molecules ◽  
2021 ◽  
Vol 26 (7) ◽  
pp. 1962
Author(s):  
Mahboubeh Nabavinia ◽  
Baishali Kanjilal ◽  
Noahiro Fujinuma ◽  
Amos Mugweru ◽  
Iman Noshadi

To address the issue of global warming and climate change issues, recent research efforts have highlighted opportunities for capturing and electrochemically converting carbon dioxide (CO2). Despite metal doped polymers receiving widespread attention in this respect, the structures hitherto reported lack in ease of synthesis with scale up feasibility. In this study, a series of mesoporous metal-doped polymers (MRFs) with tunable metal functionality and hierarchical porosity were successfully synthesized using a one-step copolymerization of resorcinol and formaldehyde with Polyethyleneimine (PEI) under solvothermal conditions. The effect of PEI and metal doping concentrations were observed on physical properties and adsorption results. The results confirmed the role of PEI on the mesoporosity of the polymer networks and high surface area in addition to enhanced CO2 capture capacity. The resulting Cobalt doped material shows excellent thermal stability and promising CO2 capture performance, with equilibrium adsorption of 2.3 mmol CO2/g at 0 °C and 1 bar for at a surface area 675.62 m2/g. This mesoporous polymer, with its ease of synthesis is a promising candidate for promising for CO2 capture and possible subsequent electrochemical conversion.


2019 ◽  
Vol 10 (33) ◽  
pp. 4611-4620 ◽  
Author(s):  
Ningning Song ◽  
Tianjiao Wang ◽  
Hongyan Yao ◽  
Tengning Ma ◽  
Kaixiang Shi ◽  
...  

Microporous polyimide networks with high surface area and excellent CO2 adsorption performance have been constructed based on cross-linkable linear polyimides through crosslinking reaction.


1962 ◽  
Vol 202 (1) ◽  
pp. 53-58 ◽  
Author(s):  
Hugh D. Van Liew

Uptake rate of a gas from a rat's subcutaneous gas pocket was divided by the surface area and by the apparent pocket-to-tissue tension difference to yield an exchange coefficient, K'. Values in (ml x 10–4)/(min cm2 atm) were O2, 6.6; CO2, 150; and N2, 2. Blood flow in adjacent tissue appeared to have little influence on uptakes of O2 and CO2, since the K'co2:K'o2 ratio indicated that the uptakes were governed by diffusion alone, and drastic alteration of blood flow (death of the animal) decreased K'o2 by only 10%. In contrast, blood flow apparently affected N2 uptake. Because O2 and CO2 uptakes were not blood flow limited, K'o2 and K'co2 are estimates of true permeability coefficients; the calculated permeability coefficient for N2 is 3.3 (ml x 10–4)/(min cm2 atm). Comparison shows the pocket surface to be 1/50–1/150 as effective for O2 transfer as the lung. Finally, corrections are calculated for pocket-to-tissue pO2 and pCO2 differences in gas pockets used for tissue tonometry.


2018 ◽  
Vol 42 (22) ◽  
pp. 18242-18251 ◽  
Author(s):  
Mona Al-Dossary ◽  
Harihara Padhy ◽  
Feng Xu ◽  
Ali R. Behzad ◽  
Omar el Tall ◽  
...  

Dicarboxylate spacer ligands enhanced the rigidity, porosity, surface area, and CO2/N2 and CO2/CH4 selectivity of Cu2+-based poly(methyl vinyl ether-alt-maleic anhydride) hydrogels.


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