Supermacroporous polydivinylbenzene cryogels with high surface area: Synthesis by solvothermal postcrosslinking and their adsorption behaviors for carbon dioxide and aniline

2019 ◽  
Vol 136 (27) ◽  
pp. 47716 ◽  
Author(s):  
Fenghao Guo ◽  
Yinping Wang ◽  
Xilu Chen ◽  
Mingqian Chen ◽  
Wei He ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Surface Area ◽  
High Surface ◽  
High Surface Area ◽  
Adsorption Behaviors

scholarly journals Developing Eco-Friendly and Cost-Effective Porous Adsorbent for Carbon Dioxide Capture

Molecules ◽  
2021 ◽  
Vol 26 (7) ◽  
pp. 1962
Author(s):  
Mahboubeh Nabavinia ◽  
Baishali Kanjilal ◽  
Noahiro Fujinuma ◽  
Amos Mugweru ◽  
Iman Noshadi
Keyword(s):  
Carbon Dioxide ◽  
Surface Area ◽  
Co2 Capture ◽  
High Surface ◽  
Scale Up ◽  
Polymer Networks ◽  
High Surface Area ◽  
Excellent Thermal Stability ◽  
Doped Polymers ◽  
Metal Doped

To address the issue of global warming and climate change issues, recent research efforts have highlighted opportunities for capturing and electrochemically converting carbon dioxide (CO2). Despite metal doped polymers receiving widespread attention in this respect, the structures hitherto reported lack in ease of synthesis with scale up feasibility. In this study, a series of mesoporous metal-doped polymers (MRFs) with tunable metal functionality and hierarchical porosity were successfully synthesized using a one-step copolymerization of resorcinol and formaldehyde with Polyethyleneimine (PEI) under solvothermal conditions. The effect of PEI and metal doping concentrations were observed on physical properties and adsorption results. The results confirmed the role of PEI on the mesoporosity of the polymer networks and high surface area in addition to enhanced CO2 capture capacity. The resulting Cobalt doped material shows excellent thermal stability and promising CO2 capture performance, with equilibrium adsorption of 2.3 mmol CO2/g at 0 °C and 1 bar for at a surface area 675.62 m2/g. This mesoporous polymer, with its ease of synthesis is a promising candidate for promising for CO2 capture and possible subsequent electrochemical conversion.

Construction and carbon dioxide capture of microporous polymer networks with high surface area based on cross-linkable linear polyimides

2019 ◽  
Vol 10 (33) ◽  
pp. 4611-4620 ◽  
Author(s):  
Ningning Song ◽  
Tianjiao Wang ◽  
Hongyan Yao ◽  
Tengning Ma ◽  
Kaixiang Shi ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Surface Area ◽  
Carbon Dioxide Capture ◽  
High Surface ◽  
Polymer Networks ◽  
High Surface Area ◽  
Crosslinking Reaction ◽  
Adsorption Performance ◽  
Microporous Polymer

Microporous polyimide networks with high surface area and excellent CO2 adsorption performance have been constructed based on cross-linkable linear polyimides through crosslinking reaction.

One-Pot Procedure to Synthesize High Surface Area Alumina Nanofibers Using Supercritical Carbon Dioxide

Langmuir ◽  
2010 ◽  
Vol 26 (4) ◽  
pp. 2707-2713 ◽  
Author(s):  
Muhammad B. I. Chowdhury ◽  
Rouhong Sui ◽  
Rahima A. Lucky ◽  
Paul A. Charpentier
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Surface Area ◽  
High Surface ◽  
High Surface Area ◽  
One Pot ◽  
Alumina Nanofibers ◽  
Supercritical Carbon

scholarly journals Carbon Dioxide Adsorption via Ultra-High Surface Area Carbon

2019 ◽  
Author(s):  
Yudhisthira Sahoo
Keyword(s):  
Carbon Dioxide ◽  
Surface Area ◽  
High Surface ◽  
High Surface Area ◽  
Carbon Dioxide Adsorption

scholarly journals Design of high surface area poly(ionic liquid)s to convert carbon dioxide into ethylene carbonate

2015 ◽  
Vol 3 (16) ◽  
pp. 8508-8518 ◽  
Author(s):  
Alessandro Dani ◽  
Elena Groppo ◽  
Claudia Barolo ◽  
Jenny G. Vitillo ◽  
Silvia Bordiga
Keyword(s):  
Carbon Dioxide ◽  
Ionic Liquid ◽  
Surface Area ◽  
Ethylene Carbonate ◽  
High Surface ◽  
High Surface Area ◽  
Poly Ionic Liquid

In situ FTIR monitoring of the evolution of ethylene carbonate catalyzed by a designed high surface area poly(ionic liquid).

Asphalt-Derived High Surface Area Activated Porous Carbons for Carbon Dioxide Capture

2015 ◽  
Vol 7 (2) ◽  
pp. 1376-1382 ◽  
Author(s):  
Almaz S. Jalilov ◽  
Gedeng Ruan ◽  
Chih-Chau Hwang ◽  
Desmond E. Schipper ◽  
Josiah J. Tour ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Surface Area ◽  
Carbon Dioxide Capture ◽  
High Surface ◽  
High Surface Area ◽  
Porous Carbons

scholarly journals Silicon oxycarbonitride ceramic containing nickel nanoparticles: from design to catalytic application

2021 ◽  
Author(s):  
Jun Wang ◽  
Albert Gili ◽  
Matthias Grünbacher ◽  
Sebastian Praetz ◽  
Jan Dirk Epping ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Surface Area ◽  
Methane Conversion ◽  
Nickel Nanoparticles ◽  
High Surface ◽  
High Surface Area ◽  
Catalytic Application ◽  
Silicon Oxycarbonitride ◽  
Ceramic Nanocomposites

We report the synthesis of Ni/SiOCN ceramic nanocomposites with high surface area as catalysts for carbon dioxide and methane conversion.

scholarly journals Synthesis and Characterization of Copper Impregnated Mesoporous Carbon as Heterogeneous Catalyst for Phenylacetylene Carboxylation with Carbon Dioxide

2020 ◽  
Vol 21 (1) ◽  
pp. 77
Author(s):  
Putri Nurul Amalia ◽  
Iman Abdullah ◽  
Dyah Utami Cahyaning Rahayu ◽  
Yuni Krisyuningsih Krisnandi
Keyword(s):  
Carbon Dioxide ◽  
Surface Area ◽  
Mesoporous Carbon ◽  
High Surface ◽  
High Surface Area ◽  
Bet Surface Area ◽  
Soft Template ◽  
Average Pore ◽  
Carbon Dioxide Co2

Carbon dioxide (CO2) is a compound that can potentially be used as a carbon source in the synthesis of fine chemicals. However, the utilization of CO2 is still constrained due to its inert and stable nature. Therefore, the presence of a catalyst is needed in CO2 conversion. This study aims to synthesize copper impregnated mesoporous carbon (Cu/MC) as a catalyst for phenylacetylene carboxylation reaction with CO2 to produce phenylpropiolic acid. The synthesis of mesoporous carbon was performed via the soft template method. The as-synthesized Cu/MC material was characterized by FTIR, SAA, XRD, and SEM-EDX. BET surface area analysis of mesoporous carbon showed that the material has a high surface area of 405.8 m2/g with an average pore diameter of 7.2 nm. XRD pattern of Cu/MC indicates that Cu has been successfully impregnated in the form of Cu(0) and Cu(I). Phenylacetylene carboxylation reaction with CO2 was carried out by varying reaction temperatures (25, 50, and 75 °C), amount of catalyst (28.6, 57.2, and 85.8 mg), type of base (Cs2CO3, K2CO3, and Na2CO3), and variation of support. The reaction mixtures were analyzed by HPLC and showed that the highest phenylacetylene conversion of 41% was obtained for the reaction at 75 °C using Cs2CO3 as a base.

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