Role of TEDA as an Activated Carbon Impregnant for the Removal of Cyanogen Chloride from Air Streams: Synergistic Effect with Cu(II)

2010 ◽  
Vol 114 (47) ◽  
pp. 20083-20090 ◽  
Author(s):  
John J. Mahle ◽  
Gregory W. Peterson ◽  
Bryan J. Schindler ◽  
Philip B. Smith ◽  
Joseph A. Rossin ◽  
...  

The authors' methodic for assessing the role of chemical and physic-chemical factors during the structure formation of gypsum stone is presented in the article. The methodic is also makes it possible to reveal the synergistic effect and to determine the ranges of variation of controls factors that ensure maximum values of such effect. The effect of a micro-sized modifier based on zinc hydro-silicates on the structure formation of building gypsum is analyzed and corresponding dependencies are found. It is shown that effects of influence of modifier on the properties of gypsum compositions are determined by chemical properties of modifier. Among the mentioned properties are sorption characteristics (which depend on the amount of silicic acid and its state) and physicochemical properties - the ability to act as a substrate during crystal formation. The proposed method can also be extended to other binding substances and materials. This article contributes to the understanding of the processes that occur during the structure formation of composites, which will make it possible to control the structure formation in the future, obtaining materials with a given set of properties.


2004 ◽  
Vol 4 (5-6) ◽  
pp. 21-28
Author(s):  
S.-C. Kim ◽  
D.-K. Lee

TiO2-coated granular activated carbon was employed for the removal of toxic microcystin-LR from water. High surface area of the activated carbon provided sites for the adsorption of microcystin-LR, and the adsorbed microcystin-LR migrated continuously onto the surface of TiO2 particles which located mainly at the exterior surface in the vicinity of the entrances of the macropores of the activated carbon. The migrated microcystin-LR was finally degraded into nontoxic products and CO2 very quickly. These combined roles of the activated carbon and TiO2 showed a synergistic effect on the efficient degradation of toxic microcystin-LR. A continuous flow fluidized bed reactor with the TiO2-coated activated carbon could successfully be employed for the efficient photocatalytic of microcystin-LR.


2021 ◽  
Author(s):  
Petar Djinović ◽  
Janez Zavašnik ◽  
Janvit Teržan ◽  
Ivan Jerman

AbstractCeO2, V2O5 and CeVO4 were synthesised as bulk oxides, or deposited over activated carbon, characterized by XRD, HRTEM, CO2-TPO, C3H8-TPR, DRIFTS and Raman techniques and tested in propane oxidative dehydrogenation using CO2. Complete oxidation of propane to CO and CO2 is favoured by lattice oxygen of CeO2. The temperature programmed experiments show the ~ 4 nm AC supported CeO2 crystallites become more susceptible to reduction by propane, but less prone to re-oxidation with CO2 compared to bulk CeO2. Catalytic activity of CeVO4/AC catalysts requires a 1–2 nm amorphous CeVO4 layer. During reaction, the amorphous CeVO4 layer crystallises and several atomic layers of carbon cover the CeVO4 surface, resulting in deactivation. During reaction, V2O5 is irreversibly reduced to V2O3. The lattice oxygen in bulk V2O5 favours catalytic activity and propene selectivity. Bulk V2O3 promotes only propane cracking with no propene selectivity. In VOx/AC materials, vanadium carbide is the catalytically active phase. Propane dehydrogenation over VC proceeds via chemisorbed oxygen species originating from the dissociated CO2. Graphic Abstract


2019 ◽  
Vol 5 (2) ◽  
pp. 383-396 ◽  
Author(s):  
Anna Patrícya Florentino ◽  
Ahmed Sharaf ◽  
Lei Zhang ◽  
Yang Liu

Methanogenesis and enrichment of microorganisms capable of interspecies electron and/or hydrogen exchange was investigated with addition of granular activated carbon (GAC) to batch anaerobic digesters treating vacuum collected blackwater with high ammonia concentration.


RSC Advances ◽  
2015 ◽  
Vol 5 (41) ◽  
pp. 32626-32636 ◽  
Author(s):  
Yaxin Li ◽  
Xian Zhang ◽  
Ruiguang Yang ◽  
Guiying Li ◽  
Changwei Hu
Keyword(s):  

H3PO4promoted the decomposition of some species to form CO2and reacted with PBTRHR to form PH3.


2014 ◽  
Vol 486 ◽  
pp. 159-169 ◽  
Author(s):  
Pankaj Raizada ◽  
Pardeep Singh ◽  
Amit Kumar ◽  
Gaurav Sharma ◽  
Brijesh Pare ◽  
...  

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