Does photomineralization of dissolved organics matter in temperate rivers?

Author(s):  
Taylor Maavara ◽  
Laura Logozzo ◽  
Aron Stubbins ◽  
Kelly Aho ◽  
Craig Brinkerhoff ◽  
...  
Keyword(s):  
1973 ◽  
Vol 8 (1) ◽  
pp. 1-15 ◽  
Author(s):  
L.A. Addie ◽  
K.L. Murphy ◽  
J.L. Robertson

Abstract The importance of removing the small amounts of residual organics is increasing as the sources of clean surface water decrease. Knowledge of the nature of these soluble residual organics will be needed in order to assess the type of treatment required for their removal. Residual organics in three different biological treatment plants were analyzed and compared. An attempt was made to characterize these organics by a molecular size distribution on a Sephadex column monitored by differential ultraviolet and refractive index detectors. The organic carbon and chemical oxygen demand of the fractions collected from the column was also determined. An investigation of some of the problems inherent in the monitoring systems was conducted.


2012 ◽  
Vol 9 (8) ◽  
pp. 11885-11924 ◽  
Author(s):  
J. Czerny ◽  
K. G. Schulz ◽  
T. Boxhammer ◽  
R. G. J. Bellerby ◽  
J. Büdenbender ◽  
...  

Abstract. Recent studies on the impacts of ocean acidification on pelagic communities have identified changes in carbon to nutrient dynamics with related shifts in elemental stoichiometry. In principle, mesocosm experiments provide the opportunity of determining the temporal dynamics of all relevant carbon and nutrient pools and, thus, calculating elemental budgets. In practice, attempts to budget mesocosm enclosures are often hampered by uncertainties in some of the measured pools and fluxes, in particular due to uncertainties in constraining air/sea gas exchange, particle sinking, and wall growth. In an Arctic mesocosm study on ocean acidification using KOSMOS (Kiel Off-Shore Mesocosms for future Ocean Simulation) all relevant element pools and fluxes of carbon, nitrogen and phosphorus were measured, using an improved experimental design intended to narrow down some of the mentioned uncertainties. Water column concentrations of particulate and dissolved organic and inorganic constituents were determined daily. New approaches for quantitative estimates of material sinking to the bottom of the mesocosms and gas exchange in 48 h temporal resolution, as well as estimates of wall growth were developed to close the gaps in element budgets. Future elevated pCO2 was found to enhance net autotrophic community carbon uptake in 2 of the 3 experimental phases but did not significantly affect particle elemental composition. Enhanced carbon consumption appears to result in accumulation of dissolved organic compounds under nutrient recycling summer conditions. This carbon over-consumption effect becomes evident from budget calculations, but was too small to be resolved by direct measurements of dissolved organics. The out-competing of large diatoms by comparatively small algae in nutrient uptake caused reduced production rates under future ocean CO2 conditions in the end of the experiment. This CO2 induced shift away from diatoms towards smaller phytoplankton and enhanced cycling of dissolved organics was pushing the system towards a retention type food chain with overall negative effects on export potential.


1981 ◽  
Vol 36 (4) ◽  
pp. 743-757 ◽  
Author(s):  
W. Fritz ◽  
W. Merk ◽  
E.U. Schlünder

2019 ◽  
Vol 145 (3) ◽  
pp. 06019001
Author(s):  
Samuel D. Snow ◽  
Caroline E. L. LaRoy ◽  
Volodymyr V. Tarabara

2017 ◽  
Vol 36 (1-2) ◽  
pp. 327-342 ◽  
Author(s):  
Andrea Luca Tasca ◽  
Farnaz Ghajeri ◽  
Ashleigh J Fletcher

Very few studies have investigated the adsorption performance of hydrophobic and hydrophilic silicas with dissolved organics in water, which is a required final step during produced water treatment. The cost of functionalization also hinders the use of hydrophobic materials as sorbents. Novel hydrophilic silicas, prepared at low temperature and ambient pressure, were characterised by SEM, FTIR and BET analysis, and studied for the adsorption of aqueous phase organic compounds at concentrations below their solubility limits. Adsorption capacities were found to be up to 264 mg/g for benzene and 78.8 mg/g for toluene. Direct comparison is made with the analogous hydrophobic version of one of the silica materials, demonstrating comparable uptakes for benzene concentrations lower than 50 mg/L. This finding supports the hypothesis that, at very low aqueous phase organic concentrations, hydrophobicization has no discernible effect on access of the pollutants to the internal porosity of the material.


1979 ◽  
Vol 36 (2) ◽  
pp. 122-131 ◽  
Author(s):  
A. R. Coote ◽  
P. A. Yeats

The general pattern of nutrient distribution in the Gulf of St. Lawrence results from regeneration processes being superimposed on the physical processes of estuarine circulation within the Gulf. This leads to a general increase in nutrient concentration with depth and with distance into the Gulf from Cabot Strait. Nutrient concentrations in the Laurentian Channel are higher inside the Gulf than at equal or even greater depths in the Atlantic Ocean some distance outside Cabot Strait. Summer nutrient concentrations in the surface layer are generally low. However, during the winter when biological activity is low, quite high concentrations of the nutrients are found in the surface waters of the Gulf. A balance exists between inward and outward fluxes of all three nutrients through Cabot Strait in the winter. However, in the summer the influxes of both nitrate and silicate at Cabot Strait greatly exceed the outgoing fluxes. Losses of biogenic silica to the sediments may account for the silicate imbalance. Excess nitrate may be accounted for if ammonia or nitrogen bound with dissolved organics had been measured. Key words: nutrients, silicate, phosphate, nitrate, distribution, regeneration, transport, Gulf of St. Lawrence, Cabot Strait, Laurentian Channel


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