Ethylene polymerization on a SiH4-modified Phillips catalyst: detection of in situ produced α-olefins by operando FT-IR spectroscopy

2012 ◽  
Vol 14 (7) ◽  
pp. 2239 ◽  
Author(s):  
Caterina Barzan ◽  
Elena Groppo ◽  
Elsje Alessandra Quadrelli ◽  
Vincent Monteil ◽  
Silvia Bordiga
Keyword(s):  
Ir Spectroscopy ◽  
Ethylene Polymerization ◽  
Phillips Catalyst ◽  
Ft Ir ◽  
Ft Ir Spectroscopy

scholarly journals Monitoring the Interfacial Polymerization of Piperazine and Trimesoyl Chloride with Hydrophilic Interlayer or Macromolecular Additive by in-situ FT-IR Spectroscopy

2019 ◽  
Author(s):  
Xi Yang
Keyword(s):  
Ir Spectroscopy ◽  
Reaction Rate ◽  
Interfacial Polymerization ◽  
Reaction System ◽  
Reaction Rates ◽  
Water Permeation ◽  
Ft Ir ◽  
Trimesoyl Chloride ◽  
Ft Ir Spectroscopy

The interfacial polymerization (IP) of piperazine (PIP) and trimesoyl chloride (TMC) has been extensively utilized to synthesize the nanofiltration (NF) membrane. However, it is still a huge challenge to monitor the IP reaction, because of the fast reaction rate and the formed ultra-thin film. Herein, two effective strategies are applied to reduce the IP reaction rate: (1) the introduction of hydrophilic interlayers between the porous substrate and the formed polyamide layer; (2) the addition of macromolecular additives in the aqueous solution of PIP. As a result, in-situ FT-IR spectroscopy was firstly used to monitor the IP reaction of PIP/TMC reaction system, with hydrophilic interlayers or macromolecular additives. Moreover, we study the formed polyamide layer growth on the substrate, in a real-time manner. The in-situ FT-IR experimental results confirm that the IP reaction rates are effectively suppressed and the formed polyamide thickness reduces from 138±24 nm to 46±2 nm. Furthermore, the optimized NF membrane with excellent performance are consequently obtained, which include the boosted water permeation flux about 141~238 (L·m2·h/MPa) and superior salt rejection of Na2SO4 > 98.4%.

The effect of high external pressure on the structure and stability of MOF α-Mg3(HCOO)6 probed by in situ Raman and FT-IR spectroscopy

2015 ◽  
Vol 3 (22) ◽  
pp. 11976-11984 ◽  
Author(s):  
Haiyan Mao ◽  
Jun Xu ◽  
Yue Hu ◽  
Yining Huang ◽  
Yang Song
Keyword(s):  
High Pressure ◽  
Ir Spectroscopy ◽  
Vibrational Spectroscopy ◽  
External Pressure ◽  
Structural Transitions ◽  
In Situ Raman ◽  
Ft Ir ◽  
High Pressure Study ◽  
Ft Ir Spectroscopy

A first high-pressure study on MOF α-Mg3(HCOO)6 probed by in situ vibrational spectroscopy revealed strongly contrasting host-dependent structural transitions and stabilities.

Mechanistic Study of Silsesquioxane Synthesis by Mass Spectrometry and in Situ ATR FT-IR Spectroscopy

2003 ◽  
Vol 107 (42) ◽  
pp. 8885-8892 ◽  
Author(s):  
Paolo P. Pescarmona ◽  
Maria E. Raimondi ◽  
John Tetteh ◽  
Ben McKay ◽  
Thomas Maschmeyer
Keyword(s):  
Mass Spectrometry ◽  
Ir Spectroscopy ◽  
Mechanistic Study ◽  
Ft Ir ◽  
Ft Ir Spectroscopy
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