A 3D MOF showing unprecedented solvent-induced single-crystal-to-single-crystal transformation and excellent CO2 adsorption selectivity at room temperature

2014 ◽  
Vol 50 (100) ◽  
pp. 15886-15889 ◽  
Author(s):  
Tao Qin ◽  
Jun Gong ◽  
Junhan Ma ◽  
Xin Wang ◽  
Yonghua Wang ◽  
...  
Keyword(s):  
Single Crystal ◽  
Structural Transformation ◽  
Room Temperature ◽  
Co2 Adsorption ◽  
Adsorption Selectivity ◽  
Crystal Transformation ◽  
Co2 Adsorption Selectivity

A multifunctional MOF material showing rare solvent-induced structural transformation with substitution of bridging-water and guest-exchange at 298 K is reported.

Zn(II)-Benzotriazolate Clusters Based Amide Functionalized Porous Coordination Polymers with High CO2 Adsorption Selectivity

2014 ◽  
Vol 53 (17) ◽  
pp. 8842-8844 ◽  
Author(s):  
Yong-Qiang Chen ◽  
Yang-Kun Qu ◽  
Guo-Rong Li ◽  
Zhan-Zhong Zhuang ◽  
Ze Chang ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Co2 Adsorption ◽  
Porous Coordination Polymers ◽  
Adsorption Selectivity ◽  
High Co2 ◽  
Co2 Adsorption Selectivity

Natural gas upgrading using a fluorinated MOF with tuned H2S and CO2 adsorption selectivity

Nature Energy ◽  
2018 ◽  
Vol 3 (12) ◽  
pp. 1059-1066 ◽  
Author(s):  
Youssef Belmabkhout ◽  
Prashant M. Bhatt ◽  
Karim Adil ◽  
Renjith S. Pillai ◽  
Amandine Cadiau ◽  
...  
Keyword(s):  
Natural Gas ◽  
Co2 Adsorption ◽  
Adsorption Selectivity ◽  
Co2 Adsorption Selectivity

Reversible single-crystal-to-single-crystal transformation from a mononuclear complex to a fourfold interpenetrated MOF with selective adsorption of CO2

2015 ◽  
Vol 44 (46) ◽  
pp. 19796-19799 ◽  
Author(s):  
Min-Min Liu ◽  
Yan-Lin Bi ◽  
Qin-Qin Dang ◽  
Xian-Ming Zhang
Keyword(s):  
Single Crystal ◽  
Room Temperature ◽  
Selective Adsorption ◽  
Low Pressure ◽  
Mononuclear Complex ◽  
Crystal Transformation ◽  
Adsorption Of Co ◽  
Adsorption Of Co2

Reversible crystal transformation was observed between a mononuclear complex to a fourfold interpenetrated MOF with selective adsorption of CO2 up to 12.5 wt% at room temperature and low pressure.

Solvent-induced single-crystal-to-single-crystal transformation and tunable magnetic properties of 1D azido-Cu(ii) chains with a carboxylate bridge

2019 ◽  
Vol 48 (30) ◽  
pp. 11268-11277 ◽  
Author(s):  
Xiangyu Liu ◽  
Xiufang Ma ◽  
Jinhui Yang ◽  
Shuchang Luo ◽  
Zheng Wang ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Single Crystal ◽  
Solvent Effect ◽  
Structural Transformation ◽  
Coordination Polymers ◽  
Crystal Transformation ◽  
Carboxylate Bridge ◽  
Copper Coordination

The solvent effect leads to structural transformation and tunable magnetism of chain-like azido-copper coordination polymers.

Reversing C2H2–CO2 adsorption selectivity in an ultramicroporous metal–organic framework platform

2019 ◽  
Vol 55 (76) ◽  
pp. 11354-11357 ◽  
Author(s):  
Hui-Min Wen ◽  
Caijun Liao ◽  
Libo Li ◽  
Ling Yang ◽  
Jing Wang ◽  
...  
Keyword(s):  
Binding Sites ◽  
Co2 Adsorption ◽  
Metal Organic Framework ◽  
Fine Tuning ◽  
Adsorption Selectivity ◽  
Pore Sizes ◽  
Metal Organic ◽  
Co2 Adsorption Selectivity ◽  
At Will ◽  
Organic Framework

Fine-tuning the pore sizes, metrics, and binding sites within a MOF platform can reverse the adsorption selectivity between C2H2 and CO2 at will.

scholarly journals Single-crystal-to-single-crystal transformation of an anion exchangeable dynamic metal–organic framework

CrystEngComm ◽  
2015 ◽  
Vol 17 (46) ◽  
pp. 8796-8800 ◽  
Author(s):  
Biplab Manna ◽  
Aamod V. Desai ◽  
Naveen Kumar ◽  
Avishek Karmakar ◽  
Sujit K. Ghosh
Keyword(s):  
Single Crystal ◽  
Room Temperature ◽  
Dynamic Behaviour ◽  
Metal Organic Framework ◽  
Donor Ligand ◽  
Crystal Transformation ◽  
Metal Organic ◽  
Transformation Experiment ◽  
Organic Framework

A 3D cationic Metal–Organic Framework has been fabricated with a neutral N-donor ligand and Cd(ClO4)2 which shows guest triggered dynamic behaviour at room temperature. This structural dynamism has been demonstrated from the SCSC transformation experiment.

Binderless zeolite NaX microspheres with enhanced CO2 adsorption selectivity

2019 ◽  
Vol 278 ◽  
pp. 267-274 ◽  
Author(s):  
Baili Yan ◽  
Shuang Yu ◽  
Changfeng Zeng ◽  
Liang Yu ◽  
Chongqing Wang ◽  
...  
Keyword(s):  
Co2 Adsorption ◽  
Adsorption Selectivity ◽  
Zeolite Nax ◽  
Co2 Adsorption Selectivity
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