scholarly journals Multiple scale investigation of molecular diffusion inside functionalized porous hosts using a combination of magnetic resonance methods

2015 ◽  
Vol 17 (24) ◽  
pp. 15976-15988 ◽  
Author(s):  
Martin Wessig ◽  
Martin Spitzbarth ◽  
Malte Drescher ◽  
Rainer Winter ◽  
Sebastian Polarz
Keyword(s):  
Magnetic Resonance ◽  
Epr Spectroscopy ◽  
Molecular Diffusion ◽  
Spin Exchange ◽  
Multiple Scale ◽  
Exchange Processes ◽  
P Diffusion

Diffusion in organo-functionalized porous hosts could be tracked by evaluation of spin exchange processes using EPR spectroscopy.

Optical Properties of (Pb,Eu)Te Thin Films and Superlattices

1986 ◽  
Vol 89 ◽  
Author(s):  
W. C. Goltsos ◽  
A. V. Nurmikko ◽  
D. L. Partin
Keyword(s):  
Thin Films ◽  
Optical Properties ◽  
Spin Exchange ◽  
Optical Measurements ◽  
Optical Gap ◽  
Exchange Processes ◽  
Reflectance Measurements

AbstractPhotoluminescence, transmission, and reflectance measurements have yielded information about the states defining an optical gap in thin films and superlattices based on the (Pb,Eu)Te system, including the limit of high Eu concentration. Magneto-optical measurements show the presence of finite spin exchange processes at low Eu-concentrations.

scholarly journals Comprehensive Studies of the Processes of the Molecular Transfer of the Momentum, Thermal Energy and Mass in the Nutrient Media of Biotechnological Industries

2022 ◽  
Vol 9 (1) ◽  
pp. 18
Author(s):  
Aleksandr G. Novoselov ◽  
Sergei A. Sorokin ◽  
Igor V. Baranov ◽  
Nikita V. Martyushev ◽  
Olga N. Rumiantceva ◽  
...  
Keyword(s):  
Thermal Diffusivity ◽  
Dynamic Viscosity ◽  
Empirical Equation ◽  
Molecular Diffusion ◽  
Transport Coefficients ◽  
Molecular Transport ◽  
Rolling Ball ◽  
Molecular Transfer ◽  
Exchange Processes ◽  
Different Temperatures

This article puts forward arguments in favor of the necessity of conducting complex measurements of molecular transport coefficients that quantitatively determine the coefficients of dynamic viscosity, thermal diffusivity and molecular diffusion. The rheological studies have been carried out on the viscometers of two types: those with a rolling ball (HÖPPLER® KF 3.2.), and those with a rotary one (Rheotest RN 4.1.). The thermophysical studies have been performed using the analyzer Hot Disk TPS 2500S. The measurements have been taken in the temperature range of 283 to 363 K. The concentration of dry substances has varied from 16.2 to 77.7% dry wt. An empirical equation for calculating the density of aqueous solutions of beet molasses has been obtained. The diagrams of the dependence of the dynamic viscosity on the shear rate in the range of 1 s−1 to 500 s−1 at different temperatures have been provided. The diagrams of the dependence of the coefficients of thermal conductivity and thermal diffusivity on the temperature and the concentration of dry substances have been presented, and empirical equations for their calculation have been obtained. The findings can be used for engineering calculations of hydrodynamic and heat-exchange processes in biotechnological equipment.

Probing molecular geometry of solids by nuclear magnetic resonance spin exchange at the n=0 rotational-resonance condition

2002 ◽  
Vol 116 (17) ◽  
pp. 7607-7616 ◽  
Author(s):  
Piotr Tekely ◽  
Carole Gardiennet ◽  
Marek J. Potrzebowski ◽  
Angelika Sebald ◽  
Detlef Reichert ◽  
...  
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Spin Exchange ◽  
Resonance Condition ◽  
Molecular Geometry ◽  
Rotational Resonance ◽  
Resonance Spin ◽  
Nuclear Magnetic

SABRE Hyperpolarization of Bipyridine Stabilized Ir-Complex at High, Low and Ultralow Magnetic Fields

2017 ◽  
Vol 231 (3) ◽  
Author(s):  
Andrey N. Pravdivtsev
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Magnetic Fields ◽  
Dynamic Nuclear Polarization ◽  
Signal Amplification ◽  
Nuclear Polarization ◽  
Optical Pumping ◽  
Spin Exchange ◽  
Spin Exchange Optical Pumping ◽  
Wide Range

AbstractA strong limitation of nuclear magnetic resonance is its low inherent sensitivity that can be overcome by using an appropriate hyperpolarization technique. Presently, dynamic nuclear polarization and spin-exchange optical pumping are the only hyperpolarization techniques that are used in applied medicine. However, both are relatively complex in use and expensive. Here we present a modification of the signal amplification by reversible exchange (SABRE) hyperpolarization method – SABRE on stabilized Ir-complexes. A stabilized Ir-complex (here we used bipyridine for stabilization) can be hyperpolarized in a wide range of magnetic fields from a few μT upto 10 T with

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