A comparison of the abilities of natural rubber (NR) and synthetic polyisoprene cis-1,4 rubber (IR) to crystallize under strain at high strain rates

2016 ◽  
Vol 18 (5) ◽  
pp. 3472-3481 ◽  
Author(s):  
Nicolas Candau ◽  
Laurent Chazeau ◽  
Jean-Marc Chenal ◽  
Catherine Gauthier ◽  
Etienne Munch
Keyword(s):  
Comparative Study ◽  
Natural Rubber ◽  
High Strain ◽  
Strain Rates ◽  
High Strain Rates ◽  
Synthetic Rubber ◽  
Strain Induced Crystallization ◽  
First Time ◽  
Induced Crystallization

In situ WAXS experiments combined with a thermodynamic approach allowed for the first time a comparative study of strain induced crystallization of natural and synthetic rubber at high strain rates.

Strain-induced crystallization of natural rubber with high strain rates

2012 ◽  
Vol 50 (23) ◽  
pp. 1630-1637 ◽  
Author(s):  
Baijin Zhao ◽  
Nan Tian ◽  
Yanpin Liu ◽  
Tingzi Yan ◽  
Weiqing Zhou ◽  
...  
Keyword(s):  
Natural Rubber ◽  
High Strain ◽  
Strain Rates ◽  
High Strain Rates ◽  
Strain Induced Crystallization ◽  
Induced Crystallization

Fracture of Laminated and In Situ Niobium Silicide-Niobium Composites

1996 ◽  
Vol 434 ◽  
Author(s):  
J. D. Rigney
Keyword(s):  
Low Temperatures ◽  
Fracture Resistance ◽  
Fracture Behavior ◽  
High Strain ◽  
Theoretical Models ◽  
High Yield ◽  
Strain Rates ◽  
High Strain Rates ◽  
Ductile Phase

AbstractThe mechanisms contributing to the fracture resistance of refractory metal intermetallic composites containing a BCC metallic phase (niobium) were investigated using model Nb-Si laminates and in situ composites. The controlling influence of ductile phase yield strength and fracture behavior were investigated by varying laminate processing parameters, and/or altering temperatures and applied strain rates during fracture experiments on all materials. The fracture behavior of “ductile” constituents were found to be influenced by phase grain size, solid solution content, constraint (as influenced by interfacial bond strengths), and the testing condition (high strain rates and low temperatures). The measured fracture resistance, when compared to theoretical models, was shown to be controlled by the “toughness” of the “ductile” phase and independent of the fracture behavior promoted (cleavage and ductile). The loss in ductility due to cleavage by high constraint, high strain rates and/or low temperatures was compensated by high yield and cleavage fracture stresses in order to provide a level of toughening similar to that contributed by ligaments which failed with lower yield stresses and greater strains.

Deformation behavior of Al/Cu in-situ metal-intermetallic laminates at low and high strain rates

2021 ◽  
pp. 159767
Author(s):  
Kartheek. S.M. Sonti ◽  
Biswaranjan Dash ◽  
K.V. Vamsi ◽  
H. Bandyopadhyay ◽  
B. Ravisankar ◽  
...  
Keyword(s):  
Deformation Behavior ◽  
High Strain ◽  
Strain Rates ◽  
High Strain Rates

Strain-Induced Crystallization of Natural Rubber: Effect of Proteins and Phospholipids

2008 ◽  
Vol 81 (5) ◽  
pp. 753-766 ◽  
Author(s):  
Sureerut Amnuaypornsri ◽  
Jitladda Sakdapipanich ◽  
Shigeyuki Toki ◽  
Benjamin S. Hsiao ◽  
Naoya Ichikawa ◽  
...  
Keyword(s):  
Natural Rubber ◽  
Decomposition Methods ◽  
Uniaxial Deformation ◽  
X Ray Diffraction ◽  
High Mechanical Property ◽  
Naturally Occurring ◽  
Stress Strain Relation ◽  
Strain Induced Crystallization ◽  
Induced Crystallization

Abstract The effects of proteins and phospholipids in natural rubber (NR) on the strain-induced crystallization behavior during uniaxial deformation were studied by in-situ synchrotron wide-angle X-ray diffraction (WAXD) technique and simultaneous measurements of stress-strain relation. The influences of proteins and phospholipids in NR were evaluated separately by decomposition methods using deproteinization and lipase treatment, respectively. It was found that both components form a naturally occurring network, which is responsible for the strain-induced crystallizability of unvulcanized NR and the corresponding high mechanical property. This network also plays a significant role in strain-induced crystallization of vulcanized natural rubber.

Strain induced crystallization and melting of natural rubber during dynamic cycles

2015 ◽  
Vol 17 (23) ◽  
pp. 15331-15338 ◽  
Author(s):  
Nicolas Candau ◽  
Laurent Chazeau ◽  
Jean-Marc Chenal ◽  
Catherine Gauthier ◽  
José Ferreira ◽  
...  
Keyword(s):  
Natural Rubber ◽  
Strain Rate ◽  
High Frequencies ◽  
Self Heating ◽  
Strain Induced Crystallization ◽  
Chain Alignment ◽  
First Time ◽  
Induced Crystallization

The investigation on strain-induced crystallization, during complete cycles at high frequencies, highlighted for the first time the concomitant effects of the strain rate, memory of the chain alignment and self-heating.

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