TEMPO-functionalized zinc phthalocyanine: synthesis, magnetic properties, and its utility for electrochemical sensing of ascorbic acid

2016 ◽  
Vol 45 (7) ◽  
pp. 3086-3092 ◽  
Author(s):  
Sibel Eken Korkut ◽  
Duygu Akyüz ◽  
Kemal Özdoğan ◽  
Yusuf Yerli ◽  
Atıf Koca ◽  
...  

Zinc(ii) phthalocyanine (TEMPO-ZnPc), peripherally functionalized with 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO) radicals is synthesized and its magneto structural and electrochemical sensing properties are investigated.

2014 ◽  
Vol 64 (3) ◽  
pp. 373-382 ◽  
Author(s):  
Kung-Chin Chang ◽  
Chien-Ming Chu ◽  
Chi-Hao Chang ◽  
Hsiao-Tung Cheng ◽  
Sheng-Chieh Hsu ◽  
...  

2019 ◽  
Vol 31 (5) ◽  
pp. 851-857 ◽  
Author(s):  
Sayed Tayyab Raza Naqvi ◽  
Bahareh Shirinfar ◽  
Dilshad Hussain ◽  
Saadat Majeed ◽  
Muhammad Naeem Ashiq ◽  
...  

Nanomaterials ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 835 ◽  
Author(s):  
Zhaotian Cai ◽  
Yabing Ye ◽  
Xuan Wan ◽  
Jun Liu ◽  
Shihui Yang ◽  
...  

Various morphologies of iron oxide nanoparticles (Fe2O3 NPs), including cubic, thorhombic and discal shapes were synthesized by a facile meta-ion mediated hydrothermal route. To further improve the electrochemical sensing properties, discal Fe2O3 NPs with the highest electrocatalytic activity were coupled with graphene oxide (GO) nanosheets. The surface morphology, microstructures and electrochemical properties of the obtained Fe2O3 NPs and Fe2O3/GO nanohybrids were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) techniques. As expected, the electrochemical performances were found to be highly related to morphology. The discal Fe2O3 NPs coupled with GO showed remarkable electrocatalytic activity toward the oxidation of dopamine (DA) and uric acid (UA), due to their excellent synergistic effect. The electrochemical responses of both DA and UA were linear to their concentrations in the ranges of 0.02–10 μM and 10–100 μM, with very low limits of detection (LOD) of 3.2 nM and 2.5 nM for DA and UA, respectively. Moreover, the d-Fe2O3/GO nanohybrids showed good selectivity and reproducibility. The proposed d-Fe2O3/GO/GCE realized the simultaneous detection of DA and UA in human serum and urine samples with satisfactory recoveries.


2017 ◽  
Vol 27 (5) ◽  
pp. 1105-1116 ◽  
Author(s):  
Gui-hong HAN ◽  
Shu-zhen YANG ◽  
Yan-fang HUANG ◽  
Jing YANG ◽  
Wen-cui CHAI ◽  
...  

2020 ◽  
Vol 3 (10) ◽  
pp. 10032-10039
Author(s):  
Fei Ma ◽  
Bin Yang ◽  
Zhe Zhao ◽  
Yuting Zhao ◽  
Ruobing Pan ◽  
...  

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