Preparation of microcapsules containing multi-functional reactive isocyanate-terminated-polyurethane-prepolymer as healing agent, part II: corrosion performance and mechanical properties of a self healing coating

RSC Advances ◽  
2016 ◽  
Vol 6 (56) ◽  
pp. 50874-50886 ◽  
Author(s):  
M. Haghayegh ◽  
S. M. Mirabedini ◽  
H. Yeganeh
Keyword(s):  
Mechanical Properties ◽  
Neat Epoxy ◽  
Self Healing ◽  
Corrosion Performance ◽  
Stress Strain ◽  
Sem Micrographs ◽  
Healing Agent ◽  
Polyurethane Prepolymer

Stress–strain curves in three modes (intact, scratched and healed) for; (a) neat epoxy and (b) sample containing 5 wt% microcapsules. SEM micrographs of scratched area of; (c) neat epoxy film, and (d) film with 5 wt% microcapsule.

scholarly journals Characteristics of Self-Healable Copolymers of Styrene and Eugenol Terminated Polyurethane Prepolymer

Polymers ◽  
2019 ◽  
Vol 11 (10) ◽  
pp. 1674 ◽  
Author(s):  
Jing-Yu Liang ◽  
Se-Ra Shin ◽  
Soo-Hyoung Lee ◽  
Dai-Soo Lee
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Fossil Fuel ◽  
Renewable Resource ◽  
Self Healing ◽  
Elongation At Break ◽  
Good Thermal Stability ◽  
Healing Property ◽  
Polyurethane Prepolymer ◽  
Reversible Nature

With limited biomass that can be currently utilized as a renewable resource, it is important to develop a method to convert biomass into materials that can replace fossil fuel product. In this paper, eugenol, a bio-based allyl chain-substituted guaiacol, was used to synthesize self-healable copolymers. Eugenol terminated polyurethane prepolymer (ETPU) was synthesized from eugenol and polyurethane prepolymers terminated with isocyanate groups. ETPU contained two allyl groups. Self-healing copolymer networks were obtained by copolymerization of ETPU and styrene monomer via free radical polymerization. Effects of ETPU content on the properties of copolymers were then studied. These copolymers containing ETPU exhibited good thermal stability and mechanical properties. These copolymers showed higher tensile strength and elongation at break than PS. Their maximum tensile strength reached 19 MPa. In addition, these copolymers showed self-healing property at elevated temperature due to the reversible nature of urethane units in ETPU.

scholarly journals Impact of Bio-Carrier Immobilized with Marine Bacteria on Self-Healing Performance of Cement-Based Materials

Materials ◽  
2020 ◽  
Vol 13 (18) ◽  
pp. 4164 ◽  
Author(s):  
Hayeon Kim ◽  
Hyeongmin Son ◽  
Joonho Seo ◽  
H. K. Lee
Keyword(s):  
Mechanical Properties ◽  
Mercury Intrusion Porosimetry ◽  
Tap Water ◽  
Bottom Ash ◽  
Self Healing ◽  
Mixing Process ◽  
Mercury Intrusion ◽  
Healing Efficiency ◽  
Cement Based Materials ◽  
Healing Agent

The present study evaluated the self-healing efficiency and mechanical properties of mortar specimens incorporating a bio-carrier as a self-healing agent. The bio-carrier was produced by immobilizing ureolytic bacteria isolated from seawater in bottom ash, followed by surface coating with cement powder to prevent loss of nutrients during the mixing process. Five types of specimens were prepared with two methods of incorporating bacteria, and were water cured for 28 days. To investigate the healing ratio, the specimens with predefined cracks were treated by applying a wet–dry cycle in three different conditions, i.e., seawater, tap water, and air for 28 days. In addition, a compression test and a mercury intrusion porosimetry analysis of the specimens were performed to evaluate their physico-mechanical properties. The obtained results showed that the specimen incorporating the bio-carrier had higher compressive strength than the specimen incorporating vegetative cells. Furthermore, the highest healing ratio was observed in specimens incorporating the bio-carrier. This phenomenon could be ascribed by the enhanced bacterial viability by the bio-carrier.

Mechanical Properties of a Microcapsule-Containing Epoxy for Self-Healing Applications

2011 ◽  
Vol 239-242 ◽  
pp. 1794-1798 ◽  
Author(s):  
Xing Liu ◽  
Jong Keun Lee
Keyword(s):  
Mechanical Properties ◽  
Polymer Matrix ◽  
Volume Fraction ◽  
Dynamic Mechanical Properties ◽  
Interfacial Interaction ◽  
Self Healing ◽  
Dynamic Mechanical ◽  
Healing Agent

The addition of microencapsulated healing agent or catalyst in a polymer matrix can potentially change its mechanical properties and processing characteristics. The extent of this change depends on the volume fraction of the additives, the level of interfacial interaction, and the inherent properties of the additives. For a self-healing concept to be viable, the healing performance should be achieved without compromising the overall processing and mechanical properties of the polymer matrix. In this study, tensile and dynamic mechanical properties were investigated and discussed for an amine-cured epoxy dispersed with different loadings of microcapsules.

Autonomous self-healing polyisoprene elastomers with high modulus and good toughness based on the synergy of dynamic ionic crosslinks and highly disordered crystals

2020 ◽  
Vol 11 (41) ◽  
pp. 6549-6558
Author(s):  
Yohei Miwa ◽  
Mayu Yamada ◽  
Yu Shinke ◽  
Shoichi Kutsumizu
Keyword(s):  
Mechanical Properties ◽  
Room Temperature ◽  
Self Healing ◽  
High Modulus ◽  
Disordered Crystals ◽  
Ionic Crosslinks

We designed a novel polyisoprene elastomer with high mechanical properties and autonomous self-healing capability at room temperature facilitated by the coexistence of dynamic ionic crosslinks and crystalline components that slowly reassembled.

Mechanical Properties and Stress/Strain Characteristics of Critical Currents in Reinforced Bronze-processed Nb3Sn Wires

2004 ◽  
Vol 39 (9) ◽  
pp. 433-438 ◽  
Author(s):  
Kazumune KATAGIRI ◽  
Kazuo WATANABE ◽  
Koshichi NOTO ◽  
Koichi KASABA ◽  
Yoshitaka SHOJI
Keyword(s):  
Mechanical Properties ◽  
Critical Currents ◽  
Stress Strain

Polypyrrole/PU hybrid hydrogels: electrically conductive and fast self-healing for the potential application in body-monitor sensor

2021 ◽  
Author(s):  
Zhanyu Jia ◽  
Guangyao Li ◽  
Juan Wang ◽  
shouhua Su ◽  
Jie Wen ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Electrical Conductivity ◽  
Potential Application ◽  
Self Healing ◽  
Electrically Conductive ◽  
Sensor Application ◽  
Hybrid Hydrogels ◽  
Health Monitor

Conductivity, self-healing and moderate mechanical properties are necessary for multifunctional hydrogels which have great potential in health-monitor sensor application. However, the combination of electrical conductivity, self-healing and good mechanical properties...

Sign in / Sign up

Export Citation Format

Share Document