Freestanding CuS nanowalls: ionic liquid-assisted synthesis and prominent catalytic performance for the decomposition of ammonium perchlorate

CrystEngComm ◽  
2017 ◽  
Vol 19 (34) ◽  
pp. 5048-5057 ◽  
Author(s):  
Kaisheng Yao ◽  
Chenchen Zhao ◽  
Nannan Sun ◽  
Weiwei Lu ◽  
Yuan Zhang ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Ionic Liquid ◽  
Catalytic Activity ◽  
Ammonium Perchlorate ◽  
Catalytic Performance ◽  
Liquid Interface

Freestanding CuS nanowalls, with excellent catalytic activity for AP thermal decomposition, were grown and assembled at the [C10mim]Br-modulated liquid–liquid interface.

scholarly journals Facile preparation of rGO/MFe2O4(M = Cu, Co, Ni) nanohybrids and its catalytic performance during the thermal decomposition of ammonium perchlorate

RSC Advances ◽  
2018 ◽  
Vol 8 (56) ◽  
pp. 32221-32230 ◽  
Author(s):  
Weiran Wang ◽  
Dongxiang Zhang
Keyword(s):  
Thermal Decomposition ◽  
Catalytic Activity ◽  
Ammonium Perchlorate ◽  
Catalytic Performance ◽  
Decomposition Process ◽  
Thermal Decomposition Process ◽  
Facile Preparation

The rGO/MFe2O4(M = Cu, Co, Ni) nanohybrids show amazing catalytic activity in the thermal decomposition process of AP.

scholarly journals Preparation of Co Nanocrystallites by Solvothermal Process and Its Catalytic Activity on the Thermal Decomposition of Ammonium Perchlorate

2010 ◽  
Vol 2010 ◽  
pp. 1-5 ◽  
Author(s):  
Shusen Zhao ◽  
Dongxu Ma
Keyword(s):  
Thermal Decomposition ◽  
Catalytic Activity ◽  
Ammonium Perchlorate ◽  
Catalytic Performance ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
Selected Area Electron Diffraction ◽  
Transmission Electron ◽  
Polyol Medium ◽  
Decomposition Behavior

Nanometer cobalt ferrite (Co) was synthesized by polyol-medium solvothermal method and characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), and selected area electron diffraction (SAED). Further, the catalytic activity and kinetic parameters of Co nanocrystallites on the thermal decomposition behavior of ammonium perchlorate (AP) have been investigated by thermogravimetry and differential scanning calorimetry analysis (TG-DSC). The results imply that the catalytic performance of Co nanocrystallites is significant and the decrease in the activation energy and the increase in the rate constant for AP further confirm the enhancement in catalytic activity of Co nanocrystallites. A mechanism based on an proton transfer process has also been proposed for AP in the presence of Co nanocrystallites.

Synthesis of Nitrogen-Doped ZnO Nanocrystallites and its Novel Catalytic Activity on Ammonium Perchlorate

2011 ◽  
Vol 236-238 ◽  
pp. 1665-1669
Author(s):  
Min Zheng ◽  
Zuo Shan Wang ◽  
Qing Wang
Keyword(s):  
Thermal Decomposition ◽  
Catalytic Activity ◽  
Ammonium Perchlorate ◽  
Photoelectron Spectroscopy ◽  
Catalytic Performance ◽  
Nitrogen Doped ◽  
Nitrogen Incorporation ◽  
One Step ◽  
Doped Zno ◽  
Zno Crystal

Nitrogen-doped zinc oxide (N-doped ZnO) nanocrystallites were synthesized via improved one-step combustion technique by using citric acid as additive. Scan electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) were used to determine the grain size, shape, degree of nitrogen incorporation and nature of the resultant oxynitride chemical bonding. The catalytic performance of N-doped ZnO on the thermal decomposition of ammonium perchlorate (AP) was investigated by DSC-TG technique. The results show that the as-synthesized N-doped ZnO has uniform crystallite size about 20-30nm in diameter and 1.25%wt nitrogen incorporation, which forms into NO bonding region in ZnO crystal lattice. The nitrogen doping is accountable for the significant increase in catalytic activity on the thermal decomposition of AP versus the commercial nanometer ZnO and the thermal decomposition peak shifts 133°C downward when the content of N-doped ZnO in AP is 3%wt.

scholarly journals A Facile Method to Construct MXene/CuO Nanocomposite with Enhanced Catalytic Activity of CuO on Thermal Decomposition of Ammonium Perchlorate

Materials ◽  
2018 ◽  
Vol 11 (12) ◽  
pp. 2457 ◽  
Author(s):  
Haifeng Zhao ◽  
Jing Lv ◽  
Junshan Sang ◽  
Li Zhu ◽  
Peng Zheng ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Catalytic Activity ◽  
Ammonium Perchlorate ◽  
Photoelectron Spectra ◽  
Gravimetric Analysis ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
X Ray ◽  
Improved Performance ◽  
Calcination Method

In this work, a mixing-calcination method was developed to facilely construct MXene/CuO nanocomposite. CuO and MXene were first dispersed in ethanol with sufficient mixing. After solvent evaporation, the dried mixture was calcinated under argon to produce a MXene/CuO nanocomposite. As characterized by X-ray diffraction (XRD), field-emission scanning electron microscopy (FESEM), and X-ray photoelectron spectra (XPS), CuO nanoparticles (60–100 nm) were uniformly distributed on the surface and edge of MXene nanosheets. Furthermore, as evaluated by differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA), the high-temperature decomposition (HTD) temperature decrease of ammonium perchlorate (AP) upon addition of 1 wt% CuO (hybridized with 1 wt% MXene) was comparable with that of 2 wt% CuO alone, suggesting an enhanced catalytic activity of CuO on thermal decomposition of AP upon hybridization with MXene nanosheets. This strategy could be further applied to construct other MXene/transition metal oxide (MXene/TMO) composites with improved performance for various applications.

Rapid microwave-assisted hydrothermal synthesis of CeO2 octahedra with mixed valence states and their catalytic activity for thermal decomposition of ammonium perchlorate

2019 ◽  
Vol 6 (7) ◽  
pp. 1735-1743 ◽  
Author(s):  
Jing Shi ◽  
Huixiang Wang ◽  
Yequn Liu ◽  
Xiaobo Ren ◽  
Haizhen Sun ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Catalytic Activity ◽  
Hydrothermal Synthesis ◽  
Ammonium Perchlorate ◽  
Oxygen Vacancies ◽  
Mixed Valence ◽  
High Concentration ◽  
Microwave Assisted ◽  
Valence States

CeO2 octahedra are prepared rapidly and they exhibit improved catalytic activity due to high concentration of oxygen vacancies and exposed (111) facets.

Catalytic Activity of Magnetite with Different Shapes for the Thermal Decomposition of Ammonium Perchlorate

2014 ◽  
Vol 43 (10) ◽  
pp. 1554-1556 ◽  
Author(s):  
Weiwei Wang ◽  
Jialiang Yao
Keyword(s):  
Thermal Decomposition ◽  
Catalytic Activity ◽  
Ammonium Perchlorate ◽  
Different Shapes

Magnetic Nanoparticles Supported Acidic Ionic Liquid as a Highly Active and Reusable Catalyst for Esterification

2016 ◽  
Vol 852 ◽  
pp. 485-488 ◽  
Author(s):  
Qiang Zhang ◽  
Xin Zhao ◽  
Xue Hua Zhu ◽  
Ji Hang Li
Keyword(s):  
Ionic Liquid ◽  
Catalytic Activity ◽  
Magnetic Nanoparticles ◽  
Catalytic Performance ◽  
Significant Loss ◽  
Reusable Catalyst ◽  
Hydrogen Sulfate ◽  
External Magnet ◽  
Acidic Ionic Liquid ◽  
Highly Active

A magnetic nanoparticles supported dual acidic ionic liquid catalyst was prepared via anchoring 3-sulfobutyl-1-(3-propyltriethoxysilane) imidazolium hydrogen sulfate onto the surface of silica-coated Fe3O4 nanoparticles. And this novel supported acidic ionic liquid catalyst showed good catalytic performance in esterification. More importantly, the catalyst could be easily recovered by an external magnet and reused six times without significant loss of catalytic activity.

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