A core–shell structured LiNi0.5Mn1.5O4@LiCoO2 cathode material with superior rate capability and cycling performance

2018 ◽  
Vol 47 (2) ◽  
pp. 367-375 ◽  
Author(s):  
Yunlong Deng ◽  
Jirong Mou ◽  
Lihua He ◽  
Fengyu Xie ◽  
Qiaoji Zheng ◽  
...  
Keyword(s):  
Solid State ◽  
Cathode Material ◽  
Sol Gel ◽  
Rate Capability ◽  
Cycling Performance ◽  
Core Shell ◽  
Licoo2 Cathode

A core–shell structured LiNi0.5Mn1.5O4@LiCoO2 cathode material has been successfully synthesized by the combination of sol–gel and solid state methods.

scholarly journals Effect of surface carbonates on the cyclability of LiNbO3-coated NCM622 in all-solid-state batteries with lithium thiophosphate electrolytes

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
A-Young Kim ◽  
Florian Strauss ◽  
Timo Bartsch ◽  
Jun Hao Teo ◽  
Jürgen Janek ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolyte ◽  
Sol Gel ◽  
Rate Capability ◽  
Cycling Performance ◽  
Side Reactions ◽  
Bulk Solid ◽  
Solid State Batteries ◽  
The Individual ◽  
Surface Carbonates

AbstractWhile still premature as an energy storage technology, bulk solid-state batteries are attracting much attention in the academic and industrial communities lately. In particular, layered lithium metal oxides and lithium thiophosphates hold promise as cathode materials and superionic solid electrolytes, respectively. However, interfacial side reactions between the individual components during battery operation usually result in accelerated performance degradation. Hence, effective surface coatings are required to mitigate or ideally prevent detrimental reactions from occurring and having an impact on the cyclability. In the present work, we examine how surface carbonates incorporated into the sol–gel-derived LiNbO3 protective coating on NCM622 [Li1+x(Ni0.6Co0.2Mn0.2)1–xO2] cathode material affect the efficiency and rate capability of pellet-stack solid-state battery cells with β-Li3PS4 or argyrodite Li6PS5Cl solid electrolyte and a Li4Ti5O12 anode. Our research data indicate that a hybrid coating may in fact be beneficial to the kinetics and the cycling performance strongly depends on the solid electrolyte used.

scholarly journals Improved Electrochemical Performance of Li1.25Ni0.2Co0.333Fe0.133Mn0.333O2 Cathode Material Synthesized by the Polyvinyl Alcohol Auxiliary Sol-Gel Process for Lithium-Ion Batteries

2018 ◽  
Vol 2018 ◽  
pp. 1-7
Author(s):  
He Wang ◽  
Mingning Chang ◽  
Yonglei Zheng ◽  
Ningning Li ◽  
Siheng Chen ◽  
...  
Keyword(s):  
Polyvinyl Alcohol ◽  
Cathode Material ◽  
Discharge Capacity ◽  
Electrochemical Impedance ◽  
Coulombic Efficiency ◽  
Sol Gel ◽  
Rate Capability ◽  
Lithium Ion ◽  
Transfer Resistance ◽  
Sol Gel Process

A lithium-rich manganese-based cathode material, Li1.25Ni0.2Co0.333Fe0.133Mn0.333O2, was prepared using a polyvinyl alcohol (PVA)-auxiliary sol-gel process using MnO2 as a template. The effect of the PVA content (0.0–15.0 wt%) on the electrochemical properties and morphology of Li1.25Ni0.2Co0.333Fe0.133Mn0.333O2 was investigated. Analysis of Li1.25Ni0.2Co0.333Fe0.133Mn0.333O2 X-ray diffraction patterns by RIETAN-FP program confirmed the layered α-NaFeO2 structure. The discharge capacity and coulombic efficiency of Li1.25Ni0.2Co0.333Fe0.133Mn0.333O2 in the first cycle were improved with increasing PVA content. In particular, the best material reached a first discharge capacity of 206.0 mAhg−1 and best rate capability (74.8 mAhg−1 at 5 C). Meanwhile, the highest capacity retention was 87.7% for 50 cycles. Finally, electrochemical impedance spectroscopy shows that as the PVA content increases, the charge-transfer resistance decreases.

scholarly journals Improved electrochemical performance of SiO2-coated Li-rich layered oxides-Li1.2Ni0.13Mn0.54Co0.13O2

2020 ◽  
Vol 31 (21) ◽  
pp. 19475-19486
Author(s):  
Jeffin James Abraham ◽  
Umair Nisar ◽  
Haya Monawwar ◽  
Aisha Abdul Quddus ◽  
R. A. Shakoor ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
Cathode Material ◽  
Sol Gel ◽  
Rate Capability ◽  
Lithium Ion ◽  
Side Reactions ◽  
Operating Voltage ◽  
Layered Oxides ◽  
Capacity Retention ◽  
Xps Characterization

AbstractLithium-rich layered oxides (LLOs) such as Li1.2Ni0.13Mn0.54Co0.13O2 are suitable cathode materials for future lithium-ion batteries (LIBs). Despite some salient advantages, like low cost, ease of fabrication, high capacity, and higher operating voltage, these materials suffer from low cyclic stability and poor capacity retention. Several different techniques have been proposed to address the limitations associated with LLOs. Herein, we report the surface modification of Li1.2Ni0.13Mn0.54Co0.13O2 by utilizing cheap and readily available silica (SiO2) to improve its electrochemical performance. Towards this direction, Li1.2Ni0.13Mn0.54Co0.13O2 was synthesized utilizing a sol–gel process and coated with SiO2 (SiO2 = 1.0 wt%, 1.5 wt%, and 2.0 wt%) employing dry ball milling technique. XRD, SEM, TEM, elemental mapping and XPS characterization techniques confirm the formation of phase pure materials and presence of SiO2 coating layer on the surface of Li1.2Ni0.13Mn0.54Co0.13O2 particles. The electrochemical measurements indicate that the SiO2-coated Li1.2Ni0.13Mn0.54Co0.13O2 materials show improved electrochemical performance in terms of capacity retention and cyclability when compared to the uncoated material. This improvement in electrochemical performance can be related to the prevention of electrolyte decomposition when in direct contact with the surface of charged Li1.2Ni0.13Mn0.54Co0.13O2 cathode material. The SiO2 coating thus prevents the unwanted side reactions between cathode material and the electrolyte. 1.0 wt% SiO2-coated Li1.2Ni0.13Mn0.54Co0.13O2shows the best electrochemical performance in terms of rate capability and capacity retention.

Hybrid LiV3O8/carbon encapsulated Li1.2Mn0.54Co0.13Ni0.13O2 with improved electrochemical properties for lithium ion batteries

RSC Advances ◽  
2016 ◽  
Vol 6 (34) ◽  
pp. 28729-28736 ◽  
Author(s):  
Kailing Sun ◽  
Can Peng ◽  
Zhaohui Li ◽  
Qichang Xiao ◽  
Gangtie Lei ◽  
...  
Keyword(s):  
Composite Material ◽  
Coulombic Efficiency ◽  
Sol Gel ◽  
Rate Capability ◽  
Lithium Ion ◽  
Core Shell ◽  
Potential Range ◽  
Stable Operation ◽  
Initial Coulombic Efficiency ◽  
Good Rate Capability

Core–shell Li1.2Mn0.54Co0.13Ni0.13O2@LiV3O8/C composite material was prepared by sol–gel method. It possessed an initial coulombic efficiency of 94% at 0.1C rate over 2.0–4.8 V potential range, and good rate capability and stable operation voltage.

IMPROVING ELECTROCHEMICAL PERFORMANCE OF LiCoO2 BY TiO2 COATING AS CATHODE FOR AQUEOUS RECHARGEABLE LITHIUM BATTERIES

2013 ◽  
Vol 06 (02) ◽  
pp. 1350016 ◽  
Author(s):  
S. TIAN ◽  
L. L. LIU ◽  
Y. S. ZHU ◽  
Y. Y. HOU ◽  
C. L. HU ◽  
...  
Keyword(s):  
Current Density ◽  
Sol Gel ◽  
Rate Capability ◽  
Cycling Performance ◽  
X Ray Diffraction ◽  
Rechargeable Lithium Batteries ◽  
Capacity Fading ◽  
X Ray ◽  
Discharge Behavior ◽  
Initial Capacity

Modified LiCoO2 was prepared via a sol–gel method followed by a TiO2 coating and characterized by X-ray diffraction analysis, transmission electronic microscopy and various measurements of charge/discharge behavior. Its cycling performance and rate capability were greatly improved compared to the original LiCoO2 . The initial capacity of the TiO2 -coated LiCoO2 is 134 mAh g-1 at the current density of 5000 mA g-1. When the current density increases to 10,000 mA g-1, the cathode displays an initial capacity of 128 mAh g-1, much higher than that (<101 mAh g-1) for the virginal LiCoO2 , and shows no evident capacity fading after 100 cycles.

K-doped layered LiNi 0.5 Co 0.2 Mn 0.3 O 2 cathode material: Towards the superior rate capability and cycling performance

2017 ◽  
Vol 699 ◽  
pp. 358-365 ◽  
Author(s):  
Zuguang Yang ◽  
Xiaodong Guo ◽  
Wei Xiang ◽  
Weibo Hua ◽  
Jun Zhang ◽  
...  
Keyword(s):  
Cathode Material ◽  
Rate Capability ◽  
Cycling Performance

Towards high areal capacitance, rate capability, and tailorable supercapacitors: Co3O4@polypyrrole core–shell nanorod bundle array electrodes

2018 ◽  
Vol 6 (39) ◽  
pp. 19058-19065 ◽  
Author(s):  
Longtao Ma ◽  
Huiqing Fan ◽  
Xinying Wei ◽  
Shengmei Chen ◽  
Qingzhao Hu ◽  
...  
Keyword(s):  
Solid State ◽  
Carbon Fiber ◽  
High Performance ◽  
Rate Capability ◽  
Core Shell ◽  
Areal Capacitance ◽  
Carbon Fiber Cloth ◽  
Nanorod Bundle

We report high-performance, flexible, and tailorable solid-state supercapacitors enabled by Co3O4@PPy nanorod bundle arrays immobilized on carbon fiber cloth (CFC).

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