Hierarchical core–shell structures of P-Ni(OH)2 rods@MnO2 nanosheets as high-performance cathode materials for asymmetric supercapacitors

Nanoscale ◽  
2018 ◽  
Vol 10 (5) ◽  
pp. 2524-2532 ◽  
Author(s):  
Kunzhen Li ◽  
Shikuo Li ◽  
Fangzhi Huang ◽  
Xin-yao Yu ◽  
Yan Lu ◽  
...  

The unique P-Ni(OH)2@MnO2 core–shell nanoarrays heterostructure grown on Ni foam were designed and synthesized as a binder-free electrode, high power and energy density asymmetrical supercapacitors were achieved.

RSC Advances ◽  
2018 ◽  
Vol 8 (55) ◽  
pp. 31594-31602 ◽  
Author(s):  
Xiaobo Chen ◽  
Xiao Liu ◽  
Yongxu Liu ◽  
Yameng Zhu ◽  
Guoce Zhuang ◽  
...  

CoMn2O4@Co3O4 core/shell arrays on Ni foam exhibit outstanding electrochemical performance for asymmetric supercapacitors with respect to high specific capacitance and high cycling stability.


2020 ◽  
Vol 15 (2) ◽  
pp. 171-178
Author(s):  
Rongda Zhao ◽  
Jinqiu Dai ◽  
Fufa Wu

Smooth NiCo2O4 nanowire@MnO2 nanosheet structure arrays grown on the surface of Ni foam base is synthesized via a simple two-step hydrothermal method. As-synthetic NiCo2O4@MnO2 electrode material shows higher performance of electrochemistry than single-phase NiCo2O4 and MnO2, which presents area capacitance of 877.4 C cm–2 at a current density 1 mA cm–2. This wonderful property could be associated with special core–shell structure, which possesses opening appearance with large active surface area and fabulous approaches of the electrolyte immersion and ion transmission. Further, the as-assembling device with a working voltage window of 1.5 V shows a highest energy density value of 0.64 Wh cm–3 and a highest power density value of 7.47 W cm–3. The device displays long-cycle stability with 75% increased of initial capacity after 8000 cycles. Providing a material used for the new-generation device for energy storing and high power and energy density with long life.


2021 ◽  
Vol 44 ◽  
pp. 103459
Author(s):  
Zhengjie Xie ◽  
Dianfeng Dai ◽  
Ying Xue ◽  
Yixin Li ◽  
Liangyu Liu ◽  
...  

2020 ◽  
Vol 12 (1) ◽  
Author(s):  
Wenfu Xie ◽  
Jianming Li ◽  
Yuke Song ◽  
Shijin Li ◽  
Jianbo Li ◽  
...  

AbstractZinc–air batteries (ZABs) hold tremendous promise for clean and efficient energy storage with the merits of high theoretical energy density and environmental friendliness. However, the performance of practical ZABs is still unsatisfactory because of the inevitably decreased activity of electrocatalysts when assembly into a thick electrode with high mass loading. Herein, we report a hierarchical electrocatalyst based on carbon microtube@nanotube core–shell nanostructure (CMT@CNT), which demonstrates superior electrocatalytic activity for oxygen reduction reaction and oxygen evolution reaction with a small potential gap of 0.678 V. Remarkably, when being employed as air–cathode in ZAB, the CMT@CNT presents an excellent performance with a high power density (160.6 mW cm−2), specific capacity (781.7 mAhg Zn −1 ) as well as long cycle stability (117 h, 351 cycles). Moreover, the ZAB performance of CMT@CNT is maintained well even under high mass loading (3 mg cm−2, three times as much as traditional usage), which could afford high power density and energy density for advanced electronic equipment. We believe that this work is promising for the rational design of hierarchical structured electrocatalysts for advanced metal-air batteries.


2015 ◽  
Vol 3 (38) ◽  
pp. 19545-19555 ◽  
Author(s):  
Huan Yi ◽  
Huanwen Wang ◽  
Yuting Jing ◽  
Tianquan Peng ◽  
Yiran Wang ◽  
...  

Asymmetric supercapacitors with CNT@nickel hydroxide nanosheet composites and 3-D graphene networks demonstrated a high energy density (∼44.0 W h kg−1) and high power density (∼16 kW kg−1) in aqueous KOH electrolyte.


RSC Advances ◽  
2017 ◽  
Vol 7 (13) ◽  
pp. 7843-7856 ◽  
Author(s):  
Zenghui Qiu ◽  
Dawei He ◽  
Yongsheng Wang ◽  
Xuan Zhao ◽  
Wen Zhao ◽  
...  

In this work, we report a fast and cost-effective cobalt catalyzed gasification strategy to obtain defect-introduced graphene sheets (DGNs) with hole structure.


2018 ◽  
Vol 47 (7) ◽  
pp. 2266-2273 ◽  
Author(s):  
Xinyang Zhang ◽  
Ziqing Zhang ◽  
Shuanggan Sun ◽  
Qiushi Sun ◽  
Xiaoyang Liu

Hierarchical NiFe2O4@MnO2 core–shell nanosheet arrays synthesized via a two-step hydrothermal method with successive annealing exhibited outstanding electrochemical performance.


2011 ◽  
Vol 21 (12) ◽  
pp. 2366-2375 ◽  
Author(s):  
Zhuangjun Fan ◽  
Jun Yan ◽  
Tong Wei ◽  
Linjie Zhi ◽  
Guoqing Ning ◽  
...  

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