scholarly journals Synthesis of tetragonal zirconia in mesoporous silica and its catalytic properties for methanol oxidative decomposition

RSC Advances ◽  
2017 ◽  
Vol 7 (88) ◽  
pp. 55819-55829 ◽  
Author(s):  
Naohiro Shimoda ◽  
Kyoko Nakayama ◽  
Keiko Kiyota ◽  
Shigeo Satokawa

Nano-sized tetragonal ZrO2 with large surface area can be synthesized by the hard template method using meso-porous silica KIT-6.

2014 ◽  
Vol 896 ◽  
pp. 78-81
Author(s):  
Teruhisa Hongo ◽  
Yoshihiro Usami ◽  
Atsushi Yamazaki

Nanostructured WO3 was synthesized by a hard template method using platelet-shaped mesoporous silica SBA-15. The nanostructured WO3 consisted of nanorod arrays comprised of mixed crystalline tetragonal and monoclinic phases with the diameter of 8.5 nm and the length of 170-300 nm. The specific surface area was 30 m2/g, which was about 6 times higher compared to that synthesized without the template.


RSC Advances ◽  
2017 ◽  
Vol 7 (89) ◽  
pp. 56375-56381 ◽  
Author(s):  
Xinxin Jin ◽  
Yu Jiang ◽  
Qi Hu ◽  
Shaohua Zhang ◽  
Qike Jiang ◽  
...  

Low-cost dual transition metal (Fe and Co) based non-noble metal electrocatalysts (NNMEs) with large surface area and porous structure boost oxygen reduction reaction (ORR) performance in alkaline solution.


2017 ◽  
Vol 17 (1) ◽  
pp. 30
Author(s):  
Ratna Ediati ◽  
Amirul Mukminin ◽  
Nurul Widiastuti

A series of carbon with ZSM-5 mesoporous (ZMC) and Ni/ZMC ZSM-5 templates were synthesized and gravimetrically known its adsorption capacity to H2 gases. ZMC carbon was synthesized using a hard template method at a carbonation temperature of 900 oC with sucrose as a source of carbon. A mesoporous ZSM-5 template was synthesized by using a hydrothermal method at an aging and crystallization temperature of respectively 60oC and 150oC for as long as 24 hours. The characterized result of ZMC carbon using XRD powder has shown a diffracted pattern of amorphous carbon. Impregnating Ni with ZMC carbon each resulted in 5%, 15% and 25% of weight, which in turn also resulted in a diffractogram pattern of Ni/ZMC-5, Ni/ZMC-15, and Ni/ZMC-25, where each patterns were uniform and had no additional peaks. The results of SEM-EDAX showed that Ni had been successfully impregnated on the surface of ZMC carbon with a random morphology surface of ZMC carbon. The isothermal results of adsorption – desorption of N2 showed that the larger the Ni loading on the supporting ZMC carbon, the smaller the surface area of the ZMC specific carbon. The distribution of the pore size that was counted by using the BJH method, which was applied to all the samples, was as big as 3,8 nm. The adsorption capacity of H2 was measured by using the gravimetry method at ambient temperature for Ni/ZMC-5, Ni/ZMC-15, and Ni/ZMC-25, which each gave a weight percentage of 0,331%; 0,663% and 0,649% respectively, whilst the ZMC carbon has a weight of 2,18%.


2020 ◽  
Vol 7 (9) ◽  
pp. 2654-2668
Author(s):  
Wei Li ◽  
Xiao-shan Chu ◽  
Shu-ao He ◽  
Xue-chuan Wang ◽  
Chuan-yi Wang

Gourd-like hollow mesoporous silica particles with large surface area supporting the Ag/AgBr Schottky junction for a high-efficieny TTC mineralization.


Nanoscale ◽  
2020 ◽  
Vol 12 (25) ◽  
pp. 13637-13653 ◽  
Author(s):  
Xia Chen ◽  
Shuang Zhu ◽  
Xisu Hu ◽  
Dayu Sun ◽  
Junling Yang ◽  
...  

It aims to explore the toxicity and mechanism of large-surface-area MSiNPs and MSiNPs-Ag+ exposed to hCEC cells and cornea. A protein corona-based therapy was proposed to treat MSiNPs and MSiNPs-Ag+ induced corneal damage and dry eye.


2011 ◽  
Vol 9 (1) ◽  
pp. 328-331 ◽  
Author(s):  
Haijiao Zhang ◽  
Zhijin Tan ◽  
Lin Wang ◽  
Zhiyong Li ◽  
Ping Gu ◽  
...  

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