scholarly journals Determination of berberine hydrochloride using a fluorimetric method with silica nanoparticles as a probe

RSC Advances ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 6075-6082 ◽  
Author(s):  
Qing Liu ◽  
Zhihai Xie ◽  
Tao Liu ◽  
Jin Fan
Keyword(s):  
Aqueous Solution ◽  
Silica Nanoparticles ◽  
Berberine Hydrochloride ◽  
Fluorimetric Method ◽  
Spectrofluorimetric Method

A simple, green and sensitive spectrofluorimetric method was proposed for the determination of berberine hydrochloride (BRH) in aqueous solution.

Application of Silica Nanoparticles in the Determination of Herbicides in Environmental Water Samples Using Liquid Chromatography-Mass Spectroscopy

2020 ◽  
Vol 16 (5) ◽  
pp. 748-756
Author(s):  
Mir Waqas Alam ◽  
Tentu Nageswara Rao ◽  
Yarasani Prashanthi ◽  
Vourse Sridhar ◽  
Adil Alshoaibi ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Liquid Chromatography ◽  
Silica Nanoparticles ◽  
Solid Phase ◽  
Silica Nanoparticle ◽  
Environmental Water ◽  
Phase Extraction ◽  
Functionalized Nanoparticles ◽  
Supporting Material

Background: Herbicides are very beneficial in the crop yield with the aid of controlling weeds within the agriculture, but several herbicides are chronic in soil. Objective: In this study, nanoparticles and the packages of synthesized novel silica nanoparticles were studied for the preconcentration of herbicides. Methods: These nanoparticles prepared by the Stöber mechanism were purified and functionalized. Nanoparticles thus prepared successfully were used as supporting material for the preconcentration of residues of herbicides in the water. Results: Preconcentration was achieved by preparing the silica-based solid-phase-extraction cartridges. Nanoparticles used for this purpose were within the range of 50-250 nm. An SPE cartridge was prepared by packing 200 mg of silica nanoparticle in the empty cartridge of diameter 5.5 cm and length 0.6 cm in between PTFE frits. Aqueous solutions of 0.1 μg/ml of herbicides were prepared separately, and 10 ml of the solution was passed through the cartridge at the rate of 0.2 ml/min. After passing 10 ml volume of the aqueous solution, residues adsorbed on the cartridge were eluted using 2 ml of acetonitrile. The eluate was injected to determine the herbicide residue adsorbed on the SPE cartridge. Conclusion: In the study, it was found that greater than 90% of the herbicide residues were trapped on silica nanoparticle-based SPE cartridge. An analytical method was developed for the simultaneous determination of these herbicides. The residues were quantified by LC-MS/MS with ESI mode.

A rapid and highly sensitive fluorimetric method for the determination of meloxicam using uranyl acetate

2014 ◽  
Vol 6 (14) ◽  
pp. 5221-5226 ◽  
Author(s):  
Jing Tian ◽  
Chunyan Li ◽  
Shaopu Liu ◽  
Zhongfang Liu ◽  
Jidong Yang ◽  
...  
Keyword(s):  
High Sensitivity ◽  
Uranyl Acetate ◽  
Fluorimetric Method ◽  
Spectrofluorimetric Method ◽  
Highly Sensitive

A novel quick spectrofluorimetric method with high sensitivity and simplicity for determining meloxicam was established based on the interaction of uranyl acetate with meloxicam.

Fluorimetric Method for the Determination of Trace Amounts of Molybdenum Using 2-Hydroxy-1-Naphthaldehydene-p-Aminotoluene

2014 ◽  
Vol 556-562 ◽  
pp. 584-587 ◽  
Author(s):  
Wei Wei Bian
Keyword(s):  
Detection Limit ◽  
Cation Exchange ◽  
Good Precision ◽  
Pig Liver ◽  
Fluorimetric Method ◽  
Ethanol Medium ◽  
Spectrofluorimetric Method ◽  
Highly Sensitive ◽  
Precision And Accuracy

A new fluorescent reagent, 2-hydroxy-1-naphthaldehydene-p-aminotoluene, was synthesized. The fluorescent reaction of this reagent with molybdenum was studied. Based on this chelation, a highly sensitive spectrofluorimetric method was developed for determination of trace amounts of molybdenum in a water-ethanol medium at pH 6.8. Under these conditions, the Mo-HNA complex has excitation and emission maxima at 300 and 380 nm, respectively. The linear range of the method is 0-2μg/L and the detection limit is 0.62μg/L. Interference of other ions was studied. It is necessary to remove the interfering cations through cation exchange. The procedure can be carried out easily and affords good precision and accuracy. This method has been successfully applied to the determination of molybdenum in pig liver and mussels.

The Sensitive Fluorimetric Method for the Determination of Curcumin Using the Enhancement of Mixing Micelle

2014 ◽  
Vol 525 ◽  
pp. 89-92
Author(s):  
Wei Huang ◽  
Feng Wang ◽  
Hong Long Zhu
Keyword(s):  
Aqueous Solution ◽  
Detection Limit ◽  
Fluorescence Intensity ◽  
Sodium Dodecyl ◽  
Sodium Dodecyl Benzene Sulfonate ◽  
Benzene Sulfonate ◽  
Fluorimetric Method ◽  
Dodecyl Benzene Sulfonate

It is found that the fluorescence of curcumin is greatly enhanced by La3+ in the prescence of sodium dodecyl benzene sulfonate (SDBS). Based on this, a sensitive fluorimetric method for the determination of curcumin in aqueous solution is proposed. In the HOAc-NaOAc buffer, the fluorescence intensity of curcumin is proportional to the concentration of curcumin in the range of 0.0074-7.4μg·mL-1 and the detection limit is 3.66ng·mL-1. The actual samples are satisfactorily determined.

scholarly journals Critical flocculation concentration for polyvalent ions using silica nanoparticles; a new version of Schulze-Hardy rule

2020 ◽  
Vol 38 (9-10) ◽  
pp. 435-449
Author(s):  
Rogelio Rodriguez ◽  
Susana Vargas
Keyword(s):  
Aqueous Solution ◽  
Silica Nanoparticles ◽  
Optimal Amount ◽  
Different Types ◽  
Initial Ph ◽  
Correct Determination ◽  
Critical Flocculation Concentration ◽  
The Right ◽  
Flocculation Time

Critical Flocculation Concentration (CFC) is an important quantity because allows to know the optimal amount of flocculant required to remove (adsorb) specific quantities of metal ions in aqueous solution allowing to reduce both, the flocculation time and the excess of unreacted flocculant; this unreacted material produces, by itself, an additional contamination. The results reported here show that the standard Schulze-Hardy-Rule (SHR), based only in the valence z, is not longer valid to obtain the right values of CFC. In this work it is reported a correct determination of CFC for di- and tri-valent ions using different types of silica nanoparticles. Both, the initial pH slope (-pHo) and the valence z are required to determine correctly the CFC. The proposed modified version for CFC is CFC ∝ [(-pHo)z]−1.

Enzymatic colorimetry of lecithin and sphingomyelin in aqueous solution.

1983 ◽  
Vol 29 (8) ◽  
pp. 1513-1517 ◽  
Author(s):  
M W McGowan ◽  
J D Artiss ◽  
B Zak
Keyword(s):  
Aqueous Solution ◽  
Hydrogen Peroxide ◽  
Amniotic Fluid ◽  
Enzymatic Reaction ◽  
Detergent Solution ◽  
Enzymatic Determination ◽  
Red Color ◽  
Hydrolysis Of ◽  
Zwitterionic Detergent

Abstract A procedure for the enzymatic determination of lecithin and sphingomyelin in aqueous solution is described. The phospholipids are first dissolved in chloroform:methanol (2:1 by vol), the solvent is evaporated, and the residue is redissolved in an aqueous zwitterionic detergent solution. The enzymatic reaction sequences of both assays involve hydrolysis of the phospholipids to produce choline, which is then oxidized to betaine, thus generating hydrogen peroxide. The hydrogen peroxide is subsequently utilized in the enzymatic coupling of 4-aminoantipyrine and sodium 2-hydroxy-3,5-dichlorobenzenesulfonate, an intensely red color being formed. The presence of a non-reacting phospholipid enhances the hydrolysis of the reacting phospholipid. Thus we added lecithin to the sphingomyelin standards and sphingomyelin to the lecithin standards. This precise procedure may be applicable to determination of lecithin and sphingomyelin in amniotic fluid.

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