Continuous amperometric hydrogen gas sensing in ionic liquids

The Analyst ◽  
2018 ◽  
Vol 143 (17) ◽  
pp. 4136-4146 ◽  
Author(s):  
Yongan Tang ◽  
Jianxin He ◽  
Xiaoli Gao ◽  
Tianbao Yang ◽  
Xiangqun Zeng

Continuous and real-time ionic liquid based hydrogen gas sensor with high sensitivity, selectivity, speed, accuracy, repeatability and stability.

Author(s):  
Hu Huang ◽  
Jian-Song Zhang ◽  
Weiling Luan ◽  
Shan-Tung Tu ◽  
Shang-Kuo Yang

TE (Thermoelectric) materials have been widely used in clean energy system as low-power generator and Peliter cooler, due to its salient features of being compact, light-weighted, noiseless in operation, highly reliable, and environment friendly. Recently, another application has been explored on TE materials as gas sensors based on Seebeck effect and exothermic reaction of hydrogen oxidation on catalyst. In this paper, a TE hydrogen gas sensor with a simple structure, low energy consumption and a high sensitivity was reported. Bi-Te (bismuth telluride) with a high Seebeck coefficient at room-temperature was deposited onto thin glass substrates by RF magnetron sputtering technology. Four pairs of PN film couples were connected in series to improve the output voltage. Pt/ ACC (Activated Carbon Fiber Cloth) was mounted at the joint of PN couples, acting as catalyst so as to accelerate the oxidation of hydrogen. The influences of reduction temperature and Pt content on the generated temperature difference were investigated. The voltage output and selectivity to combustible gas mixture were measured. Experimental results showed that when exposed to 3vol% H2/ air, as-prepared sensor gave out a high output signal of 33.1mV, and the response time was about 50s with recovery time of 50s.


Author(s):  
Monika Kwoka ◽  
Michal A. Borysiewicz ◽  
Pawel Tomkiewicz ◽  
Anna Piotrowska ◽  
Jacek Szuber

In this paper a novel type of a highly sensitive gas sensor device based on the surface photovoltage effect is described. The developed surface photovoltage gas sensor is based on a reverse Kelvin probe approach. As the active gas sensing electrode the porous ZnO nanostructured thin films are used deposited by the direct current (DC) reactive magnetron sputtering method exhibiting the nanocoral surface morphology combined with an evident surface nonstoichiometry related to the unintentional surface carbon and water vapor contaminations. Among others, the demonstrated SPV gas sensor device exhibits a high sensitivity of 1 ppm to NO2 with a signal to noise ratio of about 50 and a fast response time of several seconds under the room temperature conditions.


2014 ◽  
Vol 2014 ◽  
pp. 1-6 ◽  
Author(s):  
Sweejiang Yoo ◽  
Xin Li ◽  
Yuan Wu ◽  
Weihua Liu ◽  
Xiaoli Wang ◽  
...  

Reduced graphene oxide (rGO) based chemiresistor gas sensor has received much attention in gas sensing for high sensitivity, room temperature operation, and reversible. Here, for the first time, we present a promising chemiresistor for ammonia gas detection based on tannic acid (TA) functionalized and reduced graphene oxide (rGOTA functionalized). Green reductant of TA plays a major role in both reducing process and enhancing the gas sensing properties ofrGOTA functionalized. Our results showrGOTA functionalizedonly selective to ammonia with excellent respond, recovery, respond time, and recovery times.rGOTA functionalizedelectrical resistance decreases upon exposure to NH3where we postulated that it is due to n-doping by TA and charge transfer betweenrGOTA functionalizedand NH3through hydrogen bonding. Furthermore,rGOTA functionalizedhinders the needs for stimulus for both recovery and respond. The combination of greener sensing material and simplicity in overall sensor design provides a new sight for green reductant approach of rGO based chemiresistor gas sensor.


2014 ◽  
Vol 5 (11) ◽  
pp. 4404-4418 ◽  
Author(s):  
Ignacio J. Villar-Garcia ◽  
Sarah Fearn ◽  
Gilbert F. De Gregorio ◽  
Nur L. Ismail ◽  
Florence J. V. Gschwend ◽  
...  

We have identified elements present in the ionic liquid–vacuum outer atomic surface of 23 ionic liquids using high sensitivity low-energy ion scattering (LEIS), a very surface sensitive technique.


RSC Advances ◽  
2015 ◽  
Vol 5 (72) ◽  
pp. 58371-58392 ◽  
Author(s):  
Abdul Rehman ◽  
Xiangqun Zeng

Linking ionic liquid interface designs to specific device protocols to address analytical challenges in gas sensing.


Author(s):  
Waraporn Sucharitakul ◽  
Anupong Sukee ◽  
Pimchanok Leuasoongnoen ◽  
Mati Horprathum ◽  
Tossaporn Lertvanithphol ◽  
...  

Abstract Gas sensing technology is currently applied in a variety of applications. In medical applications, gas sensors can be used for the detection of the biomarker in various diseases, metabolic disorders, diabetes mellitus, asthma, renal, liver diseases, and lung cancer. In this study, we present acetone sensing characteristics of Si-doped WO3 nanorods prepared by a DC reactive magnetron co-sputtering with an oblique-angle deposition (OAD) technique. The composition of Si-doped in WO3 has been studied by varying the electrical input power applied to the Si sputtered target. The nanorods film was constructed at the glancing angle of 85°. After deposition, the films were annealed at 400 ◦C for 4 hrs in the air. The microstructures and phases of the materials were characterized by X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and field-emission scanning electron microscopy (FESEM). The results showed that 1.43 wt% Si-doped WO3 thin film exhibited the maximum response of 5.92 towards 100 ppm of acetone at performing temperature (350 °C), purifying dry air carrier. The process exposed in this work demonstrated the potential of high sensitivity acetone gas sensor at low concentration and may be used as an effective tool for diabetes non-invasive monitoring.


2020 ◽  
Vol 16 (2) ◽  
pp. 187-195
Author(s):  
Tang-Yu Lai ◽  
Te-Hua Fang ◽  
Yu-Jen Hsiao ◽  
En-Yu Kuo

Background:: A sensing material of zinc oxide (ZnO) was investigated for its use in the electrospun nanofibers for gas sensing. The metal oxide semiconductor gas sensor response is caused by the oxygen that undergoes a chemical reaction on the surface of an oxide, resulting in a change in the measured resistance. Objective:: One-dimensional nanofibers gas sensor have high sensitivity and diverse selectivity. Methods:: One-dimensional nanofiber by an electrospinning method was collected and a sensing membrane was formed. In addition, the gas sensing mechanism was discussed and verified by X-ray photoelectron spectroscopy (XPS). Results:: The ZnO nanofiber membrane had an optimum crystalline phase with a lattice spacing of 0.245 nm and a non-woven fabric structure at a calcination temperature of 500°C, whereas the nanofiber diameter and membrane thickness were about 100 nm and 8 μm, respectively. At an operating temperature of 200°C, the sensing material exhibited good recovery and reproducibility in response to Carbon monoxide (CO), and the concentration was also highly discernible. In addition, the reduction in the peak of OIII at 531.5 to 532.5 eV according to the analysis of XPS was consistent with the description of the sensing mechanism. Conclusion:: The gas sensor of ZnO nanofiber membranes has high sensitivity and diverse selectivity, which can be widely applied in potential applications in various sensors and devices.


2020 ◽  
Vol 65 ◽  
pp. 145-155
Author(s):  
Hadi Riyahi Madvar ◽  
Zoheir Kordrostami ◽  
Samaneh Hamedi

A resistive ethanol gas sensor with a high sensitivity has been proposed. The fabricated gas sensor has a very promising response and recovery at room temperature. The proposed sensor has been fabricated by depositing sensitive nanostructured material on printed circuit board interdigitated electrodes. As the sensitive material, ZnO nanorods of high uniformity have been synthesized by hydrothermal method and then decorated by PbS nanoparticles. The synthesized decorated nanorods were characterized by X-ray diffraction and scanning electron microscope which confirmed the formation of the desired nanostructures. The ethanol gas sensing properties of the ZnO nanorods decorated with PdS nanoparticles was measured in a test chamber. The minimum ethanol concentration detected by the sensor has been 10 ppm. The results showed the higher sensitivity of the proposed sensor to the ethanol at room temperature compared to similar works.


Sign in / Sign up

Export Citation Format

Share Document