A stable metal cluster-metalloporphyrin MOF with high capacity for cationic dye removal

2018 ◽  
Vol 6 (36) ◽  
pp. 17698-17705 ◽  
Author(s):  
Zheng Wang ◽  
Jian-Hua Zhang ◽  
Ji-Jun Jiang ◽  
Hai-Ping Wang ◽  
Zhang-Wen Wei ◽  
...  

A super stable anionic MOF was built from Cu5-cluster and Cu-porphyrin to exhibit 2D-HOF/3D-MOF interpenetrated topology, showing high adsorption capacity for cationic dyes.

RSC Advances ◽  
2019 ◽  
Vol 9 (47) ◽  
pp. 27674-27683 ◽  
Author(s):  
Xue Dong ◽  
Yongcen Lin ◽  
Yuqin Ma ◽  
Lang Zhao

The Ce-doped UiO-67 nanocrystals were successfully synthesized via a one-step hydrothermal method. Ce doping increases the negative charge on the surface of the material, thus the adsorbent exhibits high adsorption capacity to cationic dyes.


2021 ◽  
Author(s):  
Liangzhi Qiao ◽  
Kaifeng Du

Abstract It remains a formidable challenge to construct high-performance haemoperfusion adsorbents with fast adsorption kinetic and high adsorption capacity for efficiently removing bilirubin from human blood. In this work, we report a facile yet efficient strategy to manufacture lysine-modified macroporous cellulose/carbon nanotube microspheres (LMCMs) by surfactant micelles swelling strategy followed by modification with lysine. The macroporous structure not only provides wide channels for fast mass transfer, but also shortens the diffusion path into meso/micropores, increasing the accessibility of mesopores and micropores. The experimental results reveal that LMCMs can remove bilirubin with fast adsorption kinetic (> 90% of its equilibrium uptake within 2h) and high adsorption capacity of 338.14 mg/g. More importantly, the adsorbent can remove about 79% of bilirubin in rabbit serum, and the bilirubin concentration decreases from 213.36 mg/L to small than 45.78 mg/L within 2h, indicating a very appealing application prospect.


2014 ◽  
Vol 1 (2) ◽  
pp. 172-180 ◽  
Author(s):  
Shiyao Zhu ◽  
Shihui Jiao ◽  
Ziwei Liu ◽  
Guangsheng Pang ◽  
Shouhua Feng

The excellent adsorption performance of CuZn hydroxyl double salts results from both the surface adsorption and interlayer ion exchange.


RSC Advances ◽  
2019 ◽  
Vol 9 (37) ◽  
pp. 21075-21085 ◽  
Author(s):  
Zhenyu Yuan ◽  
Jie Wang ◽  
Yiming Wang ◽  
Qian Liu ◽  
Yujie Zhong ◽  
...  

A biocompatible Dex-MA/PAA hydrogel was prepared through copolymerization of glycidyl methacrylate substituted dextran (Dex-MA) with acrylic acid (AA), which was applied as the adsorbent to remove cationic dyes from aqueous solutions.


1999 ◽  
Vol 40 (7) ◽  
pp. 109-116 ◽  
Author(s):  
M. H. Ansari ◽  
A. M. Deshkar ◽  
P. S. Kelkar ◽  
D. M. Dharmadhikari ◽  
M. Z. Hasan ◽  
...  

Steamed Hoof Powder (SHP), size < 53μ, was observed to have high adsorption capacity for Hg(II) with >95% removal from a solution containing 100 mg/L of Hg(II) with only 0.1% (W/V) concentration of SHP. The SHP has good settling properties and gives clear and odour free effluent. Studies indicate that pH values between 2 and 10 have no effect on the adsorption of Hg(II) on SHP. Light metal ions like Na+, K+, Ca2+ and Mg2+ up to concentrations of 500 mg/L and heavy metals like Cu2+, Zn2+, Cd2+, Co2+, Pb2+, Ni2+, Mn2+, Cr3+, Cr6+, Fe2+ and Fe3+ up to concentrations of 100 mg/L do not interfere with the adsorption process. Anions like sulphate, acetate and phosphate up to concentrations of 200 mg/L do not interfere. Chloride interferes in the adsorption process when Hg(II) concentration is above 9.7 mg/L. The adsorption equilibrium was established within two hours. Studies indicate that adsorption occurs on the surface sites of the adsorbent.


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