CO2-switchable Pickering emulsions: efficient and tunable interfacial catalysis for alcohol oxidation in biphasic systems

2019 ◽  
Vol 55 (74) ◽  
pp. 11079-11082 ◽  
Author(s):  
Jun Tang ◽  
Shixiong Cao ◽  
Jianli Wang

CO2-responsive Pickering emulsion systems were used as an efficient platform for in situ separation and reuse of catalysts in biphasic reactions.

Soft Matter ◽  
2015 ◽  
Vol 11 (18) ◽  
pp. 3512-3529 ◽  
Author(s):  
Juntao Tang ◽  
Patrick James Quinlan ◽  
Kam Chiu Tam

Pickering emulsions with stimuli-responsive properties have, in recent years, received a considerable amount of attention. This paper provides a concise and comprehensive review of Pickering emulsion systems that possess the ability to respond to an array of external triggers, including pH, temperature, CO2concentration, light intensity, ionic strength, and magnetic field intensity.


2016 ◽  
Vol 4 (4) ◽  
pp. 736-744 ◽  
Author(s):  
Lei Ouyang ◽  
Dingyi Li ◽  
Lihua Zhu ◽  
Wenwen Yang ◽  
Heqing Tang

β-CD modified plasmonic Pickering emulsions were synthesized for interfacial reaction monitoring as well as for kinetic study.


Author(s):  
Haisheng Xie ◽  
Wenyu Zhao ◽  
Daniel Chikere Ali ◽  
Xuehong Zhang ◽  
Zhilong Wang

The Pickering emulsion interface is an exceptional habitat for bacteria to grow by simultaneously utilizing hydrophobic and hydrophilic chemicals.


2021 ◽  
Author(s):  
Shenghua Ma ◽  
Wei Zong ◽  
Xiaojun Han

Schematic diagram of interfacial catalysis reactions by MRGO–Pd Pickering emulsion.


2017 ◽  
Vol 19 (19) ◽  
pp. 4552-4562 ◽  
Author(s):  
Bingyu Yang ◽  
Loïc Leclercq ◽  
Jean-Marc Clacens ◽  
Véronique Nardello-Rataj

Silica nanoparticles have been designed by surface modification to stabilize solventless catalytic Pickering emulsions for effective biodiesel production.


Polymers ◽  
2018 ◽  
Vol 10 (10) ◽  
pp. 1071 ◽  
Author(s):  
Yu-Jin Cho ◽  
Dong-Min Kim ◽  
In-Ho Song ◽  
Ju-Young Choi ◽  
Seung-Won Jin ◽  
...  

A pyromellitic dianhydride (PMDA) and 4,4′-oxydianiline (ODA)-based oligoimide (PMDA-ODA) was synthesized by a one-step procedure using water as a solvent. The PMDA-ODA particles showed excellent partial wetting properties and were stably dispersed in both water and oil phases. A stable dispersion was not obtained with comparison PMDA-ODA particles that were synthesized by a conventional two-step method using an organic solvent. Both oil-in-water and water-in-oil Pickering emulsions were prepared using the oligoimide particles synthesized in water, and the size of the emulsion droplet was controlled based on the oligoimide particle concentration. The oligoimide particles were tested to prepare Pickering emulsions using various kinds of oils. The oil-in-water Pickering emulsions were successfully applied to prepare microcapsules of the emulsion droplets. Our new Pickering emulsion stabilizer has the advantages of easy synthesis, no need for surface modification, and the capability of stabilizing both oil-in-water and water-in-oil emulsions.


2017 ◽  
Vol 53 (61) ◽  
pp. 8537-8540 ◽  
Author(s):  
Lei Wang ◽  
Ping Wen ◽  
Xiaoman Liu ◽  
Yuting Zhou ◽  
Mei Li ◽  
...  

Multi-compartmentalized biphasic proteinosomes were self-assembled using a single-step double Pickering emulsion procedure, and exploited for enzyme-mediated interfacial catalysis, polysaccharide shell templating, and hydrogel functionalization.


2020 ◽  
Vol 19 (2) ◽  
pp. 169-178
Author(s):  
D Prasanthi ◽  
N Varsha Priya ◽  
Amoolya Chennuri ◽  
PK Lakshmi

Emulsifier-free, particle-stabilised emulsions called Pickering emulsions of fluconazole for topical delivery, were studied using Taguchi L9 orthogonal array (OA) design. Formulations were prepared by homogenization method, using bentonite in the concentration range of 2-4% w/v, oil phase (coconut oil, oleic acid, sesame oil). In Taguchi L9 OA experimental design, independent variables (oil phase & concentration of bentonite) effect on dependent variables (drug content & release rate) was studied. All the formulations have shown good physicochemical properties. The PS3 formulation containing sesame oil and 4% bentonite was optimized as particle size was found to be 758.0 nm, zeta potential -48 mv, with Q8 of 166.70±0.15μg/cm2, flux of 17.33±0.02 μg/cm2/hr, permeability coefficient of 3.46±0.015 cm/hr×10-3 and skin content of 4.01±0.24 mg/g. The formulations were stable and non-irritant. Hence pickering emulsion of fluconazole using sesame oil can be used for topical delivery as the drug release was maintained at the localised site. Dhaka Univ. J. Pharm. Sci. 19(2): 169-178, 2020 (December)


Sign in / Sign up

Export Citation Format

Share Document