Lithium, sodium, potassium and calcium amine-bis(phenolate) complexes in the ring-opening polymerization of rac-lactide

2020 ◽  
Vol 49 (5) ◽  
pp. 1531-1544 ◽  
Author(s):  
Katalin Devaine-Pressing ◽  
Fabio J. Oldenburg ◽  
Jan P. Menzel ◽  
Maximilian Springer ◽  
Louise N. Dawe ◽  
...  

Li, Na, K and Ca complexes capable of rac-lactide polymerization in both the melt and in solution were synthesized. MALDI-TOF MS showed mainly cyclic PLA was obtained even in the presence of an alcohol co-initiator.

2016 ◽  
Vol 6 (21) ◽  
pp. 7763-7772 ◽  
Author(s):  
Xiao-Qing Li ◽  
Bin Wang ◽  
He-Yuan Ji ◽  
Yue-Sheng Li

A plausible mechanism for ring-opening polymerization of lactide catalyzed by Zn(C6F5)2-based Lewis pairs was proposed based on in situ NMR and MALDI-TOF MS analyses. Several experimental results show very good consistency with the proposed mechanism.


2015 ◽  
Vol 44 (27) ◽  
pp. 12365-12375 ◽  
Author(s):  
Katalin Devaine-Pressing ◽  
Joshua H. Lehr ◽  
Michelle E. Pratt ◽  
Louise N. Dawe ◽  
Amy A. Sarjeant ◽  
...  

Magnesium complexes capable of rac-lactide polymerization in both the melt and in solution at elevated temperatures were synthesized. End-group analysis by MALDI-TOF showed both linear and cyclic PLA.


2007 ◽  
Vol 177 (4S) ◽  
pp. 297-297
Author(s):  
Kristina Schwamborn ◽  
Rene Krieg ◽  
Ruth Knüchel-Clarke ◽  
Joachim Grosse ◽  
Gerhard Jakse

Planta Medica ◽  
2016 ◽  
Vol 81 (S 01) ◽  
pp. S1-S381
Author(s):  
L Fougère ◽  
D Da Silva ◽  
E Destandau ◽  
C Elfakir
Keyword(s):  

2017 ◽  
Author(s):  
M Erhard ◽  
M Metzner ◽  
D Köhler-Repp ◽  
B Köhler ◽  
R Storandt
Keyword(s):  

2019 ◽  
Author(s):  
M Hooshyari ◽  
H Rezadoost ◽  
P Ghezellou ◽  
A Ghassempour

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