H2O2/periodate (IO4−): a novel advanced oxidation technology for the degradation of refractory organic pollutants

2019 ◽  
Vol 5 (6) ◽  
pp. 1113-1123 ◽  
Author(s):  
Nor Elhouda Chadi ◽  
Slimane Merouani ◽  
Oualid Hamdaoui ◽  
Mohammed Bouhelassa ◽  
Muthupandian Ashokkumar

H2O2/periodate: a novel advanced oxidation process.

2011 ◽  
Vol 64 (11) ◽  
pp. 2230-2238 ◽  
Author(s):  
Y. Lester ◽  
D. Avisar ◽  
I. Gozlan ◽  
H. Mamane

Water and wastewater effluents contain a vast range of pharmaceutical chemicals. The present study aims to determine the potential of the advanced oxidation technology UV/H2O2/O3 and its sub-processes (i.e. UV, UV/H2O2, UV/O3, O3 and H2O2/O3) for the degradation of the antibiotics ciprofloxacin (CIP) and trimethoprim (TMP), and the antineoplastic drug cyclophosphamide (CPD) from water. Creating AOP conditions improved in most cases the degradation rate of the target compounds (compared with O3 and UV alone). H2O2 concentration was found to be an important parameter in the UV/H2O2 and H2O2/O3 sub-processes, acting as •OH initiator as well as •OH scavenger. Out of the examined processes, O3 had the highest degradation rate for TMP and H2O2/O3 showed highest degradation rate for CIP and CPD. The electrical energy consumption for both CIP and CPD, as calculated using the EEO parameter, was in the following order: UV > UV/O3 > UV/H2O2/O3 > O3 > H2O2/O3. Whereas for TMP O3 was shown to be the most electrical energy efficient. Twelve degradation byproducts were identified following direct UV photolysis of CIP.


RSC Advances ◽  
2022 ◽  
Vol 12 (4) ◽  
pp. 1904-1913
Author(s):  
Jinling Zhang ◽  
Xin Jin ◽  
Hui Zhao ◽  
Chaohe Yang

A synergistic advanced oxidation process was constructed to degrade the organic pollutants in spent sulfuric acid with apricot shell-derived biochar as the catalyst. It realized the effect of treating waste with waste.


2017 ◽  
Vol 314 ◽  
pp. 240-248 ◽  
Author(s):  
Pengchao Xie ◽  
Yizhou Guo ◽  
Yiqun Chen ◽  
Zongping Wang ◽  
Ran Shang ◽  
...  

2013 ◽  
Vol 2013 ◽  
pp. 1-14 ◽  
Author(s):  
Chuan Wang ◽  
Hong Liu ◽  
Yanzhen Qu

Recent years have witnessed a rapid accumulation of investigations on TiO2-based photocatalysis, which poses as a greatly promising advanced oxidation technology for water purification. As the ability of this advanced oxidation process is well demonstrated in lab and pilot scales to decompose numerous recalcitrant organic compounds and microorganism as well in water, further overpass of the hurdles that stand before the real application has become increasingly important. This review focuses on the fundamentals that govern the actual water purification process, including the fabrication of engineered TiO2-based photocatalysts, process optimization, reactor design, and economic consideration. The state of the art of photocatalyst preparation, strategies for process optimization, and reactor design determines the enhanced separation of photo-excited electron-hole (e-h) pairs on the TiO2surface. For the process optimization, the kinetic analysis including the rate-determining steps is in need. For large-scale application of the TiO2-based photocatalysis, economics is vital to balance the fundamentals and the applied factors. The fundamentals in this review are addressed from the perspective of a bridge to the real applications. This review would bring valuably alternative paradigm to the scientists and engineers for their associated research and development activities with an attempt to push the TiO2-based photocatalysis towards industrially feasible applications.


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