Synergistic advanced oxidation process for enhanced degradation of organic pollutants in spent sulfuric acid over recoverable apricot shell-derived biochar catalyst

A synergistic advanced oxidation process was constructed to degrade the organic pollutants in spent sulfuric acid with apricot shell-derived biochar as the catalyst. It realized the effect of treating waste with waste.

Effect of fibre type and content on performance of bio-based concrete containing heat-treated apricot shell

The heat-treated apricot shell can be utilized as coarse aggregates for producing sustainable bio-based lightweight concrete with good compressive strength but poor tensile strength. In order to improve the tensile properties of apricot shell concrete (ASC), the effects of polypropylene (PP) fibre, glass (G) fibre and basalt (B) fibre at various volume fractions (Vf) (0.25%, 0.5% and 0.75%) on the performance of ASC were investigated. The results indicated that the fibre type had no significant effect on the physical properties of ASC such as slump, density, water absorption and permeable porosity. However, the slump of ASC decreases with an increase in fibre content. The B fibre has a better improvement in mechanical properties than the PP fibre and G fibre thanks to the better elastic modulus and tensile strength. When the Vf was 0.5%, the compressive strength, splitting tensile strength, flexural strength and modulus of elasticity of ASC reinforced with B fibre were increased by 16.7%, 29.1%, 29.2%, and 18.1%, respectively, compared to ASC without any fibres. The magnesium sulfate attack results showed that the incorporation of the B fibre decreased the mass loss and compressive strength of ASC exposed to a MgSO4 solution for 6 months because the fibre arrested the microcracks caused by the expansive stress. It is concluded that the mechanical properties of bio-based ASC and its resistance to magnesium sulfate attack can be significantly improved by incorporating 0.5% B fibre.

Development of new carbon supports for rhodium in the creation of benzene hydrogenation catalysts

In this article, the results of hydrogenation of benzene and toluene on rhodium catalysts supported on activated carbons are presented by obtaining from rice husk (RSHAU) and apricot shell (AKAU) in ethanol and the temperature range of 40 - 80 ◦ C hydrogen pressure of 20 - 100 atm. It is shown that the best carrier is AKAU, where the strength of the starting material is preserved while RSHAU is volatile and difficult to separate from the reaction mass. The activity of the Rh / AKAU catalyst is comparable to that of Rh supported on sibunite (Siberian carbon carrier) and birch activated carbon (BAU), and on Rh / RSHAU the reaction rate is five times lower. The characteristics of the catalysts are studied by means of Brunauer-Emmett-Teller (BET) and scanning electron microscope (SEM) methods. The composition of the catalyst, the kinetic parameters of the process are determined the reaction order with respect to hydrogen and benzene, and the activation energy.