scholarly journals Manifestation of dipole-induced disorder in self-assembly of ferroelectric and ferromagnetic nanocubes

Nanoscale ◽  
2019 ◽  
Vol 11 (15) ◽  
pp. 7293-7303 ◽  
Author(s):  
Dmitry Zablotsky ◽  
Leonid L. Rusevich ◽  
Guntars Zvejnieks ◽  
Vladimir Kuzovkov ◽  
Eugene Kotomin

Long-range positional and orientational correlations of nanocubes in self-assembled mesocrystals are highly sensitive to the presence of dipoles.

2016 ◽  
Vol 52 (48) ◽  
pp. 7564-7567 ◽  
Author(s):  
Keren Zhang ◽  
Samantha J. Talley ◽  
Ya Peng Yu ◽  
Robert B. Moore ◽  
Mitsuhiro Murayama ◽  
...  

ABC triblock copolymers bearing adenine- and thymine-functionalized external blocks self-assembled into long-range, ordered lamellar microphase-separated morphologies on non-patterned substrates.


2016 ◽  
Vol 40 (5) ◽  
pp. 4625-4634 ◽  
Author(s):  
Elaine Y. S. Oliveira ◽  
Ralf Bode ◽  
Martha V. Escárcega-Bobadilla ◽  
Gustavo A. Zelada-Guillén ◽  
Gerhard Maier

Supramolecular self-assembly and anisotropic patchiness generate long-range networks in polymer-grafted carbon nanotubes, opening new possibilities using industrially attractive processes.


Soft Matter ◽  
2020 ◽  
Vol 16 (40) ◽  
pp. 9183-9187
Author(s):  
Camille Blayo ◽  
Elaine A. Kelly ◽  
Judith E. Houston ◽  
Nikul Khunti ◽  
Nathan P. Cowieson ◽  
...  

A cationic azobenzene photosurfactant (AzoTAB) forms self-assembled structures with long-range order and optical anisotropy at high concentrations. These high-concentration mesophases are lost or disrupted with UV irradiation.


RSC Advances ◽  
2015 ◽  
Vol 5 (105) ◽  
pp. 86522-86528 ◽  
Author(s):  
Chih-Wei Chiu ◽  
Po-Hsien Lin

The use of self-assembled novel flower-like microstructures as SERS substrates allowed high-efficiency detection of adenine molecules from DNA.


2019 ◽  
Vol 7 (21) ◽  
pp. 6308-6316 ◽  
Author(s):  
Zelio Fusco ◽  
Renheng Bo ◽  
Yuling Wang ◽  
Nunzio Motta ◽  
Hongjun Chen ◽  
...  

A thermophoretically driven Au aerosol deposition process is used for the self-assembly of thin films consisting of plasmonic nano-islands (NIs) with a controllable and highly reproducible degree of disorder resulting in long-range periodicity with self-similar properties and stochastically distributed hot-spots, benefitting their applications as SERS substrates.


2015 ◽  
Vol 643 ◽  
pp. 3-7
Author(s):  
Hui Zhang ◽  
Miftakhul Huda ◽  
Jing Liu ◽  
Yu Long Zhang ◽  
Tao Jin ◽  
...  

We demonstrate the possibility of forming long-range-ordered self-assembled nanodot arrays with dots size of 5 nm and pitches of 10×7.5 nm2using guide line templates and low molecular weight (MW) (4,700–1,200 g/mol) poly (styrene)-poly (dimethylsiloxane) (PS-PDMS) for application in ultrahigh density patterned media. The self-assembled PDMS nanodots are controlled in a long range by varying the heights and gaps of the guide lines. Adopting the 14-nm-high resist guide lines with suitable gaps, the 5-nm-sized and 10×7.5 nm2-pitched self-assembled nanodots were ordered in maximum 7 dot arrays with long-range order. The experimental results demonstrate that the method is possible for achieving patterned media with magnetic recording densities of 8.6 Tbit/in.2using low MW PS-PDMS and slim guide lines.


MRS Advances ◽  
2020 ◽  
Vol 5 (64) ◽  
pp. 3507-3520
Author(s):  
Chunhui Dai ◽  
Kriti Agarwal ◽  
Jeong-Hyun Cho

AbstractNanoscale self-assembly, as a technique to transform two-dimensional (2D) planar patterns into three-dimensional (3D) nanoscale architectures, has achieved tremendous success in the past decade. However, an assembly process at nanoscale is easily affected by small unavoidable variations in sample conditions and reaction environment, resulting in a low yield. Recently, in-situ monitored self-assembly based on ion and electron irradiation has stood out as a promising candidate to overcome this limitation. The usage of ion and electron beam allows stress generation and real-time observation simultaneously, which significantly enhances the controllability of self-assembly. This enables the realization of various complex 3D nanostructures with a high yield. The additional dimension of the self-assembled 3D nanostructures opens the possibility to explore novel properties that cannot be demonstrated in 2D planar patterns. Here, we present a rapid review on the recent achievements and challenges in nanoscale self-assembly using electron and ion beam techniques, followed by a discussion of the novel optical properties achieved in the self-assembled 3D nanostructures.


2020 ◽  
Author(s):  
Daniel B. Straus ◽  
Robert J. Cava

The design of new chiral materials usually requires stereoselective organic synthesis to create molecules with chiral centers. Less commonly, achiral molecules can self-assemble into chiral materials, despite the absence of intrinsic molecular chirality. Here, we demonstrate the assembly of high-symmetry molecules into a chiral van der Waals structure by synthesizing crystals of C<sub>60</sub>(SnI<sub>4</sub>)<sub>2</sub> from icosahedral buckminsterfullerene (C<sub>60</sub>) and tetrahedral SnI4 molecules through spontaneous self-assembly. The SnI<sub>4</sub> tetrahedra template the Sn atoms into a chiral cubic three-connected net of the SrSi<sub>2</sub> type that is held together by van der Waals forces. Our results represent the remarkable emergence of a self-assembled chiral material from two of the most highly symmetric molecules, demonstrating that almost any molecular, nanocrystalline, or engineered precursor can be considered when designing chiral assemblies.


2021 ◽  
Vol 11 (7) ◽  
pp. 3254
Author(s):  
Marco Pisco ◽  
Francesco Galeotti

The realization of advanced optical fiber probes demands the integration of materials and structures on optical fibers with micro- and nanoscale definition. Although researchers often choose complex nanofabrication tools to implement their designs, the migration from proof-of-principle devices to mass production lab-on-fiber devices requires the development of sustainable and reliable technology for cost-effective production. To make it possible, continuous efforts are devoted to applying bottom-up nanofabrication based on self-assembly to decorate the optical fiber with highly ordered photonic structures. The main challenges still pertain to “order” attainment and the limited number of implementable geometries. In this review, we try to shed light on the importance of self-assembled ordered patterns for lab-on-fiber technology. After a brief presentation of the light manipulation possibilities concerned with ordered structures, and of the new prospects offered by aperiodically ordered structures, we briefly recall how the bottom-up approach can be applied to create ordered patterns on the optical fiber. Then, we present un-attempted methodologies, which can enlarge the set of achievable structures, and can potentially improve the yielding rate in finely ordered self-assembled optical fiber probes by eliminating undesired defects and increasing the order by post-processing treatments. Finally, we discuss the available tools to quantify the degree of order in the obtained photonic structures, by suggesting the use of key performance figures of merit in order to systematically evaluate to what extent the pattern is really “ordered”. We hope such a collection of articles and discussion herein could inspire new directions and hint at best practices to fully exploit the benefits inherent to self-organization phenomena leading to ordered systems.


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