A bi-component supramolecular gel for selective fluorescence detection and removal of Hg2+ in water

Soft Matter ◽  
2019 ◽  
Vol 15 (46) ◽  
pp. 9547-9552 ◽  
Author(s):  
Hai-Long Yang ◽  
Xiao-Wen Sun ◽  
You-Ming Zhang ◽  
Zhong-Hui Wang ◽  
Wei Zhu ◽  
...  

A bi-component supramolecular gel (RQ) was successfully constructed by the assembly of the gelators R and Q. The obtained the RQ exhibits excellent self-healing property. Interestingly, the RQ has been successfully applied in selective fluorescent detection and removal of Hg2+ in water.

Materials ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 869
Author(s):  
Minghua Wei ◽  
Shaopeng Wu ◽  
Haiqin Xu ◽  
Hechuan Li ◽  
Chao Yang

Steel slag is the by-product of the steelmaking industry, the negative influences of which prompt more investigation into the recycling methods of steel slag. The purpose of this study is to characterize steel slag filler and study its feasibility of replacing limestone filler in asphalt concrete by evaluating the resistance of asphalt mastic under various aging methods. Firstly, steel slag filler, limestone filler, virgin asphalt, steel slag filler asphalt mastic and limestone filler asphalt mastic were prepared. Subsequently, particle size distribution, surface characterization and pore characterization of the fillers were evaluated. Finally, rheological property, self-healing property and chemical functional groups of the asphalt mastics with various aging methods were tested via dynamic shear rheometer and Fourier transform infrared spectrometer. The results show that there are similar particle size distributions, however, different surface characterization and pore characterization in the fillers. The analysis to asphalt mastics demonstrates how the addition of steel slag filler contributes to the resistance of asphalt mastic under the environment of acid and alkaline but is harmful under UV radiation especially. In addition, the pore structure in steel slag filler should be a potential explanation for the changing resistance of the asphalt mastics. In conclusion, steel slag filler is suggested to replace limestone filler under the environment of acid and alkaline, and environmental factor should be taken into consideration when steel slag filler is applied to replace natural fillers in asphalt mastic.


The Analyst ◽  
2021 ◽  
Vol 146 (20) ◽  
pp. 6297-6305
Author(s):  
Qinglan Miao ◽  
Ji Qi ◽  
Yuanyuan Li ◽  
Xinxia Fan ◽  
Dongmei Deng ◽  
...  

A novel paper-based chip that anchored zinc-doped carbon dots was constructed for sensitive and stable fluorescent detection of Cu2+. Zn doping increased the active sites for simplifying the modification of carbon dots.


2021 ◽  
Vol 28 (3) ◽  
Author(s):  
Chenghao Dai ◽  
Xijuan Cao ◽  
Kai Gou ◽  
Qiyan Yin ◽  
Binjie Du ◽  
...  

Author(s):  
Chao Zhou ◽  
Juntao Zhou ◽  
Xiaoqing Ma ◽  
Dicky Pranantyo ◽  
Jingjing Li ◽  
...  

2012 ◽  
Vol 18 (26) ◽  
pp. 8057-8063 ◽  
Author(s):  
Pathik Sahoo ◽  
Ravish Sankolli ◽  
Hee-Young Lee ◽  
Srinivasa R. Raghavan ◽  
Parthasarathi Dastidar

Sensors ◽  
2021 ◽  
Vol 21 (11) ◽  
pp. 3917
Author(s):  
Jong-Dae Kim ◽  
Chan-Young Park ◽  
Yu-Seop Kim ◽  
Ji-Soo Hwang

Most existing commercial real-time polymerase chain reaction (RT-PCR) instruments are bulky because they contain expensive fluorescent detection sensors or complex optical structures. In this paper, we propose an RT-PCR system using a camera module for smartphones that is an ultra small, high-performance and low-cost sensor for fluorescence detection. The proposed system provides stable DNA amplification. A quantitative analysis of fluorescence intensity changes shows the camera’s performance compared with that of commercial instruments. Changes in the performance between the experiments and the sets were also observed based on the threshold cycle values in a commercial RT-PCR system. The overall difference in the measured threshold cycles between the commercial system and the proposed camera was only 0.76 cycles, verifying the performance of the proposed system. The set calibration even reduced the difference to 0.41 cycles, which was less than the experimental variation in the commercial system, and there was no difference in performance.


Polymers ◽  
2018 ◽  
Vol 10 (10) ◽  
pp. 1173 ◽  
Author(s):  
Jookyeong Lee ◽  
Hwi Moon ◽  
Keewook Paeng ◽  
Changsik Song

We induced a terpyridine moiety into a norbornene-based polymer to demonstrate its self-healing property, without an external stimulus, such as light, heat, or healing agent, using metal–ligand interactions. We synthesized terpyridine incorporated norbornene-based polymers using a ring-opening metathesis polymerization. The sol state of diluted polymer solutions was converted into supramolecular assembled gels, through the addition of transition metal ions (Ni2+, Co2+, Fe2+, and Zn2+). In particular, a supramolecular complex gel with Zn2+, which is a metal with a lower binding affinity, demonstrated fast self-healing properties, without any additional external stimuli, and its mechanical properties were completely recovered.


2011 ◽  
Vol 105 (3) ◽  
pp. 805-809 ◽  
Author(s):  
G. Scheltjens ◽  
J. Brancart ◽  
I. De Graeve ◽  
B. Van Mele ◽  
H. Terryn ◽  
...  

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