An in situ electrochemical oxidation strategy for formation of nanogrid-shaped V3O7·H2O with enhanced zinc storage properties

2019 ◽  
Vol 7 (44) ◽  
pp. 25262-25267 ◽  
Author(s):  
Ziyi Cao ◽  
Hang Chu ◽  
Hong Zhang ◽  
Yuancai Ge ◽  
Raizel Clemente ◽  
...  

Rational design and synthesis of cathode materials with a well-defined nanostructure and superior performances have always been of paramount importance for rechargeable zinc ion batteries.

2018 ◽  
Vol 433 ◽  
pp. 983-987 ◽  
Author(s):  
Nao Han ◽  
Yuguo Xia ◽  
Yanyang Han ◽  
Xiuling Jiao ◽  
Dairong Chen

Author(s):  
Jiaqi Yu ◽  
Daoping Cai ◽  
Junhui Si ◽  
Hongbing Zhan ◽  
Qian-Ting Wang

The development of high-performance cathode materials is of great importance for aqueous alkaline Zn batteries (AZBs) but also remains great challenging. Herein, we demonstrate the rational design and synthesis of...


2019 ◽  
Vol 7 (30) ◽  
pp. 17854-17866 ◽  
Author(s):  
Jun Long ◽  
Jinxing Gu ◽  
Zhanhong Yang ◽  
Jianfeng Mao ◽  
Junnan Hao ◽  
...  

Aqueous zinc ion batteries (ZIBs) are emerging as a highly promising alternative technology for grid-scale applications where high safety, environmental-friendliness, and high specific capacities are needed.


Author(s):  
Dongxiao Xu ◽  
Hong Zhang ◽  
Ziyi Cao ◽  
Lipeng Wang ◽  
Zhuolin Ye ◽  
...  

It has always been the principal purpose to explore cathode materials for achieving high-performance rechargeable zinc ion batteries through rational design and highly efficient synthesis. Based on the combination of...


Nanoscale ◽  
2021 ◽  
Author(s):  
Chunfa Lin ◽  
Fenqiang Qi ◽  
Huilong Dong ◽  
Xiao Li ◽  
Chunping Shen ◽  
...  

The polyethylene glycol pre-intercalated vanadium oxide composites deliver superior zinc-ion storage properties with high specific capacity, stable cycling capability, excellent rate and low-temperature performance.


2015 ◽  
Vol 3 (46) ◽  
pp. 23368-23375 ◽  
Author(s):  
Lin Hu ◽  
Jinlong Yang ◽  
Ibrahim Saana Amiinu ◽  
Xiaochun Kang ◽  
Wei Zhang ◽  
...  

The kinetics towards charge transfer and lithium ion diffusion are effectively enhanced with in situ adding small amounts of LiFeBO3, leading to a remarkably improved charge–discharge performance of Li2FeSiO4 as advanced cathode materials for lithium ion batteries.


2020 ◽  
Vol 2 (5) ◽  
pp. 2099-2105 ◽  
Author(s):  
Zuo Chen ◽  
Hao Deng ◽  
Man Zhang ◽  
Zhiyu Yang ◽  
Di Hu ◽  
...  

Rational design and synthesis of efficient electrodes with pronounced energy storage properties are crucial for supercapacitors.


2019 ◽  
Author(s):  
Florian Strauss ◽  
Lea de Biasi ◽  
A-Young Kim ◽  
Jonas Hertle ◽  
Simon Schweidler ◽  
...  

Measures to improve the cycling performance and stability of bulk-type all-solid-state batteries (SSBs) are currently being developed with the goal of substituting conventional Li-ion battery (LIB) technology. As known from liquid electrolyte based LIBs, layered oxide cathode materials undergo volume changes upon (de)lithiation, causing mechanical degradation due to particle fracture, among others. Unlike solid electrolytes, liquid electrolytes are somewhat capable of accommodating morphological changes. In SSBs, the rigidity of the materials used typically leads to adverse contact loss at the interfaces of cathode material and solid electrolyte during cycling. Hence, designing zero- or low-strain electrode materials for application in next-generation SSBs is desirable. In the present work, we report on novel Co-rich NCMs, NCM361 (60% Co) and NCM271 (70% Co), showing minor volume changes up to 4.5 V vs Li<sup>+</sup>/Li, as determined by <i>operando</i> X-ray diffraction and pressure measurements of LIB pouch and pelletized SSB cells, respectively. Both cathode materials exhibit good cycling performance when incorporated into SSB cells using argyrodite Li<sub>6</sub>PS<sub>5</sub>Cl solid electrolyte, albeit their morphology and secondary particle size have not yet been optimized.


2019 ◽  
Author(s):  
Florian Strauss ◽  
Lea de Biasi ◽  
A-Young Kim ◽  
Jonas Hertle ◽  
Simon Schweidler ◽  
...  

Measures to improve the cycling performance and stability of bulk-type all-solid-state batteries (SSBs) are currently being developed with the goal of substituting conventional Li-ion battery (LIB) technology. As known from liquid electrolyte based LIBs, layered oxide cathode materials undergo volume changes upon (de)lithiation, causing mechanical degradation due to particle fracture, among others. Unlike solid electrolytes, liquid electrolytes are somewhat capable of accommodating morphological changes. In SSBs, the rigidity of the materials used typically leads to adverse contact loss at the interfaces of cathode material and solid electrolyte during cycling. Hence, designing zero- or low-strain electrode materials for application in next-generation SSBs is desirable. In the present work, we report on novel Co-rich NCMs, NCM361 (60% Co) and NCM271 (70% Co), showing minor volume changes up to 4.5 V vs Li<sup>+</sup>/Li, as determined by <i>operando</i> X-ray diffraction and pressure measurements of LIB pouch and pelletized SSB cells, respectively. Both cathode materials exhibit good cycling performance when incorporated into SSB cells using argyrodite Li<sub>6</sub>PS<sub>5</sub>Cl solid electrolyte, albeit their morphology and secondary particle size have not yet been optimized.


Sign in / Sign up

Export Citation Format

Share Document