High and reversible SO2 capture by a chemically stable Cr(iii)-based MOF

2020 ◽  
Vol 8 (23) ◽  
pp. 11515-11520 ◽  
Author(s):  
Eva Martínez-Ahumada ◽  
Mariana L. Díaz-Ramírez ◽  
Hugo A. Lara-García ◽  
Daryl R. Williams ◽  
Vladimir Martis ◽  
...  
Keyword(s):  
Chemical Stability ◽  
High Uptake ◽  
High Chemical ◽  
Adsorption Sites ◽  
Preferential Adsorption ◽  
So2 Capture ◽  
Adsorption Of Co ◽  
High Chemical Stability

MIL-101(Cr)-4F(1%) shows a high uptake and high chemical stability to dry and humid SO2 and a remarkable cyclability. In situ DRIF spectroscopy upon the adsorption of CO identified the preferential adsorption sites for this MOF material.

scholarly journals TiO2-Coated ZnO Nanowire Arrays: A Photocatalyst with Enhanced Chemical Corrosion Resistance

Catalysts ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1289
Author(s):  
Lan Gao ◽  
Elyes Nefzaoui ◽  
Frédéric Marty ◽  
Mazen Erfan ◽  
Stéphane Bastide ◽  
...  
Keyword(s):  
Chemical Stability ◽  
Large Scale ◽  
Organic Dyes ◽  
Synthesis Method ◽  
Atomic Layer ◽  
Strong Acid ◽  
Tio2 Coating ◽  
High Chemical ◽  
Chemical Corrosion ◽  
High Chemical Stability

Photocatalysis is proven to be the most efficient and environmentally friendly method for the degradation of organic pollutants in water purification. To meet the requirement of large-scale water treatment, there are two important points: One is the lifetime and chemical stability of the photocatalyst material, especially in the complex and harsh aqueous conditions. The other is the ease of synthesis of such photocatalysts with specific nano-morphology. In this work, two common photocatalyst materials, zinc oxide (ZnO) and titanium dioxide (TiO2), are selected to form more sustainable photocatalysts with high chemical stability. This involves the combination of both TiO2 and ZnO in a two-step simple synthesis method. It appears advantageous to exploit the conformal deposition of atomic layer deposition (ALD) to achieve nanometer-thick TiO2 coating on ZnO nanowires (NWs) with a high aspect ratio, which are firmly anchored to a substrate and exhibit a large specific surface area. The high chemical stability of the ALD TiO2 coating has been investigated in detail and proven to be effective under both strong acid and strong alkaline aqueous solutions. In addition, photocatalysis experiments with organic dyes show that via this simple two-step synthesis method, the produced ZnO/TiO2 tandem does indeed exhibit improved chemical stability in a harsh environment, while allowing efficient photodegradation.

Synthesis of glasses with high chemical stability

1980 ◽  
Vol 37 (5) ◽  
pp. 224-227
Author(s):  
B. V. Tarasov
Keyword(s):  
Chemical Stability ◽  
High Chemical ◽  
High Chemical Stability

scholarly journals Annulated Dialkoxybenzenes as Catholyte Materials for Non-aqueous Redox Flow Batteries: Achieving High Chemical Stability through Bicyclic Substitution

2017 ◽  
Vol 7 (21) ◽  
pp. 1701272 ◽  
Author(s):  
Jingjing Zhang ◽  
Zheng Yang ◽  
Ilya A. Shkrob ◽  
Rajeev S. Assary ◽  
Siu on Tung ◽  
...  
Keyword(s):  
Chemical Stability ◽  
High Chemical ◽  
Redox Flow Batteries ◽  
Flow Batteries ◽  
High Chemical Stability

Novel enantiomorphic Pb-coordination polymers dictated by the corresponding chiral ligands, [Pb((R,R)-TBA)(H2O)]·1.7H2O and [Pb((S,S)-TBA)(H2O)]·1.7H2O [TBA = 1,3,5-triazin-2(1H)-one-4,6-bis(alanyl)]

2021 ◽  
Author(s):  
Yunseung Kuk ◽  
Kang Min Ok
Keyword(s):  
Hydrogen Bonds ◽  
Coordination Polymers ◽  
Chemical Stability ◽  
Congo Red ◽  
Chiral Ligands ◽  
High Chemical ◽  
Selective Uptake ◽  
Congo Red Dye ◽  
Red Dye ◽  
High Chemical Stability

Two enantiomorphic Pb-coordination polymers dictated by the corresponding chiral ligands reveal high chemical stability and a selective uptake of Congo red dye through the hydrogen bonds.

Intramolecular hydrogen bond-induced high chemical stability of metal–organic frameworks

2020 ◽  
Vol 7 (19) ◽  
pp. 3548-3554
Author(s):  
Keke Wang ◽  
Qunmin Wang ◽  
Xiong Wang ◽  
Mei Wang ◽  
Qin Wang ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bonds ◽  
Intramolecular Hydrogen Bond ◽  
Chemical Stability ◽  
Metal Organic Frameworks ◽  
Carboxyl Groups ◽  
High Chemical ◽  
Metal Organic ◽  
Intramolecular Hydrogen ◽  
High Chemical Stability

Intramolecular hydrogen bonds in ligands restrict the rotation of carboxyl groups and consequently enhance the chemical stability of MOFs.

scholarly journals Attachment of hybridizable oligonucleotides to a silica support and its application for selective extraction of unmodified and antisense oligonucleotides from serum samples

RSC Advances ◽  
2020 ◽  
Vol 10 (28) ◽  
pp. 16221-16230
Author(s):  
Sylwia Studzińska ◽  
Magdalena Skoczylas ◽  
Szymon Bocian ◽  
Anna Dembska ◽  
Bogusław Buszewski
Keyword(s):  
Chemical Stability ◽  
Antisense Oligonucleotides ◽  
Selective Extraction ◽  
Silica Support ◽  
Serum Samples ◽  
High Chemical ◽  
High Chemical Stability

The main aim of the present study was the synthesis of an oligonucleotide-based material with high chemical stability, repeatability and specificity to complementary oligonucleotides.

scholarly journals N-Nmoc-l-Glutamate, a New Caged Glutamate with High Chemical Stability and Low Pre-photolysis Activity

1997 ◽  
Vol 272 (52) ◽  
pp. 32933-32939 ◽  
Author(s):  
Francis M. Rossi ◽  
Michael Margulis ◽  
Cha-Min Tang ◽  
Joseph P. Y. Kao
Keyword(s):  
Chemical Stability ◽  
High Chemical ◽  
Caged Glutamate ◽  
High Chemical Stability
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