Palladium nanoparticle loaded β-cyclodextrin monolith as a flow reactor for concentration enrichment and conversion of pollutants based on molecular recognition

2020 ◽  
Vol 56 (92) ◽  
pp. 14408-14411
Author(s):  
Shunsuke Mizuno ◽  
Taka-Aki Asoh ◽  
Yoshinori Takashima ◽  
Akira Harada ◽  
Hiroshi Uyama
Keyword(s):  
Molecular Recognition ◽  
Environmental Effect ◽  
Flow Reactor ◽  
Palladium Nanoparticle ◽  
Residual Concentration ◽  
Polymer Monolith

A palladium nanoparticle immobilized β-cyclodextrin cross-linked polymer monolith not only adsorbed pollutants to the residual concentration with no environmental effect, but also converted them into concentrated useful substances.

scholarly journals Suzuki–Miyaura Coupling Using Monolithic Pd Reactors and Scaling-Up by Series Connection of the Reactors

Catalysts ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 300 ◽  
Author(s):  
Aiichiro Nagaki ◽  
Katsuyuki Hirose ◽  
Yuya Moriwaki ◽  
Masahiro Takumi ◽  
Yusuke Takahashi ◽  
...  
Keyword(s):  
Pressure Drop ◽  
Flow Rate ◽  
Flow Reactor ◽  
Scale Up ◽  
Good Method ◽  
Aryl Halides ◽  
Series Connection ◽  
Pore Sizes ◽  
Polymer Monolith ◽  
Increase In Productivity

The space integration of the lithiation of aryl halides, the borylation of aryllithiums, and Suzuki–Miyaura coupling using a Pd catalyst supported by a polymer monolith flow reactor without using an intentionally added base was achieved. To scale up the process, a series connection of the monolith Pd reactor was examined. To suppress the increase in the pressure drop caused by the series connection, a monolith reactor having larger pore sizes was developed by varying the temperature of the monolith preparation. The monolithic Pd reactor having larger pore sizes enabled Suzuki–Miyaura coupling at a higher flow rate because of a lower pressure drop and, therefore, an increase in productivity. The present study indicates that series connection of the reactors with a higher flow rate serves as a good method for increasing the productivity without decreasing the yields.

Personal Goals of Older Female Twins

2009 ◽  
Vol 14 (2) ◽  
pp. 160-167 ◽  
Author(s):  
Katariina Salmela-Aro ◽  
Sanna Read ◽  
Jari-Erik Nurmi ◽  
Markku Koskenvuo ◽  
Jaakko Kaprio ◽  
...  
Keyword(s):  
Physical Exercise ◽  
Independent Living ◽  
Environmental Effect ◽  
Close Relationships ◽  
Environmental Influence ◽  
Genetic Effect ◽  
Additive Genetic Effect ◽  
Personal Goals ◽  
Cultural Activities ◽  
The Individual

This study examined genetic and environmental influences on older women’s personal goals by using data from the Finnish Twin Study on Aging. The interview for the personal goals was completed by 67 monozygotic (MZ) pairs and 75 dizygotic (DZ) pairs. The tetrachoric correlations for personal goals related to health and functioning, close relationships, and independent living were higher in MZ than DZ twins, indicating possible genetic influence. The pattern of tetrachoric correlations for personal goals related to cultural activities, care of others, and physical exercise indicated environmental influence. For goals concerning health and functioning, independent living, and close relationships, additive genetic effect accounted for about half of the individual variation. The rest was the result of a unique environmental effect. Goals concerning physical exercise and care of others showed moderate common environmental effect, while the rest of the variance was the result of a unique environmental effect. Personal goals concerning cultural activities showed unique environmental effects only.

Environmental effect on diet, fecundity and condition of an endangered fishNeosalanx reganius(Osmeriformes) in the Chikugo Estuary, in the upper Ariake Bay, Japan

2006 ◽  
Vol 19 (1) ◽  
pp. 59-68 ◽  
Author(s):  
Md. Shahidul Islam ◽  
Manabu Hibino ◽  
Taro Ohta ◽  
Kouji Nakayama ◽  
Masaru Tanaka
Keyword(s):  
Environmental Effect ◽  
Ariake Bay

Hydrogenolysis of glucose and fructose in glycol solutions over CuO-MgO-ZrO2 catalyst

2020 ◽  
pp. 48-55
Author(s):  
M.E. Sharanda ◽  
◽  
E.A. Bondarenko ◽  
Keyword(s):  
Ethylene Glycol ◽  
Propylene Glycol ◽  
Flow Reactor ◽  
General Trend ◽  
Raw Materials ◽  
Reaction Products ◽  
Renewable Raw Materials ◽  
High Partial Pressure ◽  
Zro2 Catalyst ◽  
Phase Process

Ethylene glycol and propylene glycol are important representatives of polyols. On an industrial scale, they are obtained from petrochemical raw materials. Within a decade, significant efforts were made for the producing of polyols from biologically renewable raw materials - carbohydrates. The general trend for carbohydrate hydrogenolysis includes application of liquid-phase process with the use of modified metal-oxide catalysts, at 120-120 ° C and pressure of 3MPa or above. So high pressure is used for the reason to increase hydrogen solubility, and also due to the high partial pressure of low boiling solvents. We supposed that usage of high boiling solvents could allow hydrogenolysis to be performed at the lower pressure. Ethylene glycol and propylene glycol are of particular interest as such kind of solvent since they are both the main products of glucose hydrogenolysis. In this work, the process of hydrogenolysis of glucose and fructose over Cu / MgO-ZrO2 catalyst have been studied at temperature range of 160-200 °C and a pressure of 0.1-0.3 MPa in a flow reactor. The solvents were simultaneously the target products of the reaction - ethylene glycol and / or propylene glycol. Gas chromatography and 13C NMR were used for the reaction products identification. It was found that the solubility of glucose in propylene glycol is 21 % by weight, and in ethylene glycol 62% by weight. It was pointed out that the process of hydrogenolysis can take place at a pressure close to atmospheric. Under these conditions, the conversion of hexoses reaches 96-100 %. The reaction products are preferably propylene glycol and ethylene glycol. The total selectivity for C3-2 polyols is 90-94 %, that is higher than in the hydrogenolysis of glucose in aqueous solution.

Conversion of fructose into methyl lactate over SnO2/Al2O3 catalystin flow regime

2020 ◽  
pp. 43-47
Author(s):  
S.V. Prudius ◽  
◽  
N.L. Hes ◽  
A.M. Mylin ◽  
V.V. Brei ◽  
...  
Keyword(s):  
Flow Reactor ◽  
Practical Interest ◽  
Dimethyl Acetal ◽  
Racemic Mixture ◽  
Process Conditions ◽  
Impregnation Method ◽  
Aqueous Methanol ◽  
Methyl Lactate ◽  
Al2o3 Catalyst ◽  
Target Reaction

In recent years, numerous researchers have focused on the development of catalytic methods for processing of biomass-derived sugars into alkyl lactates, which are widely used as non-toxic solvents and are the starting material for obtaining monomeric lactide. In this work, the transformation of fructose into methyl lactate on Sn-containing catalyst in the flow reactor that may be of practical interest was studied. The supported Sn-containing catalyst was ob-tained by a simple impregnation method of granular γ-Al2O3. The catalytic ex-periments were performed in a flow reactor at temperatures of 160-190 °C and pressure of 3.0 MPa. The 1.6-9.5 wt.% fructose solutions in 80% aqueous methanol were used as a reaction mixture. It was found that addition to a reac-tion mixture of 0.03 wt.% potassium carbonate leads to the increase in selec-tivity towards methyl lactate on 15% at 100% conversion of fructose. Prod-ucts of the target reaction С6Н12О6 + 2СН3ОН = 2С4Н8О3 + 2Н2О were ana-lyzed using 13C NMR method. The following process conditions for obtaining of 65 mol% methyl lactate yield at 100% fructose conversion were found: use of 4.8 wt.% fructose solution in 80% methanol, 180 °С, 3.0 МПа and a load on catalyst 1.5 mmol C6H12O6/mlcat/h at contact time of 11 minutes. The cata-lyst productivity is 2.0 mmol C4H8O3/mlcat/h and the by-productі are 1,3-dihydroxyacetone dimethyl acetal (20%) and 5-hydroxymethylfurfural (10%). It should be noted that a racemic mixture of L- and D-methyl lactates has been obtained by conversion of D-fructose on the SnO2/Al2O3 catalyst. The SnO2/Al2O3 catalyst was found to be stable for 6 h while maintaining full fruc-tose conversion at 55–70% methyl lactate selectivity. After regeneration the catalyst completely restores the initial activity.

ENVIRONMENTAL EFFECT OF ECONOMIC WASTE MANAGEMENT

2020 ◽  
Author(s):  
A.A. Lavrentiev ◽  
◽  
V.V. Sidorkin ◽  
E.A. Gamoyunov ◽  
A.S. Rusaleev ◽  
...  
Keyword(s):  
Environmental Management ◽  
Waste Management ◽  
Environmental Effect ◽  
Agricultural Waste ◽  
Waste Recycling ◽  
Ecological Effect ◽  
Nature Management ◽  
Modern Concept ◽  
Rational Nature ◽  
Modern Technologies

The article explores ways of forming a modern concept of rational nature management of agricultural waste. The analysis of the nomenclature of agricultural waste was carried out, their influence on the environmental situation was studied. The modern technologies of rational nature management of agricultural waste are systematized, the most promising areas of waste recycling are identified. The ecological effect of the application of technologies for the rational environmental management of agricultural waste was studied.

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