scholarly journals Recent progress in the catalytic transformation of carbon dioxide into biosourced organic carbonates

2021 ◽  
Vol 23 (3) ◽  
pp. 1077-1113 ◽  
Author(s):  
Vatcharaporn Aomchad ◽  
Àlex Cristòfol ◽  
Francesco Della Monica ◽  
Bart Limburg ◽  
Valerio D'Elia ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Fatty Acids ◽  
Vegetable Oils ◽  
Recent Progress ◽  
Catalytic Transformation ◽  
Cyclic Carbonates ◽  
Recent Advances ◽  
Organic Carbonates ◽  
Potential Applications ◽  
Made In

The recent advances made in the catalytic preparation of biobased cyclic carbonates derived from sugars, glycerol, fatty acids/vegetable oils and terpenes are presented, together with a discussion surrounding their potential applications.

Recent Progress in Microwave-assisted Modification of Vegetable Oils or Their Derivatives

2020 ◽  
Vol 24 (8) ◽  
pp. 870-884
Author(s):  
Jinshuai Zhang ◽  
Yun Hu ◽  
Fei Zhang ◽  
Jianyu Lu ◽  
Jia Huang ◽  
...  
Keyword(s):  
Fatty Acids ◽  
Reaction Time ◽  
Free Fatty Acids ◽  
Vegetable Oils ◽  
Recent Progress ◽  
The Other ◽  
Side Reactions ◽  
Microwave Technology ◽  
Microwave Assisted ◽  
Recent Advances

Vegetable oils have been widely used in food, surfactants, lubricants, biodiesel, coatings, and other fields due to their advantages such as renewable, abundant, suitable for further processing, and biodegradable. On the other hand, microwave technology has attracted extensive attention in organic and polymeric chemistry because the technology can greatly shorten the reaction time, improve the yield of products, reduce side reactions, etc. This paper summarized recent advances on the microwave-assisted modification of vegetable oils or their derivatives, such as esterification of free fatty acids, transesterification of triglycerides, epoxidation, and polymerization.

Synthesis of cyclic organic carbonates via catalytic oxidative carboxylation of olefins in flow reactors

2017 ◽  
Vol 7 (1) ◽  
pp. 84-89 ◽  
Author(s):  
Ajay A. Sathe ◽  
Anirudh M. K. Nambiar ◽  
Robert M. Rioux
Keyword(s):  
Carbon Dioxide ◽  
Continuous Flow ◽  
Catalytic Conversion ◽  
Cyclic Carbonates ◽  
Flow Reactors ◽  
Organic Carbonates ◽  
Continuous Flow Reactors

The direct catalytic conversion of olefins into cyclic carbonates using peroxide and carbon dioxide is demonstrated using continuous flow reactors.

Novel iron(iii) catalyst for the efficient and selective coupling of carbon dioxide and epoxides to form cyclic carbonates

2015 ◽  
Vol 5 (1) ◽  
pp. 118-123 ◽  
Author(s):  
Antonio Buonerba ◽  
Assunta De Nisi ◽  
Alfonso Grassi ◽  
Stefano Milione ◽  
Carmine Capacchione ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Cyclic Carbonates ◽  
Organic Carbonates

“Re-cycling carbon dioxide with iron”. The synthesis of cyclic organic carbonates was accomplished by the coupling of CO2 and epoxides, using a novel air-stable and easy-to-handle iron(iii) catalyst.

Synthesis of metalloporphyrin-based porous organic polymers and their functionalization for conversion of CO2 into cyclic carbonates: recent advances, opportunities and challenges

2021 ◽  
Author(s):  
Rongchang Luo ◽  
Min Chen ◽  
Farong Zhou ◽  
Jiamin Zhan ◽  
Qi Deng ◽  
...  
Keyword(s):  
Cyclic Carbonates ◽  
Organic Polymers ◽  
Specific Design ◽  
Porous Organic Polymers ◽  
Design And Synthesis ◽  
Recent Advances ◽  
Made In

This review summarized the recent advances made in the task-specific design and synthesis of metalloporphyrin-based porous organic polymers (POPs) and their functionalization for conversion of CO2 into cyclic carbonates.

Carbon dioxide chemistry: Examples and challenges in chemical utilization of carbon dioxide

2009 ◽  
Vol 81 (11) ◽  
pp. 2069-2080 ◽  
Author(s):  
Liang-Nian He ◽  
Jin-Quan Wang ◽  
Jing-Lun Wang
Keyword(s):  
Carbon Dioxide ◽  
Transition Metal Catalysts ◽  
Solid Catalyst ◽  
Homogeneous Catalyst ◽  
Chemical Transformations ◽  
Organic Carbonates ◽  
Benign Synthesis ◽  
Solvent Free Conditions ◽  
Potential Applications ◽  
Molecular Catalysts

The development of catalytic methods for chemical transformation of CO2 into useful compounds is of paramount importance from a standpoint of C1 chemistry and so-called green chemistry. The kinetic and thermodynamic stability of CO2 molecule presents significant challenges in designing efficient chemical transformations based on this potential feedstock. In this context, efforts to convert CO2 to useful chemicals will inevitably rely on its activation through molecular catalysts, particularly transition-metal catalysts. Two preparative processes employing solid catalyst or CO2-philic homogeneous catalyst were devised for environmentally benign synthesis of organic carbonates and oxazolidinones under solvent-free conditions. Those processes represent pathways for greener chemical fixations of CO2 to afford industrial useful materials such as organic carbonates and oxazolidinones with great potential applications.

Recent advances in the field of selective epoxidation of vegetable oils and their derivatives: a review and perspective

2017 ◽  
Vol 7 (17) ◽  
pp. 3659-3675 ◽  
Author(s):  
S. M. Danov ◽  
O. A. Kazantsev ◽  
A. L. Esipovich ◽  
A. S. Belousov ◽  
A. E. Rogozhin ◽  
...  
Keyword(s):  
Fatty Acids ◽  
Fatty Acid ◽  
Vegetable Oils ◽  
Critical Review ◽  
Fatty Acid Methyl Esters ◽  
Recent Progress ◽  
Unsaturated Fatty Acids ◽  
Methyl Esters ◽  
Acid Methyl ◽  
Review Reports

The present critical review reports the recent progress of the last 15 years in the selective epoxidation of vegetable oils and their derivatives, in particular unsaturated fatty acids (UFAs) and fatty acid methyl esters (FAMEs).

Poly(ethylene glycol): an Alternative Solvent for the Synthesis of Cyclic Carbonate from Vicinal Halohydrin and Carbon Dioxide

2009 ◽  
Vol 62 (8) ◽  
pp. 917 ◽  
Author(s):  
Jing-Lun Wang ◽  
Liang-Nian He ◽  
Xiao-Yong Dou ◽  
Fang Wu
Keyword(s):  
Carbon Dioxide ◽  
Ethylene Glycol ◽  
Reaction Medium ◽  
Cyclic Carbonate ◽  
High Yield ◽  
Cyclic Carbonates ◽  
Poly Ethylene Glycol ◽  
Potential Applications ◽  
Ready Availability ◽  
Poly Ethylene

Poly(ethylene glycol) (PEG) in this work proved to be an efficient reaction medium for the reaction of vicinal halohydrin with carbon dioxide in the presence of a base to synthesise cyclic carbonates. Notably, PEG-400 as an environmentally friendly solvent exhibits a unique influence on reactivity compared with conventional organic solvents. Various cyclic carbonates were prepared in high yield employing this protocol. The process presented here has potential applications in the industrial production of cyclic carbonates because of its simplicity, cost benefits, ready availability of starting materials, and mild reaction conditions.

scholarly journals Cyclic Carbonates Based on Vegetable Oils

2014 ◽  
Vol 27 ◽  
pp. 20-29 ◽  
Author(s):  
D. Miloslavskiy ◽  
E. Gotlib ◽  
O. Figovsky ◽  
D. Pashin
Keyword(s):  
Carbon Dioxide ◽  
Chemical Composition ◽  
Vegetable Oils ◽  
Catalyst Concentration ◽  
Raw Materials ◽  
Cyclic Carbonates ◽  
Carbonation Reaction ◽  
Carbonation Process ◽  
Carbon Dioxide Pressure ◽  
Vegetable Raw Materials

The analysis of literary data on the obtaining of cyclic carbonates based on the vegetable oils has been carried out. The influence on carbonation reaction the type of vegetable oil, the chemical composition and catalyst concentration, state of carbon dioxide, pressure and temperature have thus been considered. The carbonation process of epoxidized oils that are valuable renewable vegetable raw materials is studied insufficiently.

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