A novel quinolinyl-tetraphenylethene-based fluorescence “turn-on” sensor for Zn2+ with a large Stokes shift and its applications for portable test strips and biological imaging

2020 ◽  
Vol 4 (11) ◽  
pp. 3338-3348
Author(s):  
Jianxing Xu ◽  
Jingwen Xiong ◽  
Yanlin Qin ◽  
Zongzhi Li ◽  
Chengqiang Pan ◽  
...  

A new 8-hydroxyquinoline derivative TPE(OH)-8HQ, has been synthesized and evaluated as an efficient fluorescence “turn-on” sensor for detection of Zn2+ based on the chelation-enhanced fluorescence (CHEF) mechanism in neutral aqueous solution.

2021 ◽  
Author(s):  
Gyeongjin Kim ◽  
Donghwan Choi ◽  
Cheal Kim

Abstract A new benzothiazole-based chemosensor BTN (1-((Z)-(((E)-3-methylbenzo[d]thiazol-2(3H)-ylidene)hydrazono)methyl)naphthalen-2-ol) was synthesized for the detection of Cu2+. BTN could detect Cu2+ with “off-on” fluorescent response from colorless to yellow irrespective of presence of other cations. Limit of detection for Cu2+ was determined to be 3.3 µM. Binding ratio of BTN and Cu2+ turned out to be a 1:1 with the analysis of Job plot and ESI-MS. Sensing feature of Cu2+ by BTN was explained with theoretical calculations, which might be owing to internal charge transfer and chelation-enhanced fluorescence processes.


2018 ◽  
Vol 42 (17) ◽  
pp. 14510-14516 ◽  
Author(s):  
Yaoyao Ning ◽  
Xiaoqing Wang ◽  
Kangjia Sheng ◽  
Lili Yang ◽  
Wei Han ◽  
...  

A novel naked-eye colorimetric and fluorescent turn-on pH sensor based on a naphthalenone scaffold was rationally designed and facilely synthesized.


Author(s):  
Hong-Bo Liu ◽  
Hai Xu ◽  
Xin Guo ◽  
Jian Xiao ◽  
Zheng-Hong Cai ◽  
...  

A near-infrared (NIR) fluorescent probe with a large Stokes shift (143 nm) for the rapid identification of Cys over Hcy and GSH in aqueous solution was developed.


2014 ◽  
Vol 9 (12) ◽  
pp. 3397-3402 ◽  
Author(s):  
Hio-Ieng Un ◽  
Chang-Bo Huang ◽  
Junhai Huang ◽  
Chusen Huang ◽  
Ti Jia ◽  
...  

2012 ◽  
Vol 41 (24) ◽  
pp. 7212 ◽  
Author(s):  
Lin Xu ◽  
Yufang Xu ◽  
Weiping Zhu ◽  
Chunmei Yang ◽  
Le Han ◽  
...  

Molecules ◽  
2019 ◽  
Vol 24 (17) ◽  
pp. 3102 ◽  
Author(s):  
Bin Li ◽  
Datong Zhang ◽  
Ruibing An ◽  
Yaling Zhu

In this work, a novel 7-hydroxybenzoxazinone-based fluorescent probe (PBD) for the selective sensing of biothiols is reported. Upon treatment with biothiols, PBD shows a strong fluorescence enhancement (up to 70-fold) and a large Stokes shift (155 nm). Meanwhile, this probe exhibits high resistance to interference from other amino acids and competing species. PBD features good linearity ranges with a low detection limit of 14.5 nM for glutathione (GSH), 17.5 nM for cysteine (Cys), and 80.0 nM for homocysteine (Hcy), respectively. Finally, the potential utility of this probe for biothiol sensing in living HeLa cells is demonstrated.


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