The reverse water gas shift reaction: a process systems engineering perspective

2021 ◽  
Author(s):  
Miriam González-Castaño ◽  
Bogdan Dorneanu ◽  
Harvey Arellano-García
Keyword(s):  
Systems Engineering ◽  
Process Design ◽  
Process Intensification ◽  
Industrial Applications ◽  
Catalytic Systems ◽  
Process Systems ◽  
Reverse Water Gas Shift ◽  
Reaction Thermodynamics ◽  
Rwgs Reaction ◽  
Shift Reaction

RWGS reaction thermodynamics, mechanisms and kinetics. Process design and process intensification – from lab scale to industrial applications and CO2 value chains. Pathways for further improvement of catalytic systems, reactor and process design.

Boosting reverse water-gas shift reaction activity of Pt nanoparticles through light doping of W

2021 ◽  
Author(s):  
Daiya Kobayashi ◽  
Hirokazu Kobayashi ◽  
Kohei Kusada ◽  
Tomokazu Yamamoto ◽  
Takaaki Toriyama ◽  
...  
Keyword(s):  
Pt Nanoparticles ◽  
Water Gas Shift ◽  
Solid Solution Alloy ◽  
Alloy Nanoparticles ◽  
Water Gas Shift Reaction ◽  
Reverse Water Gas Shift ◽  
Rwgs Reaction ◽  
Shift Reaction ◽  
Water Gas ◽  
First Time

We report PtW solid-solution alloy nanoparticles (NPs) as a reverse water-gas shift (RWGS) reaction catalyst for the first time. Atomic-level alloying of Pt and W significantly enhanced the RWGS reaction activity of Pt NPs.

scholarly journals Catalytic manganese oxide nanostructures for the reverse water gas shift reaction

Nanoscale ◽  
2019 ◽  
Vol 11 (35) ◽  
pp. 16677-16688 ◽  
Author(s):  
Yulian He ◽  
Ke R. Yang ◽  
Ziwei Yu ◽  
Zachary S. Fishman ◽  
Laura A. Achola ◽  
...  
Keyword(s):  
Synthetic Methods ◽  
Water Gas Shift ◽  
Water Gas Shift Reaction ◽  
Structure Property ◽  
Structure Property Relationships ◽  
Oxide Nanostructures ◽  
Reverse Water Gas Shift ◽  
Rwgs Reaction ◽  
Shift Reaction ◽  
Water Gas

We develop efficient synthetic methods to prepare various MnO2 structures and investigate their structure–property relationships as applied to the reverse Water Gas Shift (rWGS) reaction with a combination of experimental and theoretical tools.

scholarly journals Activity of La0.75Sr0.25Cr0.5Mn0.5O3−δ, Ni3Sn2 and Gd-doped CeO2 towards the reverse water-gas shift reaction and carburisation for a high-temperature H2O/CO2 co-electrolysis

RSC Advances ◽  
2020 ◽  
Vol 10 (17) ◽  
pp. 10285-10296
Author(s):  
Nicky Bogolowski ◽  
Beatriz Sánchez Batalla ◽  
Baekkyoung Shin ◽  
Jean-Francois Drillet
Keyword(s):  
High Temperature ◽  
High Activity ◽  
Water Gas Shift ◽  
Water Gas Shift Reaction ◽  
Reverse Water Gas Shift ◽  
Rwgs Reaction ◽  
Doped Ceo2 ◽  
Shift Reaction ◽  
Water Gas

LSCrM, Ni3Sn2 and GDC20 powders show high activity and selectivity for the RWGS reaction.

Dispersion and distribution of bimetallic oxides in SBA-15, and their enhanced activity for reverse water gas shift reaction

2015 ◽  
Vol 2 (8) ◽  
pp. 741-748 ◽  
Author(s):  
Baowang Lu ◽  
Yiwen Ju ◽  
Takayuki Abe ◽  
Katsuya Kawamoto
Keyword(s):  
Water Gas Shift ◽  
Water Gas Shift Reaction ◽  
Enhanced Activity ◽  
Reverse Water Gas Shift ◽  
Rwgs Reaction ◽  
Shift Reaction ◽  
Water Gas ◽  
Bimetallic Oxides

Bimetallic oxides could be well distributed on the SBA-15 surface, and exhibited high catalytic perforation for RWGS reaction.

Reverse water-gas shift reaction over Pt/MoOx/TiO2: reverse Mars-van Krevelen mechanism via redox of supported MoOx

2021 ◽  
Author(s):  
Shinya Mine ◽  
Taichi Yamaguchi ◽  
Kah Wei Ting ◽  
Zen Maeno ◽  
S. M. A. Hakim Siddiki ◽  
...  
Keyword(s):  
Co2 Emissions ◽  
Water Gas Shift ◽  
Water Gas Shift Reaction ◽  
Reverse Water Gas Shift ◽  
Rwgs Reaction ◽  
Catalytic Processes ◽  
Shift Reaction ◽  
Water Gas

The reverse water-gas shift (RWGS) reaction is a promising catalytic route for reducing CO2 emissions because its product, CO, is a key intermediate in various industrialized catalytic processes that produce...

scholarly journals Effect of Pd and Ir as Promoters in the Activity of Ni/CeZrO2 Catalyst for the Reverse Water-Gas Shift Reaction

Catalysts ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 1076
Author(s):  
Lucy Idowu Ajakaiye Jensen ◽  
Sara Blomberg ◽  
Christian Hulteberg
Keyword(s):  
Catalytic Activity ◽  
Water Gas Shift ◽  
Intermediate Step ◽  
Co2 Conversion ◽  
Water Gas Shift Reaction ◽  
Co2 Utilization ◽  
Reverse Water Gas Shift ◽  
Rwgs Reaction ◽  
Shift Reaction ◽  
Water Gas

Catalytic conversion of CO2 to CO using reverse water gas shift (RWGS) reaction is a key intermediate step for many CO2 utilization processes. RWGS followed by well-known synthesis gas conversion may emerge as a potential approach to convert CO2 to valuable chemicals and fuels. Nickel (Ni) based catalysts with ceria-zirconia (Ce-Zr) support can be used to tune the metal-support interactions, resulting in a potentially enhanced CO2 hydrogenation rate and elongation of the catalyst lifespan. The thermodynamics of RWGS reaction is favored at high temperature for CO2 conversion. In this paper the effect of Palladium (Pd) and Iridium (Ir) as promoters in the activity of 10 wt%Ni 2 wt%Pd 0.1wt%Ir/CeZrO2 catalyst for the reverse water gas shift reaction was investigated. RWGS was studied for different feed (CO2:H2) ratios. The new active interface between Ni, Pd and Ir particles is proposed to be an important factor in enhancing catalytic activity. 10 wt%Ni 2 wt%Pd 0.1 wt%Ir/CeZrO2 catalyst showed a better activity with CO2 conversion of 52.4% and a CO selectivity of 98% for H2:CO2 (1:1) compared to the activity of 10%Ni/CeZrO2 with CO2 conversion of 49.9% and a CO selectivity of 93%. The catalytic activity for different feed ratios using 10 wt%Ni 2 wt%Pd 0.1 wt%Ir/CeZrO2 were also studied. The use of palladium and iridium boosts the stability and life span of the Ni-based catalysts. This indicates that the catalyst could be used potentially to design RWGS reactors for CO2 utilization units.

scholarly journals Synthesis of CuNi/C and CuNi/γ-Al2O3Catalysts for the Reverse Water Gas Shift Reaction

2015 ◽  
Vol 2015 ◽  
pp. 1-9 ◽  
Author(s):  
Maxime Lortie ◽  
Rima Isaifan ◽  
Yun Liu ◽  
Sander Mommers
Keyword(s):  
Photoelectron Spectroscopy ◽  
Synthesis Method ◽  
Water Gas Shift ◽  
Polyol Synthesis ◽  
Pt Catalysts ◽  
X Ray ◽  
Reverse Water Gas Shift ◽  
Rwgs Reaction ◽  
Shift Reaction ◽  
Water Gas

A new polyol synthesis method is described in which CuNi nanoparticles of different Cu/Ni atomic ratios were supported on both carbon and gamma-alumina and compared with Pt catalysts using the reverse water gas shift, RWGS, reaction. All catalysts were highly selective for CO formation. The concentration of CH4was less than the detection limit. Cu was the most abundant metal on the CuNi alloy surfaces, as determined by X-ray photoelectron spectroscopy, XPS, measurements. Only one CuNi alloy catalyst, Cu50Ni50/C, appeared to be as thermally stable as the Pt/C catalysts. After three temperature cycles, from 400 to 700°C, the CO yield at 700°C obtained using the Cu50Ni50/C catalyst was comparable to that obtained using a Pt/C catalyst.

Highly active and stable copper catalysts derived from copper silicate double-shell nanofibers with strong metal–support interactions for the RWGS reaction

2019 ◽  
Vol 55 (29) ◽  
pp. 4178-4181 ◽  
Author(s):  
Yang Yu ◽  
Renxi Jin ◽  
Justin Easa ◽  
Wei Lu ◽  
Man Yang ◽  
...  
Keyword(s):  
Copper Catalysts ◽  
Water Gas Shift ◽  
Highly Active ◽  
Reverse Water Gas Shift ◽  
Metal Support ◽  
Rwgs Reaction ◽  
Metal Support Interactions ◽  
Shift Reaction ◽  
Water Gas ◽  
Supported Copper Catalysts

Double-shell hollow nanofiber supported copper catalysts with strong metal–support interactions were prepared and applied in the reverse water–gas shift reaction.

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