Efficient photocatalytic CO2 reduction mediated by transitional metal borides: metal site-dependent activity and selectivity

2020 ◽  
Vol 8 (41) ◽  
pp. 21833-21841
Author(s):  
Li Shi ◽  
Pei Wang ◽  
Qi Wang ◽  
Xiaohui Ren ◽  
Fumihiko Ichihara ◽  
...  
Keyword(s):  
Low Cost ◽  
Co2 Reduction ◽  
Metal Site ◽  
Transitional Metal ◽  
Dependent Activity ◽  
Metal Borides

Transitional metal borides Ni3B, Co3B and Fe2B can serve as effective and low-cost cocatalysts to boost photocatalytic CO2 reduction performances.

Graphene Supported Tungsten Carbide as Catalyst for Electrochemical Reduction of CO2

2019 ◽  
Author(s):  
Sahithi Ananthaneni ◽  
Rees Rankin
Keyword(s):  
Tungsten Carbide ◽  
Electrochemical Reduction ◽  
Low Cost ◽  
Co2 Reduction ◽  
Platinum Group Metal ◽  
Reduction Reaction ◽  
Metal Carbides ◽  
Depth Study ◽  
Reduction Of Co2 ◽  
Co2 Reduction Reaction

<div>Electrochemical reduction of CO2 to useful chemical and fuels in an energy efficient way is currently an expensive and inefficient process. Recently, low-cost transition metal-carbides (TMCs) are proven to exhibit similar electronic structure similarities to Platinum-Group-Metal (PGM) catalysts and hence can be good substitutes for some important reduction reactions. In this work, we test graphenesupported WC (Tungsten Carbide) nanocluster as an electrocatalyst for the CO2 reduction reaction. Specifically, we perform DFT studies to understand various possible reaction mechanisms and determine the lowest thermodynamic energy landscape of CO2 reduction to various products such as CO, HCOOH, CH3OH, and CH4. This in-depth study of reaction energetics could lead to improvements and develop more efficient electrocatalysts for CO2 reduction.<br></div>

Dependence of the intrinsic phase structure of Bi2O3 catalysts on photocatalytic CO2 reduction

2021 ◽  
Vol 11 (6) ◽  
pp. 2021-2025
Author(s):  
Liujin Wei ◽  
Guan Huang ◽  
Yajun Zhang
Keyword(s):  
Fourier Transform ◽  
Infrared Spectroscopy ◽  
Fourier Transform Infrared Spectroscopy ◽  
Phase Structure ◽  
Co2 Reduction ◽  
Fourier Transform Infrared ◽  
Time Resolved ◽  
Dependent Activity

The combination of time-resolved transient photoluminescence with in-situ Fourier transform infrared spectroscopy has been conducted to investigate the intrinsic phase structure-dependent activity of Bi2O3 catalyst for CO2 reduction.

Effective Measures for CO2 Reduction Harnessing the Potential Water Energy Present in the Water Service Industry

2010 ◽  
Vol 5 (3) ◽  
Author(s):  
Ohbuchi Yoshihiro ◽  
Sasaki Takanori ◽  
Sumitomo Hiroaki ◽  
Saito Susumu ◽  
Tanaka Yoshiaki
Keyword(s):  
Power Generation ◽  
Water Purification ◽  
Service Industry ◽  
Low Cost ◽  
Co2 Reduction ◽  
Clean Energy ◽  
Net Benefit ◽  
Private Company ◽  
Joint Project ◽  
Purification Plant

Sapporo Waterworks Bureau's (SWB's) measures for CO2 reduction started in 1982 with a hydropower project at the Moiwa Water Purification Plant (MWPP) (cap. 155,000 m3/day). Operation of the generator was temporarily discontinued in 2001 for full-scale reconstruction of the water purification plant (WPP); after the completion of the reconstruction, the power generation equipment was renewed, and the operation resumed as a joint project with a private company in 2007. Power generation is on-site since the hydropower generator within the MWPP area provides energy consumed at the MWPP and the adjoining Waterworks Museum. This power generation is expected to create an energy saving effect equivalent to 1,500 tons of CO2 and over 10 million yen of annual net benefit. In order to increase the usage rate of low-cost, clean energy like hydropower at the WPP, SWB has made a series of adjustments to the operating methods of the plant. Then, as a result, the generation covers 97% of the energy used on-site at present. Furthermore, SWB is considering introducing other hydropower facilities of this kind that harness water transmission energy from the Shiraikawa WPP (cap. 650,000 m3/day) to the major distribution reservoirs.

scholarly journals Copper Oxide-Based Photocatalysts and Photocathodes: Fundamentals and Recent Advances

Molecules ◽  
2021 ◽  
Vol 26 (23) ◽  
pp. 7271
Author(s):  
Tomasz Baran ◽  
Alberto Visibile ◽  
Michael Busch ◽  
Xiufang He ◽  
Szymon Wojtyla ◽  
...  
Keyword(s):  
New Technologies ◽  
Low Cost ◽  
Renewable Energy Sources ◽  
Co2 Reduction ◽  
Chemical Properties ◽  
Water Electrolysis ◽  
Pollutant Emissions ◽  
Low Toxicity ◽  
Abundant Element ◽  
Direct Use

This work aims at reviewing the most impactful results obtained on the development of Cu-based photocathodes. The need of a sustainable exploitation of renewable energy sources and the parallel request of reducing pollutant emissions in airborne streams and in waters call for new technologies based on the use of efficient, abundant, low-toxicity and low-cost materials. Photoelectrochemical devices that adopts abundant element-based photoelectrodes might respond to these requests being an enabling technology for the direct use of sunlight to the production of energy fuels form water electrolysis (H2) and CO2 reduction (to alcohols, light hydrocarbons), as well as for the degradation of pollutants. This review analyses the physical chemical properties of Cu2O (and CuO) and the possible strategies to tune them (doping, lattice strain). Combining Cu with other elements in multinary oxides or in composite photoelectrodes is also discussed in detail. Finally, a short overview on the possible applications of these materials is presented.

scholarly journals Low cost and efficient alloy electrocatalysts for CO2 reduction to formate

2019 ◽  
Vol 32 ◽  
pp. 1-10 ◽  
Author(s):  
Shahid Rasul ◽  
Adrien Pugnant ◽  
Hang Xiang ◽  
Jean-Marie Fontmorin ◽  
Eileen H. Yu
Keyword(s):  
Low Cost ◽  
Co2 Reduction

scholarly journals Graphene Supported Tungsten Carbide as Catalyst for Electrochemical Reduction of CO2

Catalysts ◽  
2019 ◽  
Vol 9 (7) ◽  
pp. 604
Author(s):  
Sahithi Ananthaneni ◽  
Zachery Smith ◽  
Rees B. Rankin
Keyword(s):  
Tungsten Carbide ◽  
Electrochemical Reduction ◽  
Density Functional ◽  
Low Cost ◽  
Co2 Reduction ◽  
Platinum Group Metal ◽  
Reduction Reaction ◽  
Depth Study ◽  
Reduction Of Co2 ◽  
Co2 Reduction Reaction

Electrochemical reduction of CO2 to useful chemical and fuels in an energy efficient way is currently an expensive and inefficient process. Recently, low-cost transition metal-carbides (TMCs) have been proven to exhibit similar electronic structure similarities to Platinum-Group-Metal (PGM) catalysts and hence, can be good substitutes for some important reduction reactions. In this work, we test graphene-supported WC (Tungsten Carbide) nanoclusters as an electrocatalyst for the CO2 reduction reaction. Specifically, we perform density functional theory (DFT) studies to understand various possible reaction mechanisms and determine the lowest thermodynamic energy landscape of CO2 reduction to various products, such as CO, HCOOH, CH3OH, and CH4. This in-depth study of reaction energetics could lead to improvements and development of more efficient electrocatalysts for CO2 reduction.

scholarly journals A functionalised nickel cyclam catalyst for CO2 reduction: electrocatalysis, semiconductor surface immobilisation and light-driven electron transfer

2015 ◽  
Vol 17 (3) ◽  
pp. 1562-1566 ◽  
Author(s):  
Gaia Neri ◽  
James J. Walsh ◽  
Calum Wilson ◽  
Anna Reynal ◽  
Jason Y. C. Lim ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Low Cost ◽  
Co2 Reduction ◽  
Semiconductor Surface ◽  
Covalent Immobilisation

Covalent immobilisation of a low cost electrocatalyst leads to an enhanced rate of photoelectron transfer from a light absorbing semiconductor.

scholarly journals Recent Advances in TiO2-Based Heterojunctions for Photocatalytic CO2 Reduction With Water Oxidation: A Review

2021 ◽  
Vol 9 ◽  
Author(s):  
Kai Li ◽  
Chao Teng ◽  
Shuang Wang ◽  
Qianhao Min
Keyword(s):  
Water Oxidation ◽  
Rational Design ◽  
Photocatalytic Performance ◽  
High Efficiency ◽  
Low Cost ◽  
Spectral Response ◽  
Co2 Reduction ◽  
Environmental Crisis ◽  
Ultraviolet Region ◽  
Recent Advances

Photocatalytic conversion of CO2 into solar fuels has gained increasing attention due to its great potential for alleviating the energy and environmental crisis at the same time. The low-cost TiO2 with suitable band structure and high resistibility to light corrosion has proven to be very promising for photoreduction of CO2 using water as the source of electrons and protons. However, the narrow spectral response range (ultraviolet region only) as well as the rapid recombination of photo-induced electron-hole pairs within pristine TiO2 results in the low utilization of solar energy and limited photocatalytic efficiency. Besides, its low selectivity toward photoreduction products of CO2 should also be improved. Combination of TiO2 with other photoelectric active materials, such as metal oxide/sulfide semiconductors, metal nanoparticles and carbon-based nanostructures, for the construction of well-defined heterostructures can enhance the quantum efficiency significantly by promoting visible light adsorption, facilitating charge transfer and suppressing the recombination of charge carriers, resulting in the enhanced photocatalytic performance of the composite photocatalytic system. In addition, the adsorption and activation of CO2 on these heterojunctions are also promoted, therefore enhancing the turnover frequency (TOF) of CO2 molecules, so as to the improved selectivity of photoreduction products. This review focus on the recent advances of photocatalytic CO2 reduction via TiO2-based heterojunctions with water oxidation. The rational design, fabrication, photocatalytic performance and CO2 photoreduction mechanisms of typical TiO2-based heterojunctions, including semiconductor-semiconductor (S-S), semiconductor-metal (S-M), semiconductor-carbon group (S-C) and multicomponent heterojunction are reviewed and discussed. Moreover, the TiO2-based phase heterojunction and facet heterojunction are also summarized and analyzed. In the end, the current challenges and future prospects of the TiO2-based heterostructures for photoreduction of CO2 with high efficiency, even for practical application are discussed.

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