The Ba3Mo1−xWxNbO8.5 ion conductors: insights into local coordination from X-ray and neutron total scattering

2020 ◽  
Vol 8 (40) ◽  
pp. 21227-21240
Author(s):  
Mauro Coduri ◽  
Andrea Bernasconi ◽  
Henry E. Fischer ◽  
Lorenzo Malavasi
Keyword(s):  
Phase Transition ◽  
High Temperature ◽  
Local Structure ◽  
Total Scattering ◽  
X Ray ◽  
Local Coordination ◽  
Octahedral Sites ◽  
Neutron Total Scattering ◽  
Ion Conductors

The local structure of Ba3Mo1−xWxNbO8.5 is consistent with a mixture of regions richer in tetrahedral and octahedral sites, which redistribute at high temperature after a reconstructive phase transition.

Insight into the local structure of barium indate oxide-ion conductors: An X-ray total scattering study

2012 ◽  
Vol 41 (1) ◽  
pp. 50-53 ◽  
Author(s):  
Alessandro Mancini ◽  
J. Felix Shin ◽  
Alodia Orera ◽  
Peter R. Slater ◽  
Cristina Tealdi ◽  
...  
Keyword(s):  
Local Structure ◽  
Total Scattering ◽  
X Ray ◽  
Scattering Study ◽  
Oxide Ion Conductors ◽  
Oxide Ion ◽  
Insight Into ◽  
Ion Conductors

scholarly journals High-temperature phase transition of SrRuO3and SrHfO5: X-ray diffraction and PAC spectroscopy

1996 ◽  
Vol 52 (a1) ◽  
pp. C364-C364
Author(s):  
J. A. Guevara ◽  
S. L. Cuffini ◽  
Y. P. Mascarenhas ◽  
P. de la Presa ◽  
A. Ayala ◽  
...  
Keyword(s):  
Phase Transition ◽  
High Temperature ◽  
High Temperature Phase ◽  
Temperature Phase ◽  
Pac Spectroscopy ◽  
X Ray Diffraction ◽  
X Ray ◽  
Temperature Phase Transition

The role of π-bonding on the high temperature structure of the double perovskites Ba2CaUO6and BaSrCaUO6

2015 ◽  
Vol 44 (36) ◽  
pp. 16036-16044 ◽  
Author(s):  
Emily Reynolds ◽  
Gordon J. Thorogood ◽  
Maxim Avdeev ◽  
Helen E. A. Brand ◽  
Qinfen Gu ◽  
...  
Keyword(s):  
Phase Transition ◽  
High Temperature ◽  
Neutron Diffraction ◽  
Temperature Structure ◽  
Double Perovskites ◽  
Phase Transition Behavior ◽  
X Ray ◽  
Progressive Loss ◽  
Octahedral Tilting

High temperature synchrotron X-ray and neutron diffraction powder diffraction studies of the uranium perovskites Ba2CaUO6and BaSrCaUO6reveal unusual phase transition behavior associated with the progressive loss of cooperative octahedral tilting.

Structural-phase transition in (Cu2Te)2−x(ZnTe)x at high temperature

2021 ◽  
pp. 2150113
Author(s):  
H. B. Gasimov ◽  
R. M. Rzayev
Keyword(s):  
Phase Transition ◽  
Phase Transitions ◽  
High Temperature ◽  
Single Crystals ◽  
Structural Phase ◽  
X Ray Diffraction ◽  
X Ray ◽  
Temperature Range ◽  
Xrd Study ◽  
Xrd Method

Cu2Te single crystal was grown by the Bridgman method. X-ray diffraction (XRD) study of Cu2Te single crystals in the temperature range of 293–893 K was performed and possible phase transitions in the mentioned range of temperature have been investigated. (Cu2Te)[Formula: see text](ZnTe)[Formula: see text] single crystals also were grown with [Formula: see text], 0.05, 0.10 concentrations and structural properties of the obtained single crystals were investigated by the XRD method in the temperature range 293–893 K. Lattice parameters and possible phase transitions in the mention temperature range were determined for (Cu2Te)[Formula: see text](ZnTe)[Formula: see text] single crystals for [Formula: see text], 0.05, 0.10 concentrations.

scholarly journals The atomic structure of a MgCo2O4 nanoparticle for a positive electrode of a Mg rechargeable battery

2019 ◽  
Vol 55 (17) ◽  
pp. 2517-2520 ◽  
Author(s):  
Naoto Kitamura ◽  
Yuhei Tanabe ◽  
Naoya Ishida ◽  
Yasushi Idemoto
Keyword(s):  
Monte Carlo ◽  
Atomic Structure ◽  
Positive Electrode ◽  
Scattering Data ◽  
Rechargeable Battery ◽  
Reverse Monte Carlo ◽  
Spinel Type ◽  
Total Scattering ◽  
X Ray ◽  
Neutron Total Scattering

The atomic structure of a spinel-type MgCo2O4 nanoparticle was investigated by the reverse Monte Carlo modelling using X-ray and neutron total scattering data.

Analysis of phase transition behavior of BaCeO3 with thermal analyses and high temperature X-ray diffraction

2009 ◽  
Vol 180 (17-19) ◽  
pp. 1034-1039 ◽  
Author(s):  
Takeshi Ohzeki ◽  
Shinya Hasegawa ◽  
Misa Shimizu ◽  
Takuya Hashimoto
Keyword(s):  
Phase Transition ◽  
High Temperature ◽  
Thermal Analyses ◽  
X Ray Diffraction ◽  
Phase Transition Behavior ◽  
X Ray ◽  
Transition Behavior

High-temperature X-ray powder diffraction study of the tetragonal-cubic phase transition in nanocrystalline, compositionally homogeneous ZrO2–CeO2 solid solutions

2008 ◽  
Vol 23 (S1) ◽  
pp. S70-S74 ◽  
Author(s):  
L. M. Acuña ◽  
R. O. Fuentes ◽  
D. G. Lamas ◽  
I. O. Fábregas ◽  
N. E. Walsöe de Reca ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Phase Transition ◽  
High Temperature ◽  
Powder Diffraction ◽  
Solid Solutions ◽  
Tetragonal Phase ◽  
Room Temperature ◽  
Cubic Phase ◽  
X Ray ◽  
First Order

Crystal structure of compositionally homogeneous, nanocrystalline ZrO2–CeO2 solutions was investigated by X-ray powder diffraction as a function of temperature for compositions between 50 and 65 mol % CeO2. ZrO2-50 and 60 mol % CeO2 solid solutions, which exhibit the t′-form of the tetragonal phase at room temperature, transform into the cubic phase in two steps: t′-to-t″ followed by t″-to-cubic. But the ZrO2-65 mol % CeO2, which exhibits the t″-form, transforms directly to the cubic phase. The results suggest that t′-to-t″ transition is of first order, but t″-to-cubic seems to be of second order.

Sign in / Sign up

Export Citation Format

Share Document