High-performance photovoltaic application for the 2D all-inorganic Ruddlesden-Popper perovskite heterostructure Cs2PbI2Cl2/MAPbI3

Author(s):  
Pan Ling-Yu ◽  
Yu-Feng Ding ◽  
Huang-Qing Liu ◽  
Meng-Qiu Cai

Three-dimensional (3D) organic-inorganic halide perovskite MAPbI3 has excellent light-harvesting properties but is unstable. However, the newly synthesized two-dimensional (2D) all-inorganic Ruddlesden-Popper (RP) perovskite Cs2PbI2Cl2 has superior stability but adverse photoelectric...

Nanophotonics ◽  
2020 ◽  
Vol 9 (16) ◽  
pp. 4719-4728
Author(s):  
Tao Deng ◽  
Shasha Li ◽  
Yuning Li ◽  
Yang Zhang ◽  
Jingye Sun ◽  
...  

AbstractThe molybdenum disulfide (MoS2)-based photodetectors are facing two challenges: the insensitivity to polarized light and the low photoresponsivity. Herein, three-dimensional (3D) field-effect transistors (FETs) based on monolayer MoS2 were fabricated by applying a self–rolled-up technique. The unique microtubular structure makes 3D MoS2 FETs become polarization sensitive. Moreover, the microtubular structure not only offers a natural resonant microcavity to enhance the optical field inside but also increases the light-MoS2 interaction area, resulting in a higher photoresponsivity. Photoresponsivities as high as 23.8 and 2.9 A/W at 395 and 660 nm, respectively, and a comparable polarization ratio of 1.64 were obtained. The fabrication technique of the 3D MoS2 FET could be transferred to other two-dimensional materials, which is very promising for high-performance polarization-sensitive optical and optoelectronic applications.


2021 ◽  
Author(s):  
Arindam Mondal ◽  
Akash Lata ◽  
Aarya Prabhakaran ◽  
Satyajit Gupta

Application of three-dimensional (3D)-halide perovskites (HaP) in photocatalysis encourages the new exercise with two-dimensional (2D) HaP based thin-films for photocatalytic degradation of dye. The reduced dimensionality to 2D-HaPs, with a...


Nanoscale ◽  
2021 ◽  
Author(s):  
Chang Liu ◽  
Xiaodong Li ◽  
Tiangui Hu ◽  
Wenkai Zhu ◽  
Faguang Yan ◽  
...  

Integration of two dimensional (2D) materials with three dimensional (3D) semiconductors reveals intriguing optical and electrical properties that surpass those of the original materials. Here we report the high performance...


2015 ◽  
Vol 3 (20) ◽  
pp. 10787-10794 ◽  
Author(s):  
Guofeng Ren ◽  
Md Nadim Ferdous Hoque ◽  
Xuan Pan ◽  
Juliusz Warzywoda ◽  
Zhaoyang Fan

Assembling two-dimensional graphene and VO2(B) nanomaterials into an ordered three-dimensional forest structure for high performance lithium ion batteries.


Author(s):  
Bao Xiao ◽  
Qihao Sun ◽  
Fangbao Wang ◽  
Shiyao Wang ◽  
Binbin Zhang ◽  
...  

Two-dimensional (2D) organic-inorganic hybrid halide perovskites have recently attracted extensive attention for electronic and optoelectronic applications due to their tunable properties and superior stability compared with their three-dimensional (3D) counterparts....


Author(s):  
Yuepeng Liu ◽  
Zhongfang Li ◽  
Chongyun Sun ◽  
Shuaifeng Wang ◽  
Likai Wang ◽  
...  

The development of oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) catalysts with high performance and excellent stability is meaningful for fuel cells. Herein, two-dimensional closely packed amide polyphthalocyanine...


Energies ◽  
2019 ◽  
Vol 13 (1) ◽  
pp. 2 ◽  
Author(s):  
Cuili Gai ◽  
Jigang Wang ◽  
Yongsheng Wang ◽  
Junming Li

Halide perovskite solar cells (PSCs) are considered as one of the most promising candidates for the next generation solar cells as their power conversion efficiency (PCE) has rapidly increased up to 25.2%. However, the most efficient halide perovskite materials all contain toxic lead. Replacing the lead cation with environmentally friendly tin (Sn) is proposed as an important alternative. Today, the inferior performance of Sn-based PSCs mainly due to two challenging issues, namely the facile oxidation of Sn2+ to Sn4+ and the low formation energies of Sn vacancies. Two-dimensional (2D) halide perovskite, in which the large sized organic cations confine the corner sharing BX6 octahedra, exhibits higher formation energy than that of three-dimensional (3D) structure halide perovskite. The approach of mixing a small amount of 2D into 3D Sn-based perovskites was demonstrated as an efficient method to produce high performance perovskite films. In this review, we first provide an overview of key points for making high performance PSCs. Then we give an introduction to the physical parameters of 3D ASnX3 (MA+, FA+, and Cs+) perovskite and a photovoltaic device based on them, followed by an overview of 2D/3D halide perovskites based on ASnX3 (MA+ and FA+) and their optoelectronic applications. The current challenges and a future outlook of Sn-based PSCs are discussed in the end. This review will give readers a better understanding of the 2D/3D Sn-based PSCs.


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