Structural phase transitions in flexible DUT-8(Ni) under high hydrostatic pressure

The behaviours of the open pore (op) and closed pore (cp) phases of flexible [Ni2(ndc)2(dabco)]n (ndc – 2,6-naphthalene dicarboxylate, dabco -- 1,4-diazabicyclo[2.2.2]octane, DUT-8(Ni)) metal-organic framework under high hydrostatic pressure up...

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Single particle Raman spectroscopy analysis of the metal–organic framework DUT-8(Ni) switching transition under hydrostatic pressure

Chemical Communications ◽

10.1039/d0cc02491k ◽

2020 ◽

Vol 56 (59) ◽

pp. 8269-8272

Author(s):

Alexander Krylov ◽

Irena Senkovska ◽

Sebastian Ehrling ◽

Mariia Maliuta ◽

Svetlana Krylova ◽

...

Keyword(s):

Raman Spectroscopy ◽

Hydrostatic Pressure ◽

Single Particle ◽

Metal Organic Framework ◽

Spectroscopy Analysis ◽

Metal Organic ◽

Closed Pore ◽

Organic Framework

According to in situ Raman experiments, in certain pressure ranges open (op) and closed pore (cp) phases coexist in DUT-8(Ni) crystals.

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Structural Phase Transitions and Thermal Hysteresis in the Metal−Organic Framework Compound MIL-53 As Studied by Electron Spin Resonance Spectroscopy

The Journal of Physical Chemistry C ◽

10.1021/jp107487g ◽

2010 ◽

Vol 114 (45) ◽

pp. 19443-19451 ◽

Cited By ~ 53

Author(s):

Matthias Mendt ◽

Bettina Jee ◽

Norbert Stock ◽

Tim Ahnfeldt ◽

Martin Hartmann ◽

...

Keyword(s):

Phase Transitions ◽

Electron Spin Resonance ◽

Thermal Hysteresis ◽

Metal Organic Framework ◽

Structural Phase ◽

Electron Spin Resonance Spectroscopy ◽

Resonance Spectroscopy ◽

Structural Phase Transitions ◽

Spin Resonance ◽

Metal Organic

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Mn-Doped Maghemite (γ-Fe2O3) from Metal–Organic Framework Accompanying Redox Reaction in a Bimetallic System: The Structural Phase Transitions and Catalytic Activity toward NOx Removal

ACS Omega ◽

10.1021/acsomega.7b01865 ◽

2018 ◽

Vol 3 (3) ◽

pp. 2634-2640 ◽

Cited By ~ 9

Author(s):

Junhyung Lee ◽

Seung-Yeop Kwak

Keyword(s):

Catalytic Activity ◽

Phase Transitions ◽

Redox Reaction ◽

Metal Organic Framework ◽

Structural Phase ◽

Nox Removal ◽

Structural Phase Transitions ◽

Metal Organic ◽

Bimetallic System ◽

Mn Doped

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Guest-Mediated Phase Transitions in a Flexible Pillared-Layered Metal-Organic Framework under High-Pressure

Chemical Science ◽

10.1039/d1sc03108b ◽

2021 ◽

Author(s):

Gemma Turner ◽

Scott C. McKellar ◽

David Robert Allan ◽

Anthony K. Cheetham ◽

Sebastian Henke ◽

...

Keyword(s):

High Pressure ◽

Phase Transitions ◽

Single Crystal ◽

Metal Organic Framework ◽

Structural Phase ◽

X Ray Diffraction ◽

X Ray ◽

Metal Organic ◽

Organic Framework

The guest-dependent flexibility of the pillared-layered metal-organic framework (MOF), Zn2bdc2dabco·X(guest), where guest = EtOH, DMF or benzene, has been examined by high-pressure single crystal X-ray diffraction. A pressure-induced structural phase...

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Structural phase transitions and photoluminescence properties of oxonitridosilicate phosphors under high hydrostatic pressure

Scientific Reports ◽

10.1038/srep34010 ◽

2016 ◽

Vol 6 (1) ◽

Cited By ~ 6

Author(s):

Agata Lazarowska ◽

Sebastian Mahlik ◽

Marek Grinberg ◽

Guogang Li ◽

Ru-Shi Liu

Keyword(s):

Phase Transitions ◽

Hydrostatic Pressure ◽

High Hydrostatic Pressure ◽

Structural Phase ◽

Structural Phase Transitions ◽

Photoluminescence Properties

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NQR study of the structural phase transitions in a system with reduced effective dimensionality: K2ReCl6

Canadian Journal of Physics ◽

10.1139/p83-176 ◽

1983 ◽

Vol 61 (10) ◽

pp. 1374-1381 ◽

Cited By ~ 10

Author(s):

Marie D'Iorio ◽

Robin L. Armstrong

Keyword(s):

Fourier Transform ◽

Phase Transitions ◽

Hydrostatic Pressure ◽

Magnetic Resonance ◽

Structural Phase ◽

Nonlinear Phenomena ◽

Structural Phase Transitions ◽

Quadrupole Resonance ◽

Nuclear Quadrupole ◽

Effective Dimensionality

Chlorine 35 nuclear quadrupole resonance (NQR) frequency and lineshape data, obtained with a Fourier transform magnetic resonance spectrometer, are presented for the antifluorite crystal K2ReCl6. In the temperature range investigated, 85 to 130 K, two structural phase transitions occur which reduce the crystal symmetry from cubic to tetragonal to monoclinic. The variation of the NQR spectrum with temperature and with hydrostatic pressure up to 2.64 kbar is documented. The structure of the spectrum and the intensity distribution within it are unexpected from previous studies of antifluorite systems. An explanation of the results is given which is based on recent discussions of nonlinear phenomena at phase transitions in crystals exhibiting reduced effective dimensionality.

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Guest-Dependent Single-Crystal-to-Single-Crystal Phase Transitions in a Two-Dimensional Uranyl-Based Metal–Organic Framework

Crystal Growth & Design ◽

10.1021/acs.cgd.8b01689 ◽

2018 ◽

Vol 19 (1) ◽

pp. 506-512 ◽

Cited By ~ 14

Author(s):

Sylvia L. Hanna ◽

Xuan Zhang ◽

Ken-ichi Otake ◽

Riki J. Drout ◽

Peng Li ◽

...

Keyword(s):

Phase Transitions ◽

Single Crystal ◽

Metal Organic Framework ◽

Crystal Phase ◽

Two Dimensional ◽

Metal Organic ◽

Organic Framework

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Magnetic behavior of the metal organic framework [(CH3)2NH2]Co(HCOO)3

RSC Advances ◽

10.1039/c5ra01417d ◽

2015 ◽

Vol 5 (47) ◽

pp. 37818-37822 ◽

Cited By ~ 15

Author(s):

K. Vinod ◽

C. S. Deepak ◽

Shilpam Sharma ◽

D. Sornadurai ◽

A. T. Satya ◽

...

Keyword(s):

Magnetic Field ◽

Phase Transitions ◽

Specific Heat ◽

Single Crystals ◽

Metal Organic Framework ◽

Magnetic Behavior ◽

Metal Organic ◽

Organic Framework

In this study we examine the phase transitions in single crystals of [(CH3)2NH2]Co(HCOO)3, using magnetization and specific heat measurements as a function of temperature and magnetic field.

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