An ultrastable olefin-linked covalent organic framework for photocatalytic decarboxylative alkylations under highly acidic conditions

2021 ◽  
Author(s):  
Miao Tian ◽  
Yichun Wang ◽  
Xiubin Bu ◽  
Yichen Wang ◽  
Xiaobo Yang
Keyword(s):  
Visible Light ◽  
Basic Structure ◽  
Two Dimensional ◽  
Covalent Organic Frameworks ◽  
Organic Transformations ◽  
Organic Reaction ◽  
Reaction Conditions ◽  
Covalent Organic Framework ◽  
Visible Light Driven ◽  
Acidic Conditions

The application of two-dimensional covalent organic frameworks (2D-COFs) as photoredox catalysts offers a sustainable alternative for visible-light-driven organic transformations. However, under highly complicated organic reaction conditions, maintaining their basic structure...

Covalent organic frameworks as metal-free heterogeneous photocatalysts for organic transformations

2017 ◽  
Vol 5 (44) ◽  
pp. 22933-22938 ◽  
Author(s):  
Yongfeng Zhi ◽  
Ziping Li ◽  
Xiao Feng ◽  
Hong Xia ◽  
Yumin Zhang ◽  
...  
Keyword(s):  
Visible Light ◽  
Visible Light Irradiation ◽  
Light Irradiation ◽  
Two Dimensional ◽  
Covalent Organic Frameworks ◽  
Organic Transformations ◽  
Metal Free ◽  
Covalent Organic Framework ◽  
Photocatalytic Performances ◽  
Organic Framework

A robust two-dimensional covalent organic framework (COF-JLU5), which exhibits excellent heterogeneous photocatalytic performances for oxidative C–H functionalizations under visible-light irradiation using O2as a green oxygen source, is reported.

Construction of a novel 2D-2D heterojunction by coupling covalent organic framework and In2S3 for photocatalytic removal of organic pollutants with high efficiency

2021 ◽  
Author(s):  
Luqiu Li ◽  
Dongguang Yin ◽  
Xiandi Guo
Keyword(s):  
Visible Light ◽  
Hydrogen Evolution ◽  
Organic Pollutants ◽  
High Efficiency ◽  
Crystalline Material ◽  
Charge Carriers ◽  
Covalent Organic Frameworks ◽  
Covalent Organic Framework ◽  
Photocatalytic Removal ◽  
Visible Light Driven

Covalent organic frameworks (COFs) representing an emerging class of porous crystalline material have shown promising visible-light-driven hydrogen evolution activity. However, they have a high recombination ratio of charge carriers and...

Visible-Light-Driven Organic Photochemical Reactions in the Absence of External Photocatalysts

Synthesis ◽  
2019 ◽  
Vol 51 (16) ◽  
pp. 3021-3054 ◽  
Author(s):  
Yi Wei ◽  
Quan-Quan Zhou ◽  
Fen Tan ◽  
Liang-Qiu Lu ◽  
Wen-Jing Xiao
Keyword(s):  
Visible Light ◽  
Transition Metal Complexes ◽  
Organic Dyes ◽  
Photochemical Reactions ◽  
Reaction Intermediates ◽  
Organic Transformations ◽  
Reaction Conditions ◽  
Inorganic Semiconductors ◽  
Visible Light Driven ◽  
Representative Work

Visible-light-driven organic photochemical reactions have attracted substantial attention from the synthetic community. Typically, catalytic quantities of photosensitizers, such as transition metal complexes, organic dyes, or inorganic semiconductors, are necessary to absorb visible light and trigger subsequent organic transformations. Recently, in contrast to these photocatalytic processes, a variety of photocatalyst-free organic photochemical transformations have been exploited for the efficient formation of carbon–carbon and carbon–heteroatom bonds. In addition to not requiring additional photocatalysts, they employ low-energy visible light irradiation, have mild reaction conditions, and enable broad substrate diversity and functional group tolerance. This review will focus on a summary of representative work in this field in terms of different photoexcitation modes.1 Introduction2 Visible Light Photoexcitation of a Single Substrate3 Visible Light Photoexcitation of Reaction Intermediates4 Visible Light Photoexcitation of EDA Complexes between Substrates5 Visible Light Photoexcitation of EDA Complexes between Substrates and Reaction Intermediates6 Visible Light Photoexcitation of Products7 Conclusion and Outlook

scholarly journals Visible Light Photochemical Reactions for Nucleic Acid-Based Technologies

Molecules ◽  
2021 ◽  
Vol 26 (3) ◽  
pp. 556
Author(s):  
Bonwoo Koo ◽  
Haneul Yoo ◽  
Ho Jeong Choi ◽  
Min Kim ◽  
Cheoljae Kim ◽  
...  
Keyword(s):  
Nucleic Acid ◽  
Nucleic Acids ◽  
Visible Light ◽  
Chemical Reactions ◽  
Chemical Biology ◽  
Photochemical Reactions ◽  
Reaction Conditions ◽  
Promising Tool ◽  
Recent Developments ◽  
Visible Light Driven

The expanding scope of chemical reactions applied to nucleic acids has diversified the design of nucleic acid-based technologies that are essential to medicinal chemistry and chemical biology. Among chemical reactions, visible light photochemical reaction is considered a promising tool that can be used for the manipulations of nucleic acids owing to its advantages, such as mild reaction conditions and ease of the reaction process. Of late, inspired by the development of visible light-absorbing molecules and photocatalysts, visible light-driven photochemical reactions have been used to conduct various molecular manipulations, such as the cleavage or ligation of nucleic acids and other molecules as well as the synthesis of functional molecules. In this review, we describe the recent developments (from 2010) in visible light photochemical reactions involving nucleic acids and their applications in the design of nucleic acid-based technologies including DNA photocleaving, DNA photoligation, nucleic acid sensors, the release of functional molecules, and DNA-encoded libraries.

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