Study of Matrix Effects in Laser-induced Breakdown Spectroscopy by Laser defocus and Temporal Resolution

Author(s):  
Wei Wang ◽  
Lanxiang Sun ◽  
Peng Zhang ◽  
Tong Chen ◽  
Liming Zheng ◽  
...  

The laser-induced breakdown spectroscopy (LIBS) analysis method displays a significant matrix effects which greatly hinder the application of this technology. Even if the concentration of a certain element is constant,...

Author(s):  
Raquel C Machado ◽  
Diego Victor Babos ◽  
Daniel Fernandes Andrade ◽  
Edenir Rodrigues Pereira-Filho

Quantitative analysis requires several efforts to obtain an adequate calibration method to overcome matrix effects employing direct solid analysis by laser-induced breakdown spectroscopy (LIBS). To this end, in this study,...


1992 ◽  
Vol 46 (9) ◽  
pp. 1382-1387 ◽  
Author(s):  
J. A. Aguilera ◽  
C. Aragón ◽  
J. Campos

Laser-induced breakdown spectroscopy has been used to determine carbon content in steel. The plasma was formed by focusing a Nd:YAG laser on the sample surface. With the use of time-resolved spectroscopy and generation of the plasma in nitrogen atmosphere, a precision of 1.6% and a detection limit of 65 ppm have been obtained. These values are similar to those of other accurate conventional techniques. Matrix effects for the studied steels are reduced to a small slope difference between the calibration curves for stainless and nonstainless steels.


Author(s):  
Ji Chen ◽  
Kaiping Zhan ◽  
Qingzhou Li ◽  
Zhiyang Tang ◽  
Chenwei Zhu ◽  
...  

The quantification accuracy of laser-induced breakdown spectroscopy was limited due to matrix effects. In this work, a method named unsupervised-clustering-based quantification (UCQ) was proposed to reduce the matrix effects by...


Author(s):  
Fu Chang ◽  
Jianhong Yang ◽  
Huili Lu ◽  
Haixia Li

The quantitative analysis accuracy of laser-induced breakdown spectroscopy (LIBS) will decrease if the temperatures of testing samples are different from the temperature under which the calibration model is established. For...


2017 ◽  
Vol 71 (4) ◽  
pp. 600-626 ◽  
Author(s):  
Kate H. Lepore ◽  
Caleb I. Fassett ◽  
Elly A. Breves ◽  
Sarah Byrne ◽  
Stephen Giguere ◽  
...  

2014 ◽  
Vol 05 (11) ◽  
pp. 722-729 ◽  
Author(s):  
Aline Segnini ◽  
Alfredo Augusto Pereira Xavier ◽  
Pedro Luís Otaviani-Junior ◽  
Edilene Cristina Ferreira ◽  
Alex Marcel Watanabe ◽  
...  

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