scholarly journals Optimization of structural expansion and contraction for TiS2 by controlling the electrochemical window of intercalation/delithiation

2022 ◽  
Author(s):  
Xue Han ◽  
Min Wang ◽  
Jingxian Yu ◽  
Shengping Wang

The reversible layered structure of TiS2 with relaxation, such as a spring, was obtained by controlling the optimized potential range of 0.9-2.8 V (vs. Li+/Li) to yield high discharge capacity,...

2012 ◽  
Vol 562-564 ◽  
pp. 799-802 ◽  
Author(s):  
Shuai Liu ◽  
Yun Ze Long ◽  
Hong Di Zhang ◽  
Bin Sun ◽  
Cheng Chun Tang ◽  
...  

LiMn2O4 nanofibers were prepared via electrospinning and followed by calcination. The surface morphology of as-spun and pure LiMn2O4 nanofibers was characterized by a scanning electron microscope (SEM) with an average diameter of 180 nm. After calcination at 800 °C in air for 5 h, charge/discharge capacity of pure LiMn2O4 nanofibers was measured in the potential range of 3.0 to 4.3 V. Battery testing showed that LiMn2O4 have a high discharge capacity of 80 mAh/g and 85% of the initial charge capacity was maintained for 5 cycles.


2021 ◽  
Author(s):  
Jinkwang Hwang ◽  
Rika Hagiwara ◽  
Hiroshi Shinokubo ◽  
Ji-Young Shin

Dual-ion sodium-organic secondary batteries were provided with antiaromatic porphyrinoid, NiNc as an active electrode material, which implemented inherent charge-discharge behaviors with high discharge capacity, high stability, high Coulombic efficiency with...


2020 ◽  
Vol 4 (4) ◽  
pp. 1704-1711
Author(s):  
Zige Tai ◽  
Ming Shi ◽  
Wei Zhu ◽  
Xin Dai ◽  
Yanfei Xin ◽  
...  

We prepared carbon-coated β-MnO2 for the cathode of a lithium-ion battery with high discharge capacity.


2016 ◽  
Vol 4 (19) ◽  
pp. 7289-7296 ◽  
Author(s):  
T. Kimijima ◽  
N. Zettsu ◽  
K. Yubuta ◽  
K. Hirata ◽  
K. Kami ◽  
...  

Highly dispersed primary Li(Ni1/3Co1/3Mn1/3)O2 crystals, which showed high discharge capacity at a high C-rate, were grown from a Li2MoO4 flux.


2007 ◽  
Vol 280-283 ◽  
pp. 671-676 ◽  
Author(s):  
Hong Wei Chan ◽  
Jenq Gong Duh ◽  
Shyang Roeng Sheen

Surface modification on the electrode has a vital impact on lithium-ion batteries, and it is essential to probe the mechanism of the modified film on the surface of the electrode. In this study, a Li2O-2B2O3 film was coated on the surface of the cathode material by solution method. The cathode powders derived from co-precipitation method were calcined with various weight percent of the surface modified glass to form fine powder of single spinel phase with different particle size, size distribution and morphology. The thermogravimetry/differential thermal analysis was used to evaluate the appropriate heat treatment temperature. The structure was confirmed by the X-ray diffractometer along with the composition measured by the electron probe microanalyzer. From the field emission scanning electron microscope image and Laser Scattering measurements, the average particle size was in the range of 7-8µm. The electrochemical behavior of the cathode powder was examined by using two-electrode test cells consisted of a cathode, metallic lithium anode, and an electrolyte of 1M LiPF6. Cyclic charge/discharge testing of the coin cells, fabricated by both coated and un-coated cathode material, provided high discharge capacity. Furthermore, the coated cathode powder showed better cyclability than the un-coated one after the cyclic test. The introduction of the glass-coated cathode material revealed high discharge capacity and appreciably decreased the decay rate after cyclic test.


2015 ◽  
Vol 3 (42) ◽  
pp. 21290-21297 ◽  
Author(s):  
Bing Li ◽  
Chao Li ◽  
Jijun Cai ◽  
Jinbao Zhao

Lithium-rich manganese-based layered oxides with a composition of xLi2MnO3·(1 − x)LiMO2 (M = Mn, Co, Ni, etc.) are attractive, due to their high discharge capacity.


2020 ◽  
Vol 4 (12) ◽  
pp. 6105-6111
Author(s):  
Jiaojiao Ren ◽  
Xuanxuan Yang ◽  
Jianfei Yu ◽  
Xizhang Wang ◽  
Yongbing Lou ◽  
...  

A multi-dimensional structured gaseous cathode: Co-NC@CNTs with interconnected 3D conductive carbon networks for a Li–O2 battery achieve high discharge capacity, rate capability and long cycling life.


2019 ◽  
Vol 7 (12) ◽  
pp. 7213-7220 ◽  
Author(s):  
Hongyan Lu ◽  
Yuanxin Wan ◽  
Tianyi Wang ◽  
Rong Jin ◽  
Peitao Ding ◽  
...  

A novel SnO2/C AIB with high discharge capacity and long cycle life is achieved.


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