Prediction of Formation Probability of Rare earth uranates inside nuclear reactor fuel from the determined oxygen potential using solid oxide Galvanic cell

2021 ◽  
Author(s):  
Manjulata Sahu ◽  
Sumanta Mukherjee ◽  
Geeta Prakash Shelke ◽  
Smruti Dash ◽  
Manoj Kumar Saxena
Keyword(s):  
Rare Earth ◽  
Oxygen Potential ◽  
Nuclear Reactor ◽  
Combustion Method ◽  
Solid Oxide ◽  
Synthesis Conditions ◽  
Nuclear Reactor Fuel ◽  
Gel Combustion ◽  
Rare Earth Uranates ◽  
Gel Combustion Method

The Pr6UO12(s) and Er6UO12(s) were synthesized by citrate nitrate gel combustion method. The synthesis conditions were optimized from the study of precursors of these uranates in the temperature range 973...

Perovskite gels combustion synthesis from rare earth aluminates. Development of multifuncional properties.

MRS Advances ◽  
2020 ◽  
Vol 5 (62) ◽  
pp. 3301-3313
Author(s):  
A. Barrera ◽  
M.L. Chávez ◽  
E. Chavira ◽  
T.A. García ◽  
J.M.E. Carreto
Keyword(s):  
Particle Size ◽  
Rare Earth ◽  
Sol Gel ◽  
Luminescent Properties ◽  
Combustion Method ◽  
Ceramic Pigments ◽  
Material Development ◽  
Gel Combustion ◽  
Gel Combustion Method ◽  
Paramagnetic Properties

AbstractThe purpose of this work was the synthesis of the perovskites with rare earth, by gel combustion method with pigmenting, magnetic and luminescent properties. The synthesis of perovskite structure is important for material development, with multi features. In this work, the synthesis was from metal oxides by the method of combustion of gels at 500 °C, for 10 s. Color of perovskites obtained, with nanometric particle size (31-44 nm) was analysed by CIEL*a*b* with tonalities ranged from white to pink except for Pr-perovskites with yellow and brown. Its paramagnetic properties were verified by magnetic susceptibility. Its luminescence was at 260 nm, except for Pr-perovskites. This work opens an important opportunity to develop ceramic pigments with perovskites structures integrating other properties as luminescence and paramagnetism by combustion sol-gel method.

Synthesis and Processing of Perovskite Oxides for Solid Oxide Fuel Cells Anode Fabrication

2006 ◽  
Vol 45 ◽  
pp. 1864-1868
Author(s):  
Dario Montinaro ◽  
Massimo Bertoldi ◽  
Vincenzo M. Sglavo
Keyword(s):  
Fuel Cells ◽  
Solid Oxide Fuel Cells ◽  
Single Phase ◽  
Tape Casting ◽  
Combustion Method ◽  
Solid Oxide ◽  
Oxide Fuel ◽  
Gel Combustion ◽  
Synthesis And Processing ◽  
Gel Combustion Method

In the present work materials alternative to Ni/YSZ cermets anodes for Solid Oxide Fuel Cells (SOFCs) have been studied in order to overcome the problems related to catalytic deposition of carbon and the limited tolerance to sulphur. Anodes consisting of (La0.75Sr0.25)(Cr0.5Mn0.5)O3-δ (LSCM25) have been investigated with regard to synthesis and processing related problems. Single phase LSCM25 perovskites were synthesized by urea/nitrates gel combustion method and the as prepared powders were used to produce green tapes by tape casting processing. Thick LSCM25 substrates, suitable as anodes in anode supported SOFC fabrication, were successfully obtained by sintering of green LSCM25 laminates.

scholarly journals UV Light Induced Thermoluminescence of Rare Earth doped Nanomaterials Y\(_2\)O\(_3\):Eu\(^{3+}\), Gd\(_2\)O\(_3\):Eu\(^{3+}\) and Gd\(_2\)O\(_3\):Er\(^{3+}\)

2018 ◽  
Vol 28 (1) ◽  
pp. 75 ◽  
Author(s):  
Nguyen Thi Quy Hai ◽  
Tran Kim Anh ◽  
Vu Thi Thai Ha ◽  
Pham Thi Minh Chau ◽  
Ho Van Tuyen ◽  
...  
Keyword(s):  
Rare Earth ◽  
Low Temperature ◽  
High Efficiency ◽  
Uv Light ◽  
Combustion Method ◽  
Gel Combustion ◽  
Doped Nanomaterials ◽  
Gel Combustion Method ◽  
Rare Earth Doped ◽  
Very High

Thermoluminescence  properties of ultraviolet irradiated Y2O3:Eu3+, Gd2O3:Eu3+ and Gd2O3:Er3+ nanophosphors have been reported. The materials were synthesized by gel- combustion method with EDTA- Na2 as organic agent. This method allows production of very fine white powder at low temperature with very high efficiency. XRD has been studied to determine the structure of the prepared nano powders. The obtained materials exhibit sufficient sensibility to UV radiation and may be useful in UV light measurements.

Li(Ni1/3Co1/3Mn1/3)O2 with High Rate Capability Synthesized via a Novel Gel-Combustion Method

2011 ◽  
Vol 391-392 ◽  
pp. 973-977
Author(s):  
Jing Mao ◽  
Ke Hua Dai ◽  
Yu Chun Zhai
Keyword(s):  
Energy Dispersive Spectrometer ◽  
Rate Capability ◽  
Chelating Agent ◽  
Combustion Method ◽  
Xrd Analysis ◽  
High Rate ◽  
High Rate Capability ◽  
Sem Images ◽  
Gel Combustion ◽  
Gel Combustion Method

Li(Ni1/3Co1/3Mn1/3)O2material with high rate capability was synthesized by a novel gel-combustion method using polyvinylpyrrolidone as a polymer chelating agent and a fuel. X-ray diffraction (XRD), scanning electron microscope (SEM) and energy dispersive spectrometer (EDS) were used to study the structure, morphology and element distribution of the Li(Ni1/3Co1/3Mn1/3)O2material. XRD analysis showed that all samples were α-NaFeO2structure and Li(Ni1/3Co1/3Mn1/3)O2prepared at 900 °C had the highest c/a of 4.977 indicating the highest layered-ness. EDS scan demonstrated that the precursor was homogeneous. SEM images indicated all samples were well crystallized. Charge and discharge tests showed all samples had good rate capability. Among them, Li(Ni1/3Co1/3Mn1/3)O2prepared at 900 °C had the highest capacity and the best rate capability. It delivered 162.1 mAh•g−1at 0.25 C between 2.5 and 4.3 V and the capacity retention was about 81% compared to that of 0.25C rate.

Kinetics of nanocrystalline MgO growth by the sol–gel combustion method

2014 ◽  
Vol 185 ◽  
pp. 86-91 ◽  
Author(s):  
Alexandre R. Bueno ◽  
Renata F.M. Oman ◽  
Paula M. Jardim ◽  
Nicolás A. Rey ◽  
Roberto R. de Avillez
Keyword(s):  
Sol Gel ◽  
Combustion Method ◽  
Gel Combustion ◽  
Kinetics Of ◽  
Gel Combustion Method ◽  
Nanocrystalline Mgo

scholarly journals Synthesis of Blue-Green Phosphors Sr4Si3O8Cl4:Eu2+by Gel-Combustion Method and Their Luminescent Properties

2013 ◽  
Vol 2013 ◽  
pp. 1-6 ◽  
Author(s):  
Yong-Qing Zhai ◽  
Li-Li Wang ◽  
Juan Chen ◽  
Shi-Hua Feng
Keyword(s):  
Broad Band ◽  
Orthorhombic Phase ◽  
Luminescent Properties ◽  
Combustion Method ◽  
Main Peak ◽  
X Ray Diffraction ◽  
Doping Amount ◽  
Gel Combustion ◽  
Main Emission Peak ◽  
Gel Combustion Method

Sr4Si3O8Cl4:Eu2+blue-green phosphors were synthesized by the gel-combustion method. The as-synthesized phosphors were analyzed and characterized by X-ray diffraction and fluorescence spectrophotometer. The results indicate that orthorhombic phaseSr4Si3O8Cl4:Eu2+has been formed after the precursor calcined at 900°C reductive temperature. The excitation spectrum ofSr4Si3O8Cl4:Eu2+is a broad band in the range of 250 ~ 450 nm and the main peak at 324 nm. The emission spectrum is also a broad band with the main emission peak at about 484 nm, which is ascribed to the typical 4f5d1to 4f7transition ofEu2+. Moreover, the effects of the concentration ofEu2+, the reductive temperature, and the doping amount ofMg2+on luminescent properties were discussed.

Synthesis of nanocrystalline Ca2Cu2Fe12O22 Y-type hexaferrites by the sol–gel combustion method in metal nitrates system

2018 ◽  
Vol 526 (1) ◽  
pp. 187-192 ◽  
Author(s):  
S. B. Bankar ◽  
N. S. Meshram ◽  
N. N. Sarkar ◽  
H. S. Ahamad ◽  
S. J. Dhobale ◽  
...  
Keyword(s):  
Sol Gel ◽  
Combustion Method ◽  
Metal Nitrates ◽  
Gel Combustion ◽  
Gel Combustion Method

Low temperature synthesis of wollastonite using sol–gel combustion method: In vitro bioactivity evaluation

2019 ◽  
Vol 33 (10) ◽  
pp. 1950081 ◽  
Author(s):  
Madeeha Riaz ◽  
Rehana Zia ◽  
Snudia Aslam ◽  
Alliya Qamar ◽  
Tousif Hussain ◽  
...  
Keyword(s):  
Low Temperature ◽  
Sol Gel ◽  
Calcium Nitrate ◽  
Combustion Method ◽  
Calcium Nitrate Tetrahydrate ◽  
In Vitro Bioactivity ◽  
Nitrate Tetrahydrate ◽  
Gel Combustion ◽  
Gel Combustion Method

In this paper, low temperature, economical sol–gel combustion method was adopted to synthesize wollastonite ceramic. Calcium nitrate tetrahydrate and tetraethyl orthosilicate were taken as source for Ca and Si, while citric acid and nitric acid were used as chelating/combustion agents. The yielded powder calcined at 600[Formula: see text]C for 4 h was characterized by FTIR, XRD and SEM techniques. Results showed that the citrate combustion method was the most efficient method to prepare wollastonite at low temperature. Moreover, in vitro bioactivity test performed in simulated body fluid (SBF) showed good bioactivity of synthesized wollastonite ceramics.

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