scholarly journals Novel bio-based filler: hyperbranched polymer modified leather buffing dust and its influence on the porous structure and mechanical properties of polyurethane film

RSC Advances ◽  
2021 ◽  
Vol 11 (44) ◽  
pp. 27183-27192
Author(s):  
Jie Liu ◽  
Feifei Zhang ◽  
Zhendi An ◽  
Wanpeng Shi ◽  
Hong Li

In this research, amino functional buffing dust (HBD) was used as an excellent biomass functional filler to improve the hygienic properties of synthetic leather, and provide a novel way for the treatment and disposal of leather buffing waste.

2010 ◽  
Vol 34-35 ◽  
pp. 1165-1169 ◽  
Author(s):  
Yong Feng Li ◽  
Bao Gang Wang ◽  
Qi Liang Fu ◽  
Yi Xing Liu ◽  
Xiao Ying Dong

In order to improve the value-added applications of low-quality wood, a novel composite, wood-polymer composite, was fabricated by in-situ terpolymerization of MMA, VAc and St within wood porous structure. The structure of the composite and the reaction of monomers within wood were both analyzed by SEM and FTIR, and the mechanical properties were also evaluated. The SEM observation showed that the polymer mainly filled up wood pores, suggesting good polymerizating crafts. The FTIR results indicated that under the employed crafts, three monomers terpolymerized in wood porous structure, and grafted onto wood matrix through reaction of ester group from monomers and hydroxyl group from wood components, suggesting chemical combination between the two phases. The mechanical properties of the wood-polymer composite involving modulus of rupture, compressive strength, wearability and hardness were improved 69%, 68%, 36% and 210% over those of untreated wood, respectively. Such method seems to be an effective way to converting low-quality wood to high-quality wood.


2010 ◽  
Vol 152-153 ◽  
pp. 1650-1659
Author(s):  
Qing Hao Yang ◽  
Guang Xu Cheng ◽  
Zhi Cheng Zhang

In an effort to seek poly(vinyl formal) (PVFM) foams based wound dressing pad material, a series of foamed PVFM materials have been synthesized under varied conditions. The influence of conditions on the properties of PVFM foam, such as mechanical properties, water absorption, pore structure and bulk density, is well discussed individually. It has been shown that both the reactant and acid catalyst affect the degree and speed of acetalization, therefore the mechanical properties, pores continuity and water absorption of the resultant sample. The addition of Na2CO3, surfactant and CMCNa are mainly influencing the porous structure as well as the mechanical properties and water absorption. One best sample with balanced properties is obtained. It possesses higher mechanical strength and water absorption while the other properties are similar, comparing with a commercial surgical PVFM sponge (YJ-1) currently used.


Cerâmica ◽  
2019 ◽  
Vol 65 (375) ◽  
pp. 443-451 ◽  
Author(s):  
B. A. Medeiros ◽  
G. A. Neves ◽  
N. P. Barbosa ◽  
R. R. Menezes ◽  
H. C. Ferreira

Abstract The residue generated by industrial activities represents a cost, since the generators are responsible for its management, transportation, treatment and disposal. Rio Grande do Norte State in Brazil is the greatest producer of scheelite residue. The aim of this research was to characterize this mining residue, identify its similarity with natural sand and produce a coating mortar with it. In the composition of mortar, a Brazilian Portland cement type CPII-F32 and an industrialized calcium hydroxide as a binder were used. Laser granulometry, bulk and relative density, EDX, XRD and thermal analysis were done to obtain a physical and chemical characterization of the residue. Mechanical tests (tensile bond strength and compressive strength), SEM and water absorption test were done to analyze the behavior of mortar. All tests confirmed that mechanical properties were according to standards for tile mortar.


2020 ◽  
Vol 143 (5) ◽  
Author(s):  
V. Sheremetyev ◽  
S. Dubinskiy ◽  
M. A. Iqbal ◽  
K. Lukashevich ◽  
S. Prokoshkin ◽  
...  

Abstract Improving the post-processing of metallic porous tissue scaffolds is an essential step to create a new generation of superelastic implants for the replacement of damaged bone tissue. In this study, the dynamic chemical etching technique is applied to improve the permeability and to optimize the porous structure of Ti-Nb-Zr scaffolds fabricated by the powder metallurgy-based space holder technique. The etched scaffolds are characterized in terms of their porous structure geometry, permeability, and mechanical properties. It is shown that an increase in porosity from 49% to 54% during the etching is mainly due to an increase in the number of 100 to 800 μm-diameter pores, from 30% to 50% of them measuring from 100 to 300 μm in size. These changes in the porous structure lead to a significant increase of its permeability, i.e., from (0.1–15) × 10−11 m2 before etching to (44–91) × 10−11 m2, after etching; these permeability ranges corresponding to those of bone tissues. Furthermore, the etched scaffolds show systematically higher yield compressive stresses as compared to the as-sintered scaffolds of equivalent porosities. Finally, the highly permeable etched Ti-Nb-Zr scaffolds with a porosity varying from 40% to 60% exhibit an apparent Young’s modulus ranging from 8.6 to 1.9 GPa and an ultimate compressive strength from 650 to 190 MPa, which can be considered as a promising balance of properties for the potential use of these scaffolds as bone implants.


2014 ◽  
Vol 1662 ◽  
Author(s):  
Max Larner ◽  
John Acker ◽  
Lilian P. Dávila

ABSTRACTLightweight porous foams have been of particular interest in recent years, since they have a very unique set of properties which can be significantly different from their solid parent materials. These properties arise from their random porous structure which is generated through specialized processing techniques. Their unique structure gives these materials interesting properties which allow them to be used in diverse applications. In particular, highly porous Al foams have been used in aircraft components and sound insulation; however due to the difficulty in processing and the random nature of the foams, they are not well understood and thus have not yet been utilized to their full potential. The objective of this study was to integrate experiments and simulations to determine whether a relationship exists between the relative density (porous density/bulk density) and the mechanical properties of open-cell Al foams. Compression experiments were performed using an Instron Universal Testing Machine (IUTM) on ERG Duocel open-cell Al foams with 5.8% relative density, with compressive loads ranging from 0-6 MPa. Foam models were generated using a combination of an open source code, Voro++, and MATLAB. A Finite Element Method (FEM)-based software, COMSOL Multiphysics 4.3, was used to simulate the mechanical behavior of Al foam structures under compressive loads ranging from 0-2 MPa. From these simulated structures, the maximum von Mises stress, volumetric strain, and other properties were calculated. These simulation results were compared against data from compression experiments. CES EduPack software, a materials design program, was also used to estimate the mechanical properties of open-cell foams for values not available experimentally, and for comparison purposes. This program allowed for accurate prediction of the mechanical properties for a given percent density foam, and also provided a baseline for the Al foam samples tested via the IUTM method. Predicted results from CES EduPack indicate that a 5.8% relative density foam will have a Young’s Modulus of 0.02-0.92 GPa while its compressive strength will be 0.34-3.37 MPa. Overall results revealed a relationship between pores per inch and selected mechanical properties of Al foams. The methods developed in this study can be used to efficiently generate open-cell foam models, and to combine experiments and simulations to calculate structure-property relationships and predict yielding and failure, which may help in the pursuit of simulation-based design of metallic foams. This study can help to improve the current methods of characterizing foams and porous materials, and enhance knowledge about theirproperties for novel applications.


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